Influence of Mixture Characteristics on the Oxidative Aging of Asphalt Binders

Influence of Mixture Characteristics on the Oxidative Aging of Asphalt Binders

Author: Nathaniel Evan Morian

Publisher:

Published: 2014

Total Pages: 1802

ISBN-13:

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The objective of this research effort focused on the evaluation of asphalt mixtures with respect to thermal cracking. Preliminary investigations soon indicated that a fundamental evaluation of thermal cracking was highly dependent upon the more complicated understanding of asphalt binder oxidation. The oxidation of asphalt binders within an asphalt mixture were understood to potentially be influenced by the mixture characteristics (i.e. air void levels, binder content, etc.) and aggregate properties (i.e. aggregate absorption, gradation, etc.). Therefore, this study was conducted in order to investigate and quantify the effects different aggregate sources and mixture properties may have on the oxidation and thermal cracking performance of asphalt mixtures. The investigation specifically focused on quantifying the oxidation of the asphalt binder alone and as part of the asphalt mixture when subjected to isothermal oven aging. The oxidation parameters of pan-aged asphalt binders were quantified, according to the standard of practice in the industry. These parameters were then compared to extracted and recovered mixture-aged asphalt binders to examine the influence of the main aggregate and mixture factors on the binder oxidation. The study observed differences between the pan-aged and mixture-aged asphalt binders in terms of oxidation kinetics, rheological measures, and the combined effect represented as the hardening susceptibility. Further evaluation of the binder oxidation based upon the dynamic modulus measures indicated marked influences of the mixture characteristics, the individual component materials, and the interactions between the investigated factors. Differentiation of the experimental factors was further identified by the newly developed low-temperature evaluation method, Uniaxial Thermal Stress and Strain Test (UTSST). The UTSST provides a fundamental approach to characterize the thermo-viscoelastic properties of asphalt mixtures permitting the pragmatic evaluation of changes in the stiffness and overall behavior of mixtures as a function of oxidative aging. Five distinct stages in the UTSST modulus were identified as thermo-viscoelastic properties, which are identified as a function of temperature: viscous softening, viscous-glassy transition, glassy hardening, crack initiation, and fracture stages. Through consideration of the thermo-viscoelastic properties, marked differences in the binder oxidation were noted between the experimental factors. Typically, decreases in the viscous response of the mixtures as well as increases in both the stiffness and brittle behavior were observed with aging. The evaluation method provides definitive measures to monitor multiple aspects of the performance of asphalt mixtures subjected to thermal loading.


Evaluation of Short Term Aging Effect of Hot Mix Asphalt Due to Elevated Temperatures and Extended Aging Time

Evaluation of Short Term Aging Effect of Hot Mix Asphalt Due to Elevated Temperatures and Extended Aging Time

Author: Rubben Lolly

Publisher:

Published: 2013

Total Pages: 97

ISBN-13:

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Heating of asphalt during production and construction causes the volatilization and oxidation of binders used in mixes. Volatilization and oxidation causes degradation of asphalt pavements by increasing the stiffness of the binders, increasing susceptibility to cracking and negatively affecting the functional and structural performance of the pavements. Degradation of asphalt binders by volatilization and oxidation due to high production temperature occur during early stages of pavement life and are known as Short Term Aging (STA). Elevated temperatures and increased exposure time to elevated temperatures causes increased STA of asphalt. The objective of this research was to investigate how elevated mixing temperatures and exposure time to elevated temperatures affect aging and stiffening of binders, thus influencing properties of the asphalt mixtures. The study was conducted in two stages. The first stage evaluated STA effect of asphalt binders. It involved aging two Performance Graded (PG) virgin asphalt binders, PG 76-16 and PG 64-22 at two different temperatures and durations, then measuring their viscosities. The second stage involved evaluating the effects of elevated STA temperature and time on properties of the asphalt mixtures. It involved STA of asphalt mixtures produced in the laboratory with the PG 64-22 binder at mixing temperatures elevated 25OF above standard practice; STA times at 2 and 4 hours longer than standard practices, and then compacted in a gyratory compactor. Dynamic modulus (E*) and Indirect Tensile Strength (IDT) were measured for the aged mixtures for each temperature and duration to determine the effect of different aging times and temperatures on the stiffness and fatigue properties of the aged asphalt mixtures. The binder test results showed that in all cases, there was increased viscosity. The results showed the highest increase in viscosity resulted from increased aging time. The results also indicated that PG 64-22 was more susceptible to elevated STA temperature and extended time than the PG 76-16 binders. The asphalt mixture test results confirmed the expected outcome that increasing the STA and mixing temperature by 25oF alters the stiffness of mixtures. Significant change in the dynamic modulus mostly occurred at four hour increase in STA time regardless of temperature.


