Water and Aqueous Solutions
Water and Aqueous Solutions

Author: Arieh Ben-Naim

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 481

ISBN-13: 1461587026

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The molecular theory of water and aqueous solutions has only recently emerged as a new entity of research, although its roots may be found in age-old works. The purpose of this book is to present the molecular theory of aqueous fluids based on the framework of the general theory of liquids. The style of the book is introductory in character, but the reader is presumed to be familiar with the basic properties of water [for instance, the topics reviewed by Eisenberg and Kauzmann (1969)] and the elements of classical thermodynamics and statistical mechanics [e.g., Denbigh (1966), Hill (1960)] and to have some elementary knowledge of probability [e.g., Feller (1960), Papoulis (1965)]. No other familiarity with the molecular theory of liquids is presumed. For the convenience of the reader, we present in Chapter 1 the rudi ments of statistical mechanics that are required as prerequisites to an under standing of subsequent chapters. This chapter contains a brief and concise survey of topics which may be adopted by the reader as the fundamental "rules of the game," and from here on, the development is very slow and detailed.

Molecular Theory Of Water And Aqueous Solutions - Part 1: Understanding Water
Molecular Theory Of Water And Aqueous Solutions - Part 1: Understanding Water

Author: Arieh Ben-naim

Publisher: World Scientific

Published: 2009-07-17

Total Pages: 660

ISBN-13: 9814469033

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The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules. It is mostly the result of the author's own research spanning over 40 years in the field of aqueous solutions. An understanding of the properties of liquid water is a prelude to the understanding of the role of water in biological systems and for the evolvement of life.The book is targeted at anyone who is interested in the outstanding properties of water and its role in biological systems. It is addressed to both students and researchers in chemistry, physics and biology.

Molecular Theory of Water and Aqueous Solutions: The role of water in protein folding, self-assembly and molecular recognition
Molecular Theory of Water and Aqueous Solutions: The role of water in protein folding, self-assembly and molecular recognition

Author: Arieh Ben-Naim

Publisher: World Scientific

Published: 2009

Total Pages: 482

ISBN-13: 9814350532

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"The aim of this book is to explain the unusual properties of both pure liquid water and simple aqueous solutions, in terms of the properties of single molecules and interactions among small numbers of water molecules. It is mostly the result of the author's own research spanning over 40 years in the field of aqueous solutions."--Jacket.

Information Theory
Information Theory

Author: Arieh Ben-Naim

Publisher: World Scientific

Published: 2017-05-26

Total Pages: 365

ISBN-13: 9813208821

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This book is about the definition of the Shannon measure of Information, and some derived quantities such as conditional information and mutual information. Unlike many books, which refer to the Shannon's Measure of information (SMI) as "Entropy," this book makes a clear distinction between the SMI and Entropy. In the last chapter, Entropy is derived as a special case of SMI. Ample examples are provided which help the reader in understanding the different concepts discussed in this book. As with previous books by the author, this book aims at a clear and mystery-free presentation of the central concept in Information theory — the Shannon's Measure of Information. This book presents the fundamental concepts of Information theory in a friendly-simple language and is devoid of all kinds of fancy and pompous statements made by authors of popular science books who write on this subject. It is unique in its presentation of Shannon's measure of information, and the clear distinction between this concept and the thermodynamic entropy. Although some mathematical knowledge is required by the reader, the emphasis is on the concepts and their meaning rather on the mathematical details of the theory.

Solvent-Induced Interactions and Forces in Protein Folding
Solvent-Induced Interactions and Forces in Protein Folding

Author: Arieh Ben-Naim

Publisher: Springer Nature

Published: 2023-06-12

Total Pages: 185

ISBN-13: 3031318714

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This monograph presents the molecular theory and necessary tools for the study of solvent-induced interactions and forces. After introducing the reader to the basic definitions of solvent-induced interactions, the author provides a brief analysis of the statistical thermodynamics. The book thoroughly overviews the connection of those interactions with thermodynamics and consequently focuses on specifically discussing the hydrophobic-hydrophilic interactions and forces. The importance of the implementation of hydrophilic interactions and forces in various biochemical processes is thoroughly analyzed, while evidence based on theory, experiments, and simulated calculations supporting that hydrophilic interactions and forces are far more important than the corresponding hydrophobic effects in many biochemical processes such as protein folding, self-assembly of proteins, molecular recognitions, are described in detail. This title is of great interest to students and researchers working in the fields of chemistry, physics, biochemistry, and molecular biology.

Hydrophobic Interactions
Hydrophobic Interactions

Author: Arieh Y. Ben-Naim

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 320

ISBN-13: 1468435450

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My personal involvement with the problem of hydrophobic interactions (HI) began about ten years ago. At that time I was asked to write a review article on the properties of aqueous solutions of nonpolar solutes. While surveying the literature on this subject I found numerous discussions of the concept of HI. My interest in these interactions increased especially after reading the now classical review of W. Kauzmann (1959), in which the importance of the HI to biochemical processes is stressed. Yet, in spite of having read quite extensively on the various aspects of the subject, I acquired only a very vague idea of what people actually had in mind when referring to HI. In fact, it became quite clear that the term HI was applied by different authors to describe and interpret quite different phenomena occurring in aqueous solutions. Thus, even the most fundamental question of the very definition of the concept of HI remained unanswered. But other questions followed, e. g. : Are HI really a well established experimental fact? Is there any relation between HI and the peculiar properties of water? Is the phenomenon really unique to aqueous solutions? Finally, perhaps the most crucial question I sought to answer was whether or not there exists hard evidence that HI are really important -as often claimed-in biological processes.

