Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment

Advanced Separation Techniques for Nuclear Fuel Reprocessing and Radioactive Waste Treatment

Author: Kenneth L Nash

Publisher: Elsevier

Published: 2011-03-15

Total Pages: 513

ISBN-13: 0857092278

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Advanced separations technology is key to closing the nuclear fuel cycle and relieving future generations from the burden of radioactive waste produced by the nuclear power industry. Nuclear fuel reprocessing techniques not only allow for recycling of useful fuel components for further power generation, but by also separating out the actinides, lanthanides and other fission products produced by the nuclear reaction, the residual radioactive waste can be minimised. Indeed, the future of the industry relies on the advancement of separation and transmutation technology to ensure environmental protection, criticality-safety and non-proliferation (i.e., security) of radioactive materials by reducing their long-term radiological hazard.Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment provides a comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment. Part one covers the fundamental chemistry, engineering and safety of radioactive materials separations processes in the nuclear fuel cycle, including coverage of advanced aqueous separations engineering, as well as on-line monitoring for process control and safeguards technology. Part two critically reviews the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment. The section includes discussions of advanced PUREX processes, the UREX+ concept, fission product separations, and combined systems for simultaneous radionuclide extraction. Part three details emerging and innovative treatment techniques, initially reviewing pyrochemical processes and engineering, highly selective compounds for solvent extraction, and developments in partitioning and transmutation processes that aim to close the nuclear fuel cycle. The book concludes with other advanced techniques such as solid phase extraction, supercritical fluid and ionic liquid extraction, and biological treatment processes.With its distinguished international team of contributors, Advanced separation techniques for nuclear fuel reprocessing and radioactive waste treatment is a standard reference for all nuclear waste management and nuclear safety professionals, radiochemists, academics and researchers in this field. - A comprehensive and timely reference on nuclear fuel reprocessing and radioactive waste treatment - Details emerging and innovative treatment techniques, reviewing pyrochemical processes and engineering, as well as highly selective compounds for solvent extraction - Discusses the development and application of separation and extraction processes for nuclear fuel reprocessing and radioactive waste treatment


Advances in Nuclear Fuel Chemistry

Advances in Nuclear Fuel Chemistry

Author: Markus H.A. Piro

Publisher: Woodhead Publishing

Published: 2020-03-20

Total Pages: 672

ISBN-13: 008102651X

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Advances in Nuclear Fuel Chemistry presents a high-level description of nuclear fuel chemistry based on the most recent research and advances. Dr. Markus H.A. Piro and his team of global, expert contributors cover all aspects of both the conventional uranium-based nuclear fuel cycle and non-conventional fuel cycles, including mining, refining, fabrication, and long-term storage, as well as emerging nuclear technologies, such as accident tolerant fuels and molten salt materials. Aimed at graduate students, researchers, academics and practicing engineers and regulators, this book will provide the reader with a single reference from which to learn the fundamentals of classical thermodynamics and radiochemistry. - Consolidates the latest research on nuclear fuel chemistry into one comprehensive reference, covering all aspects of traditional and non-traditional nuclear fuel cycles - Includes contributions from world-renowned experts from many countries representing government, industry and academia - Covers a variety of fuel designs, including conventional uranium dioxide, mixed oxides, research reactor fuels, and molten salt fuels - Written by experts with hands-on experience in the development of such designs


