In this book well-known experts highlight cutting-edge research priorities and discuss the state of the art in the field of solid oxide fuel cells giving an update on specific subjects such as protonic conductors, interconnects, electrocatalytic and catalytic processes and modelling approaches.Fundamentals and advances in this field are illustrated to help young researchers address issues in the characterization of materials and in the analysis of processes, not often tackled in scholarly books.
Developing materials for SOFC applications is one of the key topics in energy research. The book focuses on manganite structured materials, such as doped lanthanum chromites and lanthanum manganites, which have interesting properties: thermal and chemical stability, mixed ionic and electrical conductivity, electrocatalytic activity, magnetocaloric property and colossal magnetoresistance (CMR). These materials have applications in solid oxide fuel cells, high temperature NOx sensors, hard disk read heads, magnetic sensors and magnetoresistive random access memories. For the first time, the charge density distributions have been studied in these materials as synthesized by high temperature solid state reaction. Charge density analysis is helpful in understanding the physical and chemical properties of materials and in developing optimized structures. The morphological, elemental, optical and magnetic properties of the materials have also been studied. Solid Oxide Fuel Cells, SOFC, Manganite Structured Materials, Lanthanum Chromites, Lanthanum Manganites, Electrocatalytic Activity, Magnetocaloric Property, Colossal Magnetoresistance, High Temperature NOx Sensors, Hard Disk Read Heads, Magnetic Sensors, Magnetoresistive Random Access Memories, Charge Density Distribution
Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects. This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry. - Provides a single source of information on glass, electrolytes, interconnects, vanadates, pyrochlores and perovskite SOFC - Includes illustrations that provide a clear visual explanation of concepts being discussed - Progresses from a discussion of basic concepts that will enable readers to easily comprehend the subject matter
High temperature solid oxide fuel cell (SOFC) technology is a promising power generation option that features high electrical efficiency and low emissions of environmentally polluting gases such as CO2, NOox and SOx. It is ideal for distributed stationary power generation applications where both high-efficiency electricity and high-quality heat are in strong demand. For the past few decades, SOFC technology has attracted intense worldwide R&D effort and, along with polymer electrolyte membrane fuel cell (PEMFC) technology, has undergone extensive commercialization development.This book presents a systematic and in-depth narrative of the technology from the perspective of fundamentals, providing comprehensive theoretical analysis and innovative characterization techniques for SOFC technology. The book initially deals with the basics and development of SOFC technology from cell materials to fundamental thermodynamics, electronic properties of solids and charged particle transport. This coverage is extended with a thorough analysis of such operational features as current flow and energy balance, and on to voltage losses and electrical efficiency. Furthermore, the book also covers the important issues of fuel cell stability and durability with chapters on performance characterization, fuel processing, and electrode poisoning. Finally, the book provides a comprehensive review for SOFC materials and fabrication techniques. A series of useful scientific appendices rounds off the book.Solid oxide fuel cell technology is a standard reference for all those researching this important field as well as those working in the power industry. - Provides a comprehensive review of solid oxide fuel cells from history and design to chemistry and materials development - Presents analysis of operational features including current flow, energy balance, voltage losses and electrical efficiency - Explores fuel cell stability and durability with specific chapters examining performance characterization, fuel processing and electrode poisoning
Fuel cells are expected to play a relevant role in the transition towards a sustainable-energy-driven world. Although this type of electrochemical system was discovered a long time ago, only in recent years has global energy awareness, together with newly developed materials and available technologies, made such key advances in relation to fuel cell potential and its deployment. It is now unquestionable that fuel cells are recognized, alongside their possibility to work in the reverse mode, as the hub of the new energy deal. Now the questions are, why are they not yet ready to be used, despite the strong economic support given from the society? What prevents them from being entered into the hydrogen energy scenario in which renewable sources will provide energy when it is not readily available? How much are researchers involved in this urgent step towards change? This book gives a clear answer, engaging with some of the open issues that explain the delay of fuel cell deployment and, at the same time, it opens a window that shows how wide and attractive the opportunities offered by this technology are. Papers collected here are not only specialist-oriented but also offer a clear landscape to curious readers and show how challenging the road to the future is.
This book covers all the proposed fuel cell systems including PEMFC, SOFC, PAFC, MCFC, regenerative fuel cells, direct alcohol fuel cells, and small fuel cells to replace batteries.
High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information. The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level.
In order to enable an affordable, sustainable, fossil-free future energy supply, research activities on relevant materials and related technologies have been intensified in recent years, Advanced Ceramics for Energy Conversion and Storage describes the current state-of-the-art concerning materials, properties, processes, and specific applications. Academic and industrial researchers, materials scientists, and engineers will be able to get a broad overview of the use of ceramics in energy applications, while at the same time become acquainted with the most recent developments in the field. With chapters written by recognized experts working in their respective fields the book is a valuable reference source covering the following application areas: ceramic materials and coatings for gas turbines; heat storage and exchange materials for solar thermal energy; ceramics for nuclear energy; ceramics for energy harvesting (thermoelectrics, piezoelectrics, and sunlight conversion); ceramic gas separation membranes; solid oxide fuel cells and electrolysers; and electrochemical storage in battery cells. Advanced Ceramics for Energy Conversion and Storage offers a sound base for understanding the complex requirements related to the technological fields and the ceramic materials that make them possible. The book is also suitable for people with a solid base in materials science and engineering that want to specialize in ceramics. - Presents an extensive overview of ceramic materials involved in energy conversion and storage - Updates on the tremendous progress that has been achieved in recent years - Showcases authors at the forefront of their fields, including results from the huge amount of published data - Provides a list of requirements for the materials used for each energy technology - Includes an evaluation and comparison of materials available, including their structure, properties and performance
This book is a collection of papers from The American Ceramic Society's 35th International Conference on Advanced Ceramics and Composites, held in Daytona Beach, Florida, January 23-28, 2011. This issue includes papers presented in the 8th International Symposium on Solid Oxide Fuel Cells: Materials, Science, and Technology on topics such as Cell and Stack Development; Electrochemical/Mechanical/Thermal Performance; Electrodes; Interconnects; Novel Cell/Stack Design and Processing; and Reliability/Degradation.
Ceramic fuel cells, commonly known as solid oxide fuel cells (SOFCs), have been under development for a broad range of electric power generation applications. The most attractive feature of the SOFC is its clean and efficient production of electricity from a variety of fuels. The SOFC has the potential to be manufactured and operated cost-effectively. The widening interest in this technology, thus, arises from the continuing need to develop cleaner and more efficient means of converting energy sources into useful forms.This topical book provides a comprehensive treatise on solid oxide fuel cells and succeeds successfully in filling the gap in the market for a reference book in this field. Directed towards scientists, engineers, and technical managers working with SOFCs as well as ceramic devices based on conducting materials, and in related fields, the book will also be invaluable as a textbook for science and engineering courses.
