The Synthetic Use of Metals in Organic Chemistry

The Synthetic Use of Metals in Organic Chemistry

Author: Arthur James Hale

Publisher: Forgotten Books

Published: 2015-06-26

Total Pages: 184

ISBN-13: 9781330419922

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Excerpt from The Synthetic Use of Metals in Organic Chemistry The student of Organic Chemistry will probably be impressed at an early stage with the importance of metallic sodium and its compounds in synthetic work, and will subsequently mark the value of such substances as acetoacetic-, malonic-, and cyanacetic-ester and their sodium compounds. He will notice the use of aluminium chloride in the preparation of various aromatic compounds, will hear the story of the discovery of the zinc alkyls, and will possibly be attracted by those interesting bodies, the organo-metals. Various metals and metallic derivatives have been utilised in the development of Organic Chemistry, and during recent years, much attention has been given to the use of magnesium in the Grignard reaction and to the value of the carbides in the fixation of atmospheric nitrogen, while the reduction and synthesis of organic compounds in the presence of reduced nickel and other metals has, by development, led to the discovery of numerous catalytic changes in the presence of certain metallic oxides. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.


The Synthetic Use of Metals in Organic Chemistry

The Synthetic Use of Metals in Organic Chemistry

Author: Arthur James Hale

Publisher: Palala Press

Published: 2018-02-17

Total Pages: 188

ISBN-13: 9781377770499

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This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.


The Synthetic Use of Metals in Organic Chemistry (Classic Reprint)

The Synthetic Use of Metals in Organic Chemistry (Classic Reprint)

Author: Arthur James Hale

Publisher: Forgotten Books

Published: 2018-01-04

Total Pages: 188

ISBN-13: 9780428332617

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Excerpt from The Synthetic Use of Metals in Organic Chemistry The student of Organic Chemistry will probably be impressed at an early stage with the importance of metallic sodium and its compounds in synthetic work, and Will subsequently mark the value of such substances as acetoacetic malonic and cyanacetic ester and their sodium compounds. He Will notice the use of aluminium chloride in the preparation of various aromatic compounds, will hear the story of the discovery of the zinc alkyls, and will possibly be attracted by those interesting bodies, the organo-metals. Various metals and metallic derivatives have been utilised in the development of Organic Chemistry, and during recent years, much attention has been given to the use of magnesium in the Grignard reaction and to the value of the carbides in the fixation of atmospheric nitrogen, While the reduction and synthesis of organic compounds in the presence of reduced nickel and other metals has, by develop ment, led to the discovery of numerous catalytic changes in the presence of certain metallic oxides. In this volume an attempt has been made to present an account of the uses to which the metals and certain of their compounds have been put, and the work is based upon a course of lectures, on this subject, recently given by the author to the advanced students of Finsbury Technical College. Each chapter is supplemented by an appendix of practical work exemplifying the methods mentioned in the text. About the Publisher Forgotten Books publishes hundreds of thousands of rare and classic books. Find more at www.forgottenbooks.com This book is a reproduction of an important historical work. Forgotten Books uses state-of-the-art technology to digitally reconstruct the work, preserving the original format whilst repairing imperfections present in the aged copy. In rare cases, an imperfection in the original, such as a blemish or missing page, may be replicated in our edition. We do, however, repair the vast majority of imperfections successfully; any imperfections that remain are intentionally left to preserve the state of such historical works.


Transition Metals in the Synthesis of Complex Organic Molecules

Transition Metals in the Synthesis of Complex Organic Molecules

Author: Louis S. Hegedus

Publisher: University Science Books

Published: 1999

Total Pages: 358

ISBN-13: 9781891389047

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This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.


New Pathways for Organic Synthesis

New Pathways for Organic Synthesis

Author: H.M. Colquhoun

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 459

ISBN-13: 1461326516

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The continually growing contribution of transition metal chemistry to synthetic organic chemistry is, of course, widely recognized. Equally well known is the difficulty in keeping up-to-date with the multifarious reactions and procedures that seem to be spawned at an ever-increasing rate. These can certainly be summarized on the basis of reviews under the headings of the individual transition metals. More useful to the bench organic chemist, however, would be the opposite type of concordance based on the structural type of the desired synthetic product. This is the approach taken in the present monograph, which presents for each structural entity a conspectus of the transition metal-mediated processes that can be employed in its production. The resulting comparative survey should be a great help in devising the optimum synthetic approach for a particular goal. It is presented from an essentially practical viewpoint, with detailed direc tions interspersed in the Houben-Weyl style. The wide scope of the volume should certainly encourage synthetic organic chemists to utilize fully the range and versatility of these transition metal-mediated processes. This will certainly be a well-thumbed reference book! R. A. RAPHAEL Cambridge University v Preface In recent years an enormous amount of work has been done on the catalysis of organic reactions by various transition metal species and on the organic reactivity of organo-transition-metal compounds.


The Synthetic Use of Metals in Organic Chemistry - Primary Source Edition

The Synthetic Use of Metals in Organic Chemistry - Primary Source Edition

Author: Arthur James Hale

Publisher: Nabu Press

Published: 2014-01-05

Total Pages: 190

ISBN-13: 9781295460045

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This is a reproduction of a book published before 1923. This book may have occasional imperfections such as missing or blurred pages, poor pictures, errant marks, etc. that were either part of the original artifact, or were introduced by the scanning process. We believe this work is culturally important, and despite the imperfections, have elected to bring it back into print as part of our continuing commitment to the preservation of printed works worldwide. We appreciate your understanding of the imperfections in the preservation process, and hope you enjoy this valuable book.


Main Group Metals in Organic Synthesis

Main Group Metals in Organic Synthesis

Author: Hisashi Yamamoto

Publisher: John Wiley & Sons

Published: 2006-03-06

Total Pages: 905

ISBN-13: 3527605355

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This is the first handbook to cover in detail all aspects of this fascinating field of chemistry. In this handy two-volume set, readers will instantly find the information they need, clearly structured according to the individual metals in the main groups, hitherto only accessible after much time-consuming research. The result is in indispensable aid for everyday work in the lab. Alongside all the classical organic reactions, this book focuses on the modern variations as well as novel, current reactions in organic synthesis that are closely linked to main group elements - both stoechiometric and catalytic. With this work the two prizewinning editors have succeeded in producing a comprehensive compendium of the main group metals as reagents for organic reactions. In short, this is a must for every organic chemist, whether as an efficient introduction to current research, for retaining an overview or for looking up detailed information.