Radiochemistry and Nuclear Chemistry

Radiochemistry and Nuclear Chemistry

Author: Gregory Choppin

Publisher: Butterworth-Heinemann

Published: 2002

Total Pages: 726

ISBN-13: 0750674636

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Origin of Nuclear Science; Nuclei, Isotopes and Isotope Separation; Nuclear Mass and Stability; Unstable Nuclei and Radioactive Decay; Radionuclides in Nature; Absorption of Nuclear Radiation; Radiation Effects on Matter; Detection and Measurement Techniques; Uses of Radioactive Tracers; Cosmic Radiation and Elementary Particles; Nuclear Structure; Energetics of Nuclear Reactions; Particle Accelerators; Mechanics and Models of Nuclear Reactions; Production of Radionuclides; The Transuranium Elements; Thermonuclear Reactions: the Beginning and the Future; Radiation Biology and Radiation Protection; Principles of Nuclear Power; Nuclear Power Reactors; Nuclear Fuel Cycle; Behavior of Radionuclides in the Environment; Appendices; Solvent Extraction Separations; Answers to Exercises; Isotope Chart; Periodic Table of the Elements; Quantities and Units; Fundamental Constants; Energy Conversion Factors; Element and Nuclide Index; Subject Index.


Nuclear Power and the Environment

Nuclear Power and the Environment

Author: Royal Society of Chemistry (Great Britain)

Publisher: Royal Society of Chemistry

Published: 2011

Total Pages: 247

ISBN-13: 1849731942

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Reviews the political and social context for nuclear power generation, the nuclear fuel cycles and their implications for the environment.


State-of-the-art Report on the Progress of Nuclear Fuel Cycle Chemistry

State-of-the-art Report on the Progress of Nuclear Fuel Cycle Chemistry

Author:

Publisher:

Published: 2018

Total Pages: 148

ISBN-13:

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The implementation of advanced nuclear systems requires that new technologies associated with the back end of the fuel cycle are developed. The separation of minor actinides from other fuel components is one of the advanced concepts being studied to help close the nuclear fuel cycle and to improve the long-term effects on the performance of geological repositories. Separating spent fuel elements and subsequently converting them through transmutation into short-lived nuclides should considerably reduce the longterm risks associated with nuclear power generation.


Plutonium

Plutonium

Author: Frank von Hippel

Publisher: Springer Nature

Published: 2019-12-23

Total Pages: 193

ISBN-13: 9811399018

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This book provides a readable and thought-provoking analysis of the issues surrounding nuclear fuel reprocessing and fast-neutron reactors, including discussion of resources, economics, radiological risk and resistance to nuclear proliferation. It describes the history and science behind reprocessing, and gives an overview of the status of reprocessing programmes around the world. It concludes that such programs should be discontinued. While nuclear power is seen by many as the only realistic solution to the carbon emission problem, some national nuclear establishments have been pursuing development and deployment of sodium-cooled plutonium breeder reactors, and plutonium recycling. Its proponents argue that this system would offer significant advantages relative to current light water reactor technology in terms of greater uranium utilization efficiency, and that separating out the long-lived plutonium and other transuranics from spent fuel and fissioning them in fast reactors would greatly reduce the duration of the toxicity of radioactive waste. However, the history of efforts to deploy this system commercially in a number of countries over the last six decades has been one of economic and technical failure and, in some cases, was used to mask clandestine nuclear weapon development programs. Covering topics of significant public interest including nuclear safety, fuel storage, environmental impact and the spectre of nuclear terrorism, this book presents a comprehensive analysis of the issue for nuclear engineers, policy analysts, government officials and the general public. "Frank von Hippel, Jungmin Kang, and Masafumi Takubo, three internationally renowned nuclear experts, have done a valuable service to the global community in putting together this book, which both historically and comprehensively covers the “plutonium age” as we know it today. They articulate in a succinct and clear manner their views on the dangers of a plutonium economy and advocate a ban on the separation of plutonium for use in the civilian fuel cycle in view of the high proliferation and nuclear-security risks and lack of economic justification." (Mohamed ElBaradei, Director General, International Atomic Energy Agency (1997-2009), Nobel Peace Prize (2005)) "The 1960s dream of a ‘plutonium economy’ has not delivered abundant low-cost energy, but instead has left the world a radioactive legacy of nuclear weapons proliferation and the real potential for nuclear terrorism. Kang, Takubo, and von Hippel explain with power and clarity what can be done to reduce these dangers. The governments of the remaining countries whose nuclear research and development establishments are still pursuing the plutonium dream should pay attention.” (Senator Edward Markey, a leader in the US nuclear-disarmament movement as a member of Congress since 1976) "The authors have done an invaluable service by putting together in one place the most coherent analysis of the risks associated with plutonium, and the most compelling argument for ending the practice of separating plutonium from spent fuel for any purpose. They have given us an easily accessible history of the evolution of thinking about the nuclear fuel cycle, the current realities of nuclear power around the world and, arguably most important, a clear alternative path to deal with the spent fuel arising from nuclear reactors for decades to centuries to come." (Robert Gallucci, Chief US negotiator with North Korea (1994); Dean, Georgetown University School of Foreign Service (1996-2009); President, MacArthur Foundation (2009-2014))


