Polymer Yearbook 13 brings together reviews and information on the progress of polymer science worldwide, including useful and topical information such as a list of new publications in polymer science and a compilation of dissertation abstracts. This volume includes reviews of key aspects of polymer science, including contributions from Russia, and details of important publications., This volume also contains reviews on state-of-the-art Japanese research presented at the annual Spring and Fall meetings of the Japanese Polymer Science Society. The aim of this section is to make information on the progress of Japanese polymer science, and on topics of current interest to polymer scientists in Japan, more easily available worldwide.
Polyvinyl chloride has played a key role in the development of the plastics industry over the past 40 years and continues to be a polymer of major importance. The reasons for its enormous versatility and range of application derive from a combination of the basic structure which gives rise to a relatively tough and rigid material and its ability to accept a range of plasticisers and other additives which can modify its physical characteristics to produce a range of flexible products. Two major problems, however, have tested the skill and ingenuity of PVC technologists since earliest times. One is the thermal instability of the material at the temperatures required for melt processing and fabrication, and the second is the photochemical instability which until recently has limited the potentially large range of outdoor applications. Both problems have been handled in a commercially satisfactory way by the gradual development of a range of stabilisers, lubricants and other processing aids and the high quality material which has resulted has led to massive utilisation of PVC by industry. Totally adequate stabilisation requires a detailed understanding of the mechanisms by which degradation processes are initiated and propagated. Although great advances have been made in this respect in recent years the problem remains incompletely understood. This book presents an account of the present position and the problems which remain to be solved.
A handbook on polyolefins. This second edition includes new material on the structure, morphology and properties of polyolefin (PO) synthesis. It focuses on synthetic advances, the use of additives, special coverage of PO blends, composites and fibres, and surface treatments. It also addresses the problem of interfacial and superficial phenomena.
Chemical modification of polymers by reactive modifiers is no longer an academic curiosity but a commercial reality that has delivered a diverse range of speciality materials for niche markets: reactively grafted styrenic alloys, maleated polyolefins, super-tough nylons, silane modified and moisture-cured polyolefins, and thermoplastic elastomers, are but few exam ples of commercial successes. Although the approach of reactive modification of polymers has been largely achieved either in solution or in the solid state (through in situ reactions in polymer melts), it is the latter route that has attracted most attention in the last two decades owing to its flexibility and cost-effective ness. This route, referred to as reactive processing, focuses on the use of suitable reactive modifier(s) and the adoption of conventional polymer processing machinery, an extruder or a mixer, as a chemical reactor, to perform in situ targeted reactions for chemical modification of preformed polymers. This relatively simple, though scientifically highly challenging, approach to reactive modification offers unique opportunities in exploiting various reactive modifiers for the purpose of altering and transforming in a controlled manner the properties of preformed commercial polymers into new/speciality materials with tailor-made properties and custom-designed performance for target applications. Such an economically attractive route constitutes a radical diversion away from the traditional practices of manufacturing new polymers from monomers which involves massive in vestments in sophisticated technologies and chemical plants.
This industrially relevant resource covers all established and emerging analytical methods for the deformulation of polymeric materials, with emphasis on the non-polymeric components. Each technique is evaluated on its technical and industrial merits. Emphasis is on understanding (principles and characteristics) and industrial applicability. Extensively illustrated throughout with over 200 figures, 400 tables, and 3,000 references.
This volume gives an analysis of recent achievements in the field of synthesis, structural investigations, and properties of polybutilene therephthalate (PBT). Furthermore, the mechanism of PBT synthesis by equilibrium polycondensation reaction is described together with the used reagents, catalysts, and stabilizers.
Materials in Conservation is the definitive introduction to the properties of materials used in conservation. The continual struggle of conservators to ameliorate the deterioration of objects has led to increasing use of synthetic polymers. These materials are part of the sophisticated technology that has been developed to augment and often replace traditional materials and methods. Conservators therefore have a wider range of techniques available. However, they must be able to appreciate the potentials and pitfalls of any proposed technique. The first section explains physical and chemical properties which are important in the conservation process, i.e. application, ageing, reversal. The topics covered include molecular weight, glass transition temperature, solubility and solvents, polymerisation and degradation reactions. The second section provides a detailed consideration of the individual materials, current and obsolete, used in conservation, drawing out the factors relevant to their effects on objects. The conservation uses of each material are summarised and referenced to allow further study. In five appendices, the properties of the polymers, solvents and their interactions are tabulated, with a list of suppliers and conversion table of physical units. IUPAC and SI nomenclature is used throughout the book. In this second edition, this classic text is revised and updated to include modern materials such as cyclododecane, and current ideas on adhesion, consolidation and reversibility, making Materials in Conservation the definitive source of vital information in the field. This handy reference book should be on the bench of every conservator and available wherever objects, from steam engines to dried plants, are preserved.
This volume gives an analysis of recent achievements in the field of synthesis, structural investigations, and properties of polybutilene therephthalate (PBT). Furthermore, the mechanism of PBT synthesis by equilibrium polycondensation reaction is described together with the used reagents, catalysts, and stabilizers.
