Recent years have seen a growing interest in the field of thermodynamic properties of solids due to the development of advanced experimental and modeling tools. Predicting structural phase transitions and thermodynamic properties find important applications in condensed matter and materials science research, as well as in interdisciplinary research involving geophysics and Earth Sciences. The present edited book, with contributions from leading researchers around the world, is aimed to meet the need of academic and industrial researchers, graduate students and non-specialists working in these fields. The book covers various experimental and theoretical techniques relevant to the subject.
Thermal Analysis and Thermodynamic Properties of Solids, Second Edition covers foundational principles and recent updates in the field, presenting an authoritative overview of theoretical knowledge and practical applications across several fields. Since the first edition of this book was published, large developments have occurred in the theoretical understanding of—and subsequent ability to assess and apply—principles of thermal analysis. Drawing on the knowledge of its expert author, this second edition provides fascinating insight for both new and experienced students, researchers, and industry professionals whose work is influenced or impacted by thermo analysis principles and tools. Part 1 provides a detailed introduction and guide to theoretical aspects of thermal analysis and the related impact of thermodynamics. Key terminology and concepts, the fundamentals of thermophysical examinations, thermostatics, equilibrium background, thermotics, reaction kinetics and models, thermokinetics and the exploitation of fractals are all discussed. Part 2 then goes on to discuss practical applications of this theoretical information to topics such as crystallization kinetics and glass states, thermodynamics in superconductor models, and climate change. Includes fully updated as well as new chapters on kinetic phase diagrams, thermokinetics in DTA experiments, and crystallization kinetics Discusses the influence of key derivatives such as thermostatics, thermodynamics, thermotics, and thermokinetics Helps readers understand and describe reaction kinetics in solids, both in terms of simplified descriptions of the reaction mechanism models and averaged descriptions using fractals
The minimum temperature in the natural universe is 2.7 K. Laboratory refrigerators can reach temperatures in the microkelvin range. Modern industrial refrigerators cool foods at 200 K, whereas space mission payloads must be capable of working at temperatures as low as 20 K. Superconducting magnets used for NMR work at 4.2 K. Hence the properties of materials must be accurately known also at cryogenic temperatures. This book provides a guide for engineers, physicists, chemists, technicians who wish to approach the field of low-temperature material properties. The focus is on the thermal properties and a large spectrum of experimental cases is reported. The book presents updated tables of low-temperature data on materials and a thorough bibliography supplements any further research. Key Features include: ° Detailed technical description of experiments ° Description of the newest cryogenic apparatus ° Offers data on cryogenic properties of the latest new materials ° Current reference review
This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories—as well as integral equation theories and density functional theories—for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.
This 1980 monograph develops from first principles the description of finite deformations of solids under stress and the forces acting, and also the expression of internal forces in terms of stress tensors. The important feature of the book is that elastic properties are discussed and developed consistently from classical thermodynamics. In other books, this point of view is acknowledged only by assuming the existence of an elastic energy function, thus restricting their range mainly to the problem of the spatial distribution of stresses and strains. Topics discussed as applications of the theory include thermal expansion, specific heats, stiffness and complicances, the effects of symmetry on thermodynamic properties, diffusion in a stressed solid, equilibrium in contact with a solution of the solid, phase stability, solid state phase transitions and twinning.
This is a thoroughly revised version of the original book published in 1986. About half of the contents of the previous version remain essentially unchanged, and one quarter has been rewritten and updated. The rest consists of completely new and extended material. Recent research has focussed on new materials made through "molecular engineering", and computational materials science through ab initio electron structure calculations. Another trend is the ever growing interdisciplinary aspect of both basic and applied materials science. There is an obvious need for reviews that link well established results to the modern approaches. One purpose of this book is to provide such an overview in a specific field of materials science, namely thermophysical phenomena that are intimately connected with the lattice vibrations of solids. This includes, e.g., elastic properties and electrical and thermal transport. Furthermore, this book attempts to present the results in such a form that the reader can clearly see their domain of applicability, for instance if and how they depend on crystal structure, defects, applied pressure, crystal anisotropy etc. The level and presentation is such that the results can be immediately used in research. Graduate students in condensed matter physics, metallurgy, inorganic chemistry or geophysical materials will benefit from this book as will theoretical physicists and scientists in industrial research laboratories.
Must-have reference for processes involving liquids, gases, and mixtures Reap the time-saving, mistake-avoiding benefits enjoyed by thousands of chemical and process design engineers, research scientists, and educators. Properties of Gases and Liquids, Fifth Edition, is an all-inclusive, critical survey of the most reliable estimating methods in use today --now completely rewritten and reorganized by Bruce Poling, John Prausnitz, and John O’Connell to reflect every late-breaking development. You get on-the-spot information for estimating both physical and thermodynamic properties in the absence of experimental data with this property data bank of 600+ compound constants. Bridge the gap between theory and practice with this trusted, irreplaceable, and expert-authored expert guide -- the only book that includes a critical analysis of existing methods as well as hands-on practical recommendations. Areas covered include pure component constants; thermodynamic properties of ideal gases, pure components and mixtures; pressure-volume-temperature relationships; vapor pressures and enthalpies of vaporization of pure fluids; fluid phase equilibria in multicomponent systems; viscosity; thermal conductivity;diffusion coefficients; and surface tension.