Medical Isotope Production Without Highly Enriched Uranium

Medical Isotope Production Without Highly Enriched Uranium

Author: National Research Council

Publisher: National Academies Press

Published: 2009-06-27

Total Pages: 220

ISBN-13: 0309130395

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This book is the product of a congressionally mandated study to examine the feasibility of eliminating the use of highly enriched uranium (HEU2) in reactor fuel, reactor targets, and medical isotope production facilities. The book focuses primarily on the use of HEU for the production of the medical isotope molybdenum-99 (Mo-99), whose decay product, technetium-99m3 (Tc-99m), is used in the majority of medical diagnostic imaging procedures in the United States, and secondarily on the use of HEU for research and test reactor fuel. The supply of Mo-99 in the U.S. is likely to be unreliable until newer production sources come online. The reliability of the current supply system is an important medical isotope concern; this book concludes that achieving a cost difference of less than 10 percent in facilities that will need to convert from HEU- to LEU-based Mo-99 production is much less important than is reliability of supply.


An Introduction to Nuclear Waste Immobilisation

An Introduction to Nuclear Waste Immobilisation

Author: Michael I Ojovan

Publisher: Elsevier

Published: 2013-12-06

Total Pages: 0

ISBN-13: 9780080993928

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Drawing on the authors' extensive experience in the processing and disposal of waste, An Introduction to Nuclear Waste Immobilisation, Second Edition examines the gamut of nuclear waste issues from the natural level of radionuclides in the environment to geological disposal of waste-forms and their long-term behavior. It covers all-important aspects of processing and immobilization, including nuclear decay, regulations, new technologies and methods. Significant focus is given to the analysis of the various matrices used, especially cement and glass, with further discussion of other matrices such as bitumen. The final chapter concentrates on the performance assessment of immobilizing materials and safety of disposal, providing a full range of the resources needed to understand and correctly immobilize nuclear waste.


Isotopic Analysis

Isotopic Analysis

Author: Frank Vanhaecke

Publisher: John Wiley & Sons

Published: 2012-04-24

Total Pages: 565

ISBN-13: 3527650504

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Edited by two very well-known and respected scientists in the field, this excellent practical guide is the first to cover the fundamentals and a wide range of applications, as well as showing readers how to efficiently use this increasingly important technique. From the contents: * The Isotopic Composition of the Elements * Single-Collector ICP-MS * Multi-Collector ICP-MS * Advances in Laser Ablation - Multi-Collector ICP-MS * Correction for Instrumental Mass Discrimination in Isotope Ratio Determination with Multi-Collector ICP-MS * Reference Materials in Isotopic Analysis * Quality Control in Isotope Ratio Applications * Determination of Trace Elements and Elemental Species Using Isotope Dilution ICP-MS * Geochronological Dating * Application of Multi-Collector ICP-MS to Isotopic Analysis in Cosmochemistry * Establishing the Basis for Using Stable Isotope Ratios of Metals as Paleoredox Proxies * Isotopes as Tracers of Elements Across the Geosphere-Biosphere Interface * Archaeometric Applications * Forensics Applications * Nuclear Applications * The Use of Stable Isotope Techniques for Studying Mineral and Trace Element Metabolism in Humans * Isotopic Analysis via Multi-Collector ICP-MS in Elemental Speciation A must-have for newcomers as well as established scientists seeking an overview of isotopic analysis via ICP-MS.