The Kirkwood-Buff Theory of Solutions
The Kirkwood-Buff Theory of Solutions

Author: Arieh Ben-Naim

Publisher: Elsevier

Published: 2023-10-01

Total Pages: 213

ISBN-13: 0443219168

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The Kirkwood-Buff Theory of Solutions: With Selected Applications to Solvation and Proteins presents the Kirkwood-Buff (KB) Theory of solution in a simple and didactic manner, making it understandable to those with minimal background in thermodynamics. Aside from the fact that the KB Theory may be the most important and useful theory of solutions, it is also the most general theory that can be applied to all possible solutions, including aqueous solutions of proteins and nucleic acids. Introductory chapters give readers grounding in the necessary chemical thermodynamics and statistical mechanics, but then move to a systematic derivation of Kirkwood-Buff theory and its inversion. Originally published in 1951, the KB theory was dormant for over 20 years. It became extremely useful after the publication of the "Inversion of the KB theory" by the author Arieh Ben-Naim in 1978. The book explains all necessary concepts in statistical mechanics featured in the theory in a simple and intuitive way. Researchers will find the theory useful in solving any problem in mixtures or solutions in any phase. Some examples of applications of the KB theory, to water, aqueous solutions, protein folding, and self-association of proteins, are provided in the book. - Presents an authoritative accounting of the Kirkwood-Buff (KB) Theory of solution as well as the derivation of the inversion of the Kirkwood-Buff Theory - Provides a grounding in the necessary chemical thermodynamics and statistical mechanics - Features useful examples of the applications of KB Theory to water, aqueous solutions, protein folding, and self-association of proteins - Written by world-renowned expert Arieh Ben-Naim, who himself developed the "inversion" of Kirkwood-Buff theory

Solvent Mixtures
Solvent Mixtures

Author: Yitzhak Marcus

Publisher: CRC Press

Published: 2002-09-10

Total Pages: 282

ISBN-13: 9780824708375

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Compiling, comparing, and analyzing research from a wide range of abstracts, journal articles, and Web sites, this reference examines the properties, function, and behavior of binary, ternary, and multicomponent mixtures in the presence and absence of solutes. The author uniformly presents extensive data on the properties of solvent mixtures and describes their structures and interactions. He details the impact of preferential solvation on the environment, action, and components of chemical systems. The book highlights experimental approaches to determine when, and to what extent, preferential solvation has taken place and models for organic, ionic, macromolecular, and biochemical solutes.

Information Theory and Selected Applications
Information Theory and Selected Applications

Author: Arieh Ben-Naim

Publisher: Springer Nature

Published: 2023-01-01

Total Pages: 242

ISBN-13: 3031212762

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This book focuses on analysing the applications of the Shannon Measure of Information (SMI). The book introduces the concept of frustration and discusses the question of the quantification of this concept within information theory (IT), while it also focuses on the interpretation of the entropy of systems of interacting particles in terms of the SMI and of mutual information. The author examines the question of the possibility of measuring the extent of frustration using mutual information and discusses some classical examples of processes of mixing and assimilation for which the entropy changes are interpreted in terms of SMI. A description of a few binding systems and the interpretation of cooperativity phenomena in terms of mutual information are also presented, along with a detailed discussion on the general method of using maximum SMI in order to find the “best-guess” probability distribution. This book is a valuable contribution to the field of information theory and will be of great interest to any scientist who is interested in IT and in its potential applications.

Statistical Thermodynamics for Chemists and Biochemists
Statistical Thermodynamics for Chemists and Biochemists

Author: Arieh Y. Ben-Naim

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 700

ISBN-13: 1475715986

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This book was planned and written with one central goal in mind: to demonstrate that statistical thermodynamics can be used successfully by a broad group of scientists, ranging from chemists through biochemists to biologists, who are not and do not intend to become specialists in statistical thermodynamics. The book is addressed mainly to gradu ate students and research scientists interested in designing experiments the results of which may be interpreted at the molecular level, or in interpreting such experimental results. It is not addressed to those who intend to practice statistical thermodynamics per se. With this goal in mind, I have expended a great deal of effort to make the book clear, readable, and, I hope, enjoyable. This does not necessarily mean that the book as a whole is easy to read. The first four chapters are very detailed. The last four become progressively more difficult to read, for several reasons. First, presuming that the reader has already acquired familiarity with the methods and arguments presented in the first part, I felt that similar arguments could be skipped later on, leaving the details to be filled in by the reader. Second, the systems themselves become progressively more com plicated as we proceed toward the last chapter.