Thermodynamics of the System Uranium-oxygen
Author: Carl Wagner
Publisher:
Published: 1955
Total Pages: 40
ISBN-13:
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Author: Carl Wagner
Publisher:
Published: 1955
Total Pages: 40
ISBN-13:
DOWNLOAD EBOOKAuthor: Stanley Abramowitz
Publisher:
Published: 1975
Total Pages: 30
ISBN-13:
DOWNLOAD EBOOKThe vapor pressure data for the uranium-oxygen and thorium-oxygen systems have been reviewed. Free energies of formation for the species UO, UO2, ThO, and ThO2 have been chosen. Tables of thermodynamic functions for these species are presented.
Author: K. Q. Bagley
Publisher:
Published: 1959
Total Pages:
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DOWNLOAD EBOOKAuthor: H. R. Hoekstra
Publisher:
Published: 1950
Total Pages: 10
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DOWNLOAD EBOOKAuthor: C. F. Miller
Publisher:
Published: 1961
Total Pages: 72
ISBN-13:
DOWNLOAD EBOOKAuthor: A. Pattoret
Publisher:
Published: 1966
Total Pages: 30
ISBN-13:
DOWNLOAD EBOOKAuthor: C. Ronchi
Publisher: Springer Science & Business Media
Published: 2011-06-27
Total Pages: 361
ISBN-13: 3642186033
DOWNLOAD EBOOKIn the beginning of the 1990’s, in the course of the events which were rapidly cha- ing the political con?guration of the East European countries, the crisis which - vested the vast research apparatus of the former Soviet Union was entailing con- quences whose dimension and depth were immediately realized by the international scienti?c community. In the same years, however, the most important branch of nuclear energy - searchanddevelopment,inparticularthatconcerning?ssionreactor,wasworldwide undergoing a substantial reduction due to a variety of decisional situations. Yet, paradoxically, it was a very good fortune that a number of concerns on the future of nuclear research were shared by East- and West-European scientists, especially those who were working in advanced ?elds. In fact, the only hope for coping with an uncertain future was to erect bridges between similar institutions and employ safeguarding tactics linked to a long term collaboration strategy. A decade later, this proved to be a winning decision, since the revival of nuclear energy is presently starting from a basis of common intentions and a network of established cooperation, whose seeds are to be searched in those initial, individual e?orts.
Author: Ingmar Grenthe
Publisher: Elsevier Science & Technology
Published: 1992
Total Pages: 744
ISBN-13:
DOWNLOAD EBOOKThis volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
Author: Jacob Wesley McMurray
Publisher:
Published: 2014
Total Pages: 216
ISBN-13:
DOWNLOAD EBOOKThe CALPHAD method is used to assess the thermodynamic properties and phase relations in the U-M-O system where M = Gd, La, and Th. A compound energy formalism (CEF) model for fluorite UO2±x̳ [urania] is extended to represent the complex U1−y̳̳My̳O2±x̳ [urania solid solution] phases. The lattice stabilities for fictive GdO2 [gadolinia] and LaO2 [lanthana] fluorite structure compounds are calculated from density functional theory (DFT) for use in the CEF for U1−y̳̳My̳O2±x̳ [urania solid solution phase] while U6+ [uranium 6 plus cation] is introduced into the cation sublattice of the CEF for U1−y̳̳My̳O2±x̳ [urania solid solution phase] to better reproduce phase relations in U-Ln-O systems at high fixed trivalent Ln [lanthanide] compositions. Tentative Gibbs functions and CEF representations for the fluorite derivative rhombohedral phases were developed and the two-sublattice liquid model (TSLM) was used to describe the melt. Equilibrium oxygen pressures over U1−y̳̳Thy̳O2±x̳ [urania thoria solid solution] were obtained from thermogravimetric measurements and used together with those reported in the literature, phase relations, and other experimentally determined thermodynamic values to fit adjustable parameters of the CEF and TSLM along with the standard state enthalpy and entropy of the Gibbs functions representing the stoichiometric compounds. The models can be extended to include other actinides and fission products to develop higher order multi-component system assessments to support further experimental efforts and the development of multi-physics fuel performance simulation codes.
Author:
Publisher:
Published: 1945
Total Pages: 86
ISBN-13:
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