Thermodynamic Properties of Nonelectrolyte Solutions
Thermodynamic Properties of Nonelectrolyte Solutions

Author: William Acree

Publisher: Academic Press

Published: 2012-12-02

Total Pages: 319

ISBN-13: 032314067X

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Thermodynamic Properties of Nonelectrolyte Solutions reviews several of the more classical theories on the thermodynamics of nonelectrolyte solutions. Basic thermodynamic principles are discussed, along with predictive methods and molecular thermodynamics. This book is comprised of 12 chapters; the first of which introduces the reader to mathematical relationships, such as concentration variables, homogeneous functions, Euler’s theorem, exact differentials, and method of least squares. The discussion then turns to partial molar quantities, ideal and nonideal solutions, and empirical expressions for predicting the thermodynamic properties of multicomponent mixtures from binary data. The chapters that follow explore binary and ternary mixtures containing only nonspecific interactions; the thermodynamic excess properties of liquid mixtures and ternary alcohol-hydrocarbon systems; and solubility behavior of nonelectrolytes. This book concludes with a chapter describing the use of gas-liquid chromatography in determining the activity coefficients of liquid mixtures and mixed virial coefficients of gaseous mixtures. This text is intended primarily for professional chemists and researchers, and is invaluable to students in chemistry or chemical engineering who have background in physical chemistry and classical thermodynamics.

Liquids and Liquid Mixtures
Liquids and Liquid Mixtures

Author: J S Rowlinson

Publisher: Butterworth-Heinemann

Published: 2013-09-03

Total Pages: 337

ISBN-13: 1483140679

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Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.

The Thermophysical Properties of Binary Organic Liquid Mixtures
The Thermophysical Properties of Binary Organic Liquid Mixtures

Author: Gandi Chandra Sekhar

Publisher: LAP Lambert Academic Publishing

Published: 2014-11-13

Total Pages: 276

ISBN-13: 9783659628788

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Thermodynamic and physical properties of pure liquids and liquid mixtures have a lot of importance and interest to both Chemists and Chemical Engineers, from different angles in terms of their applications. The thermodynamic and physical properties help one i. to interpret, correlate and predict thermodynamic properties of mixtures through molecular thermodynamic considerations, ii. to find the applicability of theories of liquids and to predict the properties of mixtures of similar nature and iii. to design the industrial equipment with better precision, thus reducing the capital costs. The excess thermodynamic properties are extensively used to study the deviation of a real liquid mixture from ideality. Thermodynamically an ideal solution is one which obeys the generalized form of Raoult's law defined in terms of fugacities. According to this law the fugacity, fi of any component is equal to its mole fraction xi multiplied by its fugacity in the pure state.This book is useful to those wish to do research in Chemistry and Chemical engineering .This book broadly contains research activity of Excess volumes, Excess enthalpies, Solid-liquid equilibria and sound velocities

Binary Liquid Systems of Nonelectrolytes II
Binary Liquid Systems of Nonelectrolytes II

Author: Ivan Cibulka

Publisher: Springer

Published: 2012-01-18

Total Pages: 0

ISBN-13: 9783642232763

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Vapor-liquid equilibrium data, heat of mixing (excess enthalpies), and volumetric properties of systems are required for both the applications in design of industrial technological processes and the understanding the structure and the intermolecular interactions in the systems. On the basis of classical thermodynamics the measured experimental data combined together enable us the calculation of non-measurable thermodynamic properties significant for the technological calculations. The present volume is a compilation of experimental and derived property data on subcritical binary homogeneous (single-phase) or heterogeneous (two-phase) liquid–liquid mixtures. All the components are well-defined pure substances, which are organic nonelectrolytes and water. The present volume is divided into three subvolumes (A, B, C). 800 representative data sets that cover all types of properties and chemical systems are selected for Subvolume A. While Subvolume B comprises 1032 data sets for binary mixtures containing one or two hydrocarbons, Subvolume C is providing 1014 data sets for non-hydrocarbon binary mixtures.

Thermophysical Properties of Binary Liquid Mixtures
Thermophysical Properties of Binary Liquid Mixtures

Author: Golamari Siva Reddy

Publisher: LAP Lambert Academic Publishing

Published: 2014-11-19

Total Pages: 116

ISBN-13: 9783659637322

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This book, "Thermophysical Properties of Binary Liquid Mixtures" is a compilation of principles and applications related to the field of chemical, petroleum and bioprocess engineering. In this book the authors made a tremendous effort to summarize in detail the theoretical and practical approaches towards the understanding and study of the "transport and physical properties of binary liquid mixtures." This book is suitable for students pursuing Bachelor's or Master's in the earlier mentioned areas. This book also provides insights into the applicative aspects of manufacturing of mass transfer equipments, solution thermodynamics, petroleum refining process and molecular thermodynamics.