Epoxy Polymers

Epoxy Polymers

Author: Jean-Pierre Pascault

Publisher: John Wiley & Sons

Published: 2009-12-09

Total Pages: 384

ISBN-13: 9783527628711

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In the only book to focus on new developments and innovations in this hot field international experts from industry and academia present everything scientists need to know. The first section provides general concepts of the synthesis and properties of epoxy polymers and serves as a basis for the subsequent chapters. The second section includes new types of epoxy polymers recently commercialized or not yet present on the market, while the third section includes chapters related to the capacity of generating controlled nanostructures in epoxy-based materials. A fourth section is devoted to innovations in epoxy-based materials such as adhesives, coatings, pre-pregs, structural foams, injection-molded products and self-healing epoxies. Concluding remarks and perspectives are discussed in a short final section. The result is a one-stop reference source, collecting scientific and technological breakthroughs otherwise spread over hundreds of publications, patents and reports.


Aging

Aging

Author: Chris A. Bell

Publisher:

Published: 1994

Total Pages: 104

ISBN-13:

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This research was conducted as part of the Strategic Highway Research Program (SHRP) A-003A contract at Oregon State University to validate the findings of SHRP contracts A-002A and A-003B with regard to aging. One short-term and four long-term aging methods were used to simulate aging of asphalt-aggregate mixes in the field. Four aggregates and eight asphalts for a total of 32 different material combinations were tested using the different aging methods. Results of the aging studies are compared with the A-002A and A-003B studies of asphalt binder or asphalt mixed with fine aggregate. This research concludes that aging of asphalt mixes cannot be predicted by tests on asphalt binder alone since results show that aggregates have considerable influence on aging.


The Effects of Asphalt Binder Oxidation on Hot Mix Asphalt Concrete Mixture Rheology and Fatigue Performance

The Effects of Asphalt Binder Oxidation on Hot Mix Asphalt Concrete Mixture Rheology and Fatigue Performance

Author: Sung Hoon Jung

Publisher:

Published: 2010

Total Pages:

ISBN-13:

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Asphalt oxidation causes major changes to binder properties and is hypothesized to be a major contributor to age-related pavement failure such as fatigue cracking. Extensive laboratory aging research has been done to assess the effects of oxidation on binder properties. Previous work shows binder oxidation makes the binder stiffer and more brittle, leading to higher binder stresses under a given deformation. Failure occurs when these stresses exceed the strength of the binder. However, binder oxidation in pavements has not been studied in the same detail as laboratory aging of neat binders. The impact of binder oxidation on long-term pavement performance has been either underestimated or ignored. This research includes studies of binder oxidation in Texas pavements to compare the field aging with laboratory neat binder aging, the impact of binder oxidation on HMAC mixture aging and HMAC mixture fatigue performance, and fundamental rheological property changes of the binder and the mixture. Binder oxidation is studied in fifteen pavements from locations across Texas. Results indicate that unmodified binders in pavements typically oxidize and harden to a degree that exceeds generally accepted pavement aging assumptions. This hardening may also extend much deeper into the pavement than has been previously assumed or documented. Data suggest that pavements can oxidize at rates surprisingly uniform with depth once early oxidation occurs, and that these rates continue for an extended time. Laboratory-aged HMAC mixtures and binders were tested and analyzed for fatigue resistance and their rheological properties. Mixture aging shows the same aging mechanisms as neat binder aging. Both binder and mixture have a higher modulus with aging and a good rheological correlation. The decline in mixture fatigue life (determined using the calibrated mechanistic fatigue analysis approach with surface energy measurement) due to oxidation is significant. Pavement service life is dependent on the mixture, but can be estimated by a cumulative damage approach that considers binder oxidation and pavement loading rate simultaneously. The differences in expected pavement life arise from differences in the rate of binder stiffening due to oxidation and the impact of this stiffening on the decline of fatigue life.