Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells

Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells

Author: Kentaro Ito

Publisher: John Wiley & Sons

Published: 2014-12-11

Total Pages: 449

ISBN-13: 1118437853

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Beginning with an overview and historical background of Copper Zinc Tin Sulphide (CZTS) technology, subsequent chapters cover properties of CZTS thin films, different preparation methods of CZTS thin films, a comparative study of CZTS and CIGS solar cell, computational approach, and future applications of CZTS thin film solar modules to both ground-mount and rooftop installation. The semiconducting compound (CZTS) is made up earth-abundant, low-cost and non-toxic elements, which make it an ideal candidate to replace Cu(In,Ga)Se2 (CIGS) and CdTe solar cells which face material scarcity and toxicity issues. The device performance of CZTS-based thin film solar cells has been steadily improving over the past 20 years, and they have now reached near commercial efficiency levels (10%). These achievements prove that CZTS-based solar cells have the potential to be used for large-scale deployment of photovoltaics. With contributions from leading researchers from academia and industry, many of these authors have contributed to the improvement of its efficiency, and have rich experience in preparing a variety of semiconducting thin films for solar cells.


Thin Film Solar Cells From Earth Abundant Materials

Thin Film Solar Cells From Earth Abundant Materials

Author: Subba Ramaiah Kodigala

Publisher: Newnes

Published: 2013-11-14

Total Pages: 197

ISBN-13: 0123971829

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The fundamental concept of the book is to explain how to make thin film solar cells from the abundant solar energy materials by low cost. The proper and optimized growth conditions are very essential while sandwiching thin films to make solar cell otherwise secondary phases play a role to undermine the working function of solar cells. The book illustrates growth and characterization of Cu2ZnSn(S1-xSex)4 thin film absorbers and their solar cells. The fabrication process of absorber layers by either vacuum or non-vacuum process is readily elaborated in the book, which helps for further development of cells. The characterization analyses such as XPS, XRD, SEM, AFM etc., lead to tailor the physical properties of the absorber layers to fit well for the solar cells. The role of secondary phases such as ZnS, Cu2-xS,SnS etc., which are determined by XPS, XRD or Raman, in the absorber layers is promptly discussed. The optical spectroscopy analysis, which finds band gap, optical constants of the films, is mentioned in the book. The electrical properties of the absorbers deal the influence of substrates, growth temperature, impurities, secondary phases etc. The low temperature I-V and C-V measurements of Cu2ZnSn(S1-xSex)4 thin film solar cells are clearly described. The solar cell parameters such as efficiency, fill factor, series resistance, parallel resistance provide handful information to understand the mechanism of physics of thin film solar cells in the book. The band structure, which supports to adjust interface states at the p-n junction of the solar cells is given. On the other hand the role of window layers with the solar cells is discussed. The simulation of theoretical efficiency of Cu2ZnSn(S1-xSex)4 thin film solar cells explains how much efficiency can be experimentally extracted from the cells. - One of the first books exploring how to conduct research on thin film solar cells, including reducing costs - Detailed instructions on conducting research


Reliability and Ecological Aspects of Photovoltaic Modules

Reliability and Ecological Aspects of Photovoltaic Modules

Author: Abdulkerim Gok

Publisher: BoD – Books on Demand

Published: 2020-01-08

Total Pages: 171

ISBN-13: 1789848229

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Photovoltaic (PV) solar energy is expected to be the world's largest source of electricity in the future. To enhance the long-term reliability of PV modules, a thorough understanding of failure mechanisms is of vital importance. In addition, it is important to address the potential downsides to this technology. These include the hazardous chemicals needed for manufacturing solar cells, especially for thin-film technologies, and the large number of PV modules disposed of at the end of their lifecycles. This book discusses the reliability and environmental aspects of PV modules.


Earth-Abundant Materials for Solar Cells

Earth-Abundant Materials for Solar Cells

Author: Sadao Adachi

Publisher: John Wiley & Sons

Published: 2015-10-28

Total Pages: 480

ISBN-13: 1119052831

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Systematically describes the physical and materials properties of copper-based quaternary chalcogenide semiconductor materials, enabling their potential for photovoltaic device applications. Intended for scientists and engineers, in particular, in the fields of multinary semiconductor physics and a variety of photovoltaic and optoelectronic devices.


Copper Zinc Tin Sulfide Thin Films for Photovoltaics

Copper Zinc Tin Sulfide Thin Films for Photovoltaics

Author: Jonathan J. Scragg

Publisher: Springer Science & Business Media

Published: 2011-09-01

Total Pages: 220

ISBN-13: 3642229190

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Jonathan Scragg documents his work on a very promising material suitable for use in solar cells. Copper Zinc Tin Sulfide (CZTS) is a low cost, earth-abundant material suitable for large scale deployment in photovoltaics. Jonathan pioneered and optimized a low cost route to this material involving electroplating of the three metals concerned, followed by rapid thermal processing (RTP) in sulfur vapour. His beautifully detailed RTP studies – combined with techniques such as XRD, EDX and Raman – reveal the complex relationships between composition, processing and photovoltaic performance. This exceptional thesis contributes to the development of clean, sustainable and alternative sources of energy


