Liquids and Liquid Mixtures
Liquids and Liquid Mixtures

Author: J S Rowlinson

Publisher: Butterworth-Heinemann

Published: 2013-09-03

Total Pages: 337

ISBN-13: 1483140679

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Liquids and Liquid Mixtures, Third Edition explores the equilibrium properties of liquids and liquid mixtures and relates them to the properties of the constituent molecules using the methods of statistical thermodynamics. Topics covered include the critical state, fluid mixtures at high pressures, and the statistical thermodynamics of fluids and mixtures. This book consists of eight chapters and begins with an overview of the liquid state and the thermodynamic properties of liquids and liquid mixtures, including vapor pressure and heat capacities. The discussion then turns to the thermodynamics of and inequalities at the critical point; measurement of thermodynamic functions in the critical region; experimental values of the critical exponents; and scaling of the free energy. The change of thermodynamic functions with composition is the subject of the next two chapters, followed by an analysis of fluid mixtures at high pressures. The final chapter is devoted to the statistical thermodynamics of fluids and mixtures, paying particular attention to the thermodynamic properties in terms of the forces between the molecules; the balance of intermolecular potentials between like and unlike molecules; and phase behavior. This monograph will be of interest to students and researchers in the fields of chemistry and chemical engineering.

Liquid State VIIIB
Liquid State VIIIB

Author: Douglas Henderson

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 503

ISBN-13: 0323147992

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Physical Chemistry: An Advanced Treatise: Liquid State, Volume VIIIB, deals with simple liquids because the theory is most developed for these liquids. The purpose of this treatise is to present a comprehensive treatment of physical chemistry for advanced students and investigators in a reasonably small number of volumes. An attempt has been made to include all important topics in physical chemistry together with borderline subjects which are of particular interest and importance. The book contains five chapters and begins with a discussion of various theories of mixtures, focusing on binary mixtures of simple, spherical molecules. This is followed by separate chapters on the properties of liquid helium; time-dependent correlation functions; theory of static critical phenomena; and progress in understanding the behavior of transport coefficients near the liquid-gas critical point.

Variational Methods in Molecular Modeling
Variational Methods in Molecular Modeling

Author: Jianzhong Wu

Publisher: Springer

Published: 2016-12-17

Total Pages: 331

ISBN-13: 9811025029

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This book presents tutorial overviews for many applications of variational methods to molecular modeling. Topics discussed include the Gibbs-Bogoliubov-Feynman variational principle, square-gradient models, classical density functional theories, self-consistent-field theories, phase-field methods, Ginzburg-Landau and Helfrich-type phenomenological models, dynamical density functional theory, and variational Monte Carlo methods. Illustrative examples are given to facilitate understanding of the basic concepts and quantitative prediction of the properties and rich behavior of diverse many-body systems ranging from inhomogeneous fluids, electrolytes and ionic liquids in micropores, colloidal dispersions, liquid crystals, polymer blends, lipid membranes, microemulsions, magnetic materials and high-temperature superconductors. All chapters are written by leading experts in the field and illustrated with tutorial examples for their practical applications to specific subjects. With emphasis placed on physical understanding rather than on rigorous mathematical derivations, the content is accessible to graduate students and researchers in the broad areas of materials science and engineering, chemistry, chemical and biomolecular engineering, applied mathematics, condensed-matter physics, without specific training in theoretical physics or calculus of variations.

Classical and Molecular Thermodynamics of Fluid Systems
Classical and Molecular Thermodynamics of Fluid Systems

Author: Juan H. Vera

Publisher: CRC Press

Published: 2024-11-14

Total Pages: 564

ISBN-13: 1040132774

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This text explores the connections between different thermodynamic subjects related to fluid systems. In an innovative way, it covers the subject from first principles to the state of the art in fundamental and applied topics. Using simple nomenclature and algebra, it clarifies concepts by returning to the conceptual foundation of thermodynamics. The structural elements of classical and molecular thermodynamics of fluid systems presented cover, via examples and references, both the usefulness and the limitations of thermodynamics for the treatment of practical problems. This new edition explores recent advances in statistical associated fluid theories and contains creative end‐of‐chapter problems connecting the theory with real‐life situations. It includes new chapters on thermodynamics of polymer solutions and molecular thermodynamics and also presents advances in the study of the activity of individual ions. Provides a concise structure of concepts, using simple nomenclature and algebra Clarifies problems usually overlooked by standard texts Features end‐of‐chapter problems to enhance the reader’s understanding of the concepts Includes diverse topics of interest to researchers and advanced students, including elements of statistical thermodynamics, models of solutions, statistical associated fluid theory and the activity of individual ions Offers four appendices giving step‐by‐step procedures and parameters for direct use of the PRSV equation of state and the ASOG‐KT group method for fugacity and activity coefficient calculations Features a complete set of solutions to problems throughout the book, available for download on the book’s webpage under "Support Material" This textbook is written for advanced undergraduate and graduate students studying chemical engineering and chemistry as well as for practicing engineers and researchers.

