Presents thorough coverage of the transport properties of ions in gases. Starts from first principles, making this book useful to those new to the field as well as to experts. Describes the motions of ions in gases in electric fields, methods for measuring mobilities and diffusion coefficients, and pitfalls in measuring these quantities. Provides a detailed development of the theory of transport processes in the context of the kinetic theory of gases. Includes relevant experimental techniques and an index to experimental data.
This book offers extensive knowledge and practical guidance for readers working on non-equilibrium phenomena. The book can also serve as supplementary reference for a course of non-equilibrium statistical mechanics.
Over the last decade, scientific and engineering interests have been shifting from conventional ion mobility spectrometry (IMS) to field asymmetric waveform ion mobility spectrometry (FAIMS). Differential Ion Mobility Spectrometry: Nonlinear Ion Transport and Fundamentals of FAIMS explores this new analytical technology that separates and characterizes ions by the difference between their mobility in gases at high and low electric fields. It also covers the novel topics of higher-order differential IMS and IMS with alignment of dipole direction. The book relates the fundamentals of FAIMS and other nonlinear IMS methods to the physics of gas-phase ion transport. It begins with the basics of ion diffusion and mobility in gases, covering the main attributes of conventional IMS that are relevant to all IMS approaches. Building on this foundation, the author reviews diverse high-field transport phenomena that underlie differential IMS. He discusses the conceptual implementation and first-principles optimization of FAIMS as a filtering technique, emphasizing the dependence of FAIMS performance metrics on instrumental parameters and properties of ion species. He also explores ion reactions in FAIMS caused by field heating and the effects of inhomogeneous electric field in curved FAIMS gaps. Written by an accomplished scientist in the field, this state-of-the-art book supplies the foundation to understand the new technology of nonlinear IMS methods.
Our understanding of elementary processes in plasmas has been increasing dramatically over the last few years. The development of various swarm techniques, such as the temperature variable selected ion flow tube or the selected ion flow drift tube, has provided the prerequisite for detailed investigations into ion molecule reactions both in binary and three body collisions, and the mechanisms of many reactions are now understood quite satisfactorily. This information could not have been obtained without a detailed knowledge of the transport phenomena involved. Some of these, such as the internal-energy distribution of drifting ions, have only very recently been tackled both theoretically and experimentally; a consistent model is now being developed. As the interactions between the various branches of swarm research have become more and more intense, the most obvious thing to do was putting together a review on the present state of this subject, which is the aim of this book.
This volume contains the fourteen papers presented at the NATO-sponsored Ad vanced Research Workshop on the 'Status and Future Developments in the Study of Transport Properties' held in Porto Carras, Halkidiki, Greece from May 29 to May 31, 1991. The Workshop was organised to provide a forum for the discussion among prac titioners of the state-of-the-art in the treatment of the macroscopic, non-equilibrium properties of gases. The macroscopic quantities considered all arise as a result of the pairwise interactions of molecules in states perturbed from an equilibrium, Maxwellian distribution. The non-equilibrium properties of gases have been studied in detail for well over a century following the formulation of the Boltzmann equation in 1872. Since then the range of phenomena amenable to experimental study has expanded greatly from the properties characteristic of a bulk, non-uniform gas, such as the viscosity and thermal conductivity, to the study of differential scattering cross-sections in molecular beams at thermal energies, to studies of spectral-line widths of individual molecules and of Van der Waals complexes and even further. The common thread linking all of these studies is found in the corresponding theory which relates them all to the potential energy function describing the interaction of pairs of molecules. Thus, accompanying the experimental development there has been a corresponding improvement in the theoretical formulation of the quantities characterising the various phenomena.
This authoritative reference presents a comprehensive review of the evolution of plasma science and technology fundamentals over the past five decades. One of this field’s principal challenges has been its multidisciplinary nature requiring coverage of fundamental plasma physics in plasma generation, transport phenomena under high-temperature conditions, involving momentum, heat and mass transfer, and high-temperature reaction kinetics, as well as fundamentals of material science under extreme conditions. The book is structured in five distinct parts, which are presented in a reader-friendly format allowing for detailed coverage of the science base and engineering aspects of the technology including plasma generation, mathematical modeling, diagnostics, and industrial applications of thermal plasma technology. This book is an essential resource for practicing engineers, research scientists, and graduate students working in the field.
Describes the fundamentals and applications of gaseous radiation detection, ideal for researchers and experimentalists in nuclear and particle physics.
I Reactivity: E. Uggerud: Physical Organic Chemistry of the Gas Phase. Reactivity Trends for Organic Cations.- S. Petrie, D.K. Bohme: Mass Spectrometric Approaches to Interstellar Chemistry.- F. Turecek: Transient Intermediates of Chemical Reactions by Neutralization-Reionization Mass Spectrometry.- II Metalorganic Chemistry: D. Schröder, H. Schwarz: Diastereoselective Effects in Gas-Phase Ion Chemistry.- D.A. Plattner: Metalorganic Chemistry in the Gas Phase: Insight into Catalysis.- III Mass Spectrometric Methodology: T. Wyttenbach, M.T. Bowers: Gas-Phase Conformations: The Ion Mobility/Ion Chromatography Method.- P.B. Armentrout: Threshold Collision-Induced Dissociations for the Determination of Accurate Gas-Phase Binding Energies and Reaction Barriers.- IV Medicinal Chemistry: S.A. Trauger, T. Junker, G. Siuzdak: Investigating Viral Proteins and Intact Viruses with Mass Spectrometry M. Brönstrup: High-Throughput Mass Spectrometry for Compound Characterization in Drug Discovery.
This presentation describes various aspects of the regulation of tissue oxygenation, including the roles of the circulatory system, respiratory system, and blood, the carrier of oxygen within these components of the cardiorespiratory system. The respiratory system takes oxygen from the atmosphere and transports it by diffusion from the air in the alveoli to the blood flowing through the pulmonary capillaries. The cardiovascular system then moves the oxygenated blood from the heart to the microcirculation of the various organs by convection, where oxygen is released from hemoglobin in the red blood cells and moves to the parenchymal cells of each tissue by diffusion. Oxygen that has diffused into cells is then utilized in the mitochondria to produce adenosine triphosphate (ATP), the energy currency of all cells. The mitochondria are able to produce ATP until the oxygen tension or PO2 on the cell surface falls to a critical level of about 4–5 mm Hg. Thus, in order to meet the energetic needs of cells, it is important to maintain a continuous supply of oxygen to the mitochondria at or above the critical PO2 . In order to accomplish this desired outcome, the cardiorespiratory system, including the blood, must be capable of regulation to ensure survival of all tissues under a wide range of circumstances. The purpose of this presentation is to provide basic information about the operation and regulation of the cardiovascular and respiratory systems, as well as the properties of the blood and parenchymal cells, so that a fundamental understanding of the regulation of tissue oxygenation is achieved.