Semiconductor Materials for Solar Photovoltaic Cells

Semiconductor Materials for Solar Photovoltaic Cells

Author: M. Parans Paranthaman

Publisher: Springer

Published: 2015-09-16

Total Pages: 290

ISBN-13: 3319203312

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This book reviews the current status of semiconductor materials for conversion of sunlight to electricity, and highlights advances in both basic science and manufacturing. Photovoltaic (PV) solar electric technology will be a significant contributor to world energy supplies when reliable, efficient PV power products are manufactured in large volumes at low cost. Expert chapters cover the full range of semiconductor materials for solar-to-electricity conversion, from crystalline silicon and amorphous silicon to cadmium telluride, copper indium gallium sulfide selenides, dye sensitized solar cells, organic solar cells, and environmentally friendly copper zinc tin sulfide selenides. The latest methods for synthesis and characterization of solar cell materials are described, together with techniques for measuring solar cell efficiency. Semiconductor Materials for Solar Photovoltaic Cells presents the current state of the art as well as key details about future strategies to increase the efficiency and reduce costs, with particular focus on how to reduce the gap between laboratory scale efficiency and commercial module efficiency. This book will aid materials scientists and engineers in identifying research priorities to fulfill energy needs, and will also enable researchers to understand novel semiconductor materials that are emerging in the solar market. This integrated approach also gives science and engineering students a sense of the excitement and relevance of materials science in the development of novel semiconductor materials. · Provides a comprehensive introduction to solar PV cell materials · Reviews current and future status of solar cells with respect to cost and efficiency · Covers the full range of solar cell materials, from silicon and thin films to dye sensitized and organic solar cells · Offers an in-depth account of the semiconductor material strategies and directions for further research · Features detailed tables on the world leaders in efficiency demonstrations · Edited by scientists with experience in both research and industry


Thin Film Solar Cells

Thin Film Solar Cells

Author: Jef Poortmans

Publisher: John Wiley & Sons

Published: 2006-10-16

Total Pages: 504

ISBN-13: 0470091266

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Thin-film solar cells are either emerging or about to emerge from the research laboratory to become commercially available devices finding practical various applications. Currently no textbook outlining the basic theoretical background, methods of fabrication and applications currently exist. Thus, this book aims to present for the first time an in-depth overview of this topic covering a broad range of thin-film solar cell technologies including both organic and inorganic materials, presented in a systematic fashion, by the scientific leaders in the respective domains. It covers a broad range of related topics, from physical principles to design, fabrication, characterization, and applications of novel photovoltaic devices.


Fabrication and Characterization of Low Cost Solar Cells based on Earth Abundant Materials for Sustainable Photovoltaics

Fabrication and Characterization of Low Cost Solar Cells based on Earth Abundant Materials for Sustainable Photovoltaics

Author: Mahmoud Abdelfatah

Publisher: Cuvillier Verlag

Published: 2016-07-08

Total Pages: 130

ISBN-13: 3736982968

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The low cost and low temperature electrochemical deposition technique was employed to grow Cu2O thin films and ZnO:Al thin films were deposited by d.c. magnetron sputtering in order to fabricate solar cells. The potentiostatic and galvanostatic electrodeposition modes were used to deposit the Cu2O thin films. Raman spectra of thin films have shown characteristic frequencies of crystalline Cu2O. The contact between Cu2O and Au is found to be an Ohmic contact. The devices grown by a potentiostatic mode have higher efficiency than those grown by a galvanostatic mode. The optimum thickness of Cu2O thin films as an absorber layer in solar cells. was found to be around 3 µm respect to a high efficiency. Flexible and light weight solar cell was fabricated on plastic substrate.


Solar Cells and Modules

Solar Cells and Modules

Author: Arvind Shah

Publisher: Springer Nature

Published: 2020-07-16

Total Pages: 357

ISBN-13: 3030464873

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This book gives a comprehensive introduction to the field of photovoltaic (PV) solar cells and modules. In thirteen chapters, it addresses a wide range of topics including the spectrum of light received by PV devices, the basic functioning of a solar cell, and the physical factors limiting the efficiency of solar cells. It places particular emphasis on crystalline silicon solar cells and modules, which constitute today more than 90 % of all modules sold worldwide. Describing in great detail both the manufacturing process and resulting module performance, the book also touches on the newest developments in this sector, such as Tunnel Oxide Passivated Contact (TOPCON) and heterojunction modules, while dedicating a major chapter to general questions of module design and fabrication. Overall, it presents the essential theoretical and practical concepts of PV solar cells and modules in an easy-to-understand manner and discusses current challenges facing the global research and development community.


Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells

Copper Zinc Tin Sulfide-Based Thin-Film Solar Cells

Author: Kentaro Ito

Publisher: John Wiley & Sons

Published: 2015-02-23

Total Pages: 449

ISBN-13: 111843787X

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Beginning with an overview and historical background of Copper Zinc Tin Sulphide (CZTS) technology, subsequent chapters cover properties of CZTS thin films, different preparation methods of CZTS thin films, a comparative study of CZTS and CIGS solar cell, computational approach, and future applications of CZTS thin film solar modules to both ground-mount and rooftop installation. The semiconducting compound (CZTS) is made up earth-abundant, low-cost and non-toxic elements, which make it an ideal candidate to replace Cu(In,Ga)Se2 (CIGS) and CdTe solar cells which face material scarcity and toxicity issues. The device performance of CZTS-based thin film solar cells has been steadily improving over the past 20 years, and they have now reached near commercial efficiency levels (10%). These achievements prove that CZTS-based solar cells have the potential to be used for large-scale deployment of photovoltaics. With contributions from leading researchers from academia and industry, many of these authors have contributed to the improvement of its efficiency, and have rich experience in preparing a variety of semiconducting thin films for solar cells.