Fundamentals of Inhomogeneous Fluids
Fundamentals of Inhomogeneous Fluids

Author: Douglas Henderson

Publisher: CRC Press

Published: 2021-12-17

Total Pages: 624

ISBN-13: 1000148041

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A monograph examining recent progress in the field of inhomogeneous fluids, focusing on the theoretical - as well as experimental - techniques used. It presents the comprehensive theory of first-order phase transitions, including melting, and contains numerous figures, tables and display equations.;The contributors treat such subjects as: exact sum rules for inhomogenous fluids, explaining density functional and integral equation methods; exact solutions for two-dimensional homogeneous and inhomogeneous plasmas; current advances in the theory of interfacial electrochemistry; wetting experiments and the theory of wetting; freezing, with an emphasis on quantum systems and homogeneous nucleation in liquid-vapour and solid-liquid transitions; self-organizing liquids as well as kinetic phenomena in inhomogeneous fluids, using a modified Enskog theory.;Featuring over 1000 bibliographic citations, this volume is aimed at physical, surface, colloid and surfactant chemists; also physicists, electrochemists and graduate-level students in these disciplines.

Perturbation Theories for the Thermodynamic Properties of Fluids and Solids
Perturbation Theories for the Thermodynamic Properties of Fluids and Solids

Author: J. R. Solana

Publisher: CRC Press

Published: 2013-03-22

Total Pages: 408

ISBN-13: 1439807752

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This book, Perturbation Theories for the Thermodynamic Properties of Fluids and Solids, provides a comprehensive review of current perturbation theories—as well as integral equation theories and density functional theories—for the equilibrium thermodynamic and structural properties of classical systems. Emphasizing practical applications, the text avoids complex theoretical derivations as much as possible. It begins with discussions of the nature of intermolecular forces and simple potential models. The book also presents a summary of statistical mechanics concepts and formulae. In addition, it reviews simulation techniques, providing background for the performance analyses of theories executed throughout the text using simulation data. Chapters describe integral equation theories, theoretical approaches for hard-sphere fluid or solid systems, and perturbation theories for simple fluids and solids for monocomponent and multicomponent systems. They also cover density functional theories for inhomogeneous systems and perturbative and nonperturbative approaches to describe the structure and thermodynamics of hard-body molecular fluids. The final chapter examines several more challenging systems, such as fluids near the critical point, liquid metals, molten salts, colloids, and aqueous protein solutions. This book offers a thorough account of the available equilibrium theories for the thermodynamic and structural properties of fluids and solids, with special focus on perturbation theories, emphasizing their applications, strengths, and weaknesses. Appropriate for experienced researchers as well as postgraduate students, the text presents a wide-ranging yet detailed view and provides a useful guide to the application of the theories described.

Critical Phenomena in Liquids and Liquid Crystals
Critical Phenomena in Liquids and Liquid Crystals

Author: Mikhail Alekseevich Anisimov

Publisher: CRC Press

Published: 1991

Total Pages: 452

ISBN-13: 9782881248061

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Phase transitions and critical phenomena in liquids and liquid crystals have been the subject of intensive research since the 1960s. However, books on this fascinating subject have tended to be written by theorists for theorists. Professor Anisimov offers us a new approach: he aims to introduce experimentalists to the modern theories and their applications. After introducing the thermodynamics of phase transitions, he presents the modern theory of critical phenomena. He then concludes by illustrating the utility of this theory in the analysis of experimental measurements in classical fluids and binary mixtures, superfluid mixtures of helium isotopes and liquid crystals. Not only will this book be enjoyed by experimental physicists, chemists and material scientists, it will also offer the theorist an insight into the interpretation of the experimentalist's work.

Fundamentals of Inhomogeneous Fluids
Fundamentals of Inhomogeneous Fluids

Author: Douglas Henderson

Publisher: CRC Press

Published: 1992-08-28

Total Pages: 624

ISBN-13: 9780824787110

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A monograph examining recent progress in the field of inhomogeneous fluids, focusing on the theoretical - as well as experimental - techniques used. It presents the comprehensive theory of first-order phase transitions, including melting, and contains numerous figures, tables and display equations.;The contributors treat such subjects as: exact sum rules for inhomogenous fluids, explaining density functional and integral equation methods; exact solutions for two-dimensional homogeneous and inhomogeneous plasmas; current advances in the theory of interfacial electrochemistry; wetting experiments and the theory of wetting; freezing, with an emphasis on quantum systems and homogeneous nucleation in liquid-vapour and solid-liquid transitions; self-organizing liquids as well as kinetic phenomena in inhomogeneous fluids, using a modified Enskog theory.;Featuring over 1000 bibliographic citations, this volume is aimed at physical, surface, colloid and surfactant chemists; also physicists, electrochemists and graduate-level students in these disciplines.

Hamilton’s Principle in Continuum Mechanics
Hamilton’s Principle in Continuum Mechanics

Author: Anthony Bedford

Publisher: Springer Nature

Published: 2021-12-14

Total Pages: 114

ISBN-13: 3030903060

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This revised, updated edition provides a comprehensive and rigorous description of the application of Hamilton’s principle to continuous media. To introduce terminology and initial concepts, it begins with what is called the first problem of the calculus of variations. For both historical and pedagogical reasons, it first discusses the application of the principle to systems of particles, including conservative and non-conservative systems and systems with constraints. The foundations of mechanics of continua are introduced in the context of inner product spaces. With this basis, the application of Hamilton’s principle to the classical theories of fluid and solid mechanics are covered. Then recent developments are described, including materials with microstructure, mixtures, and continua with singular surfaces.