The Chemistry of Phosphorus

The Chemistry of Phosphorus

Author: Arthur D. F. Toy

Publisher: Elsevier

Published: 2016-06-07

Total Pages: 174

ISBN-13: 148313959X

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Pergamon Texts in Inorganic Chemistry, Volume 3: The Chemistry of Phosphorus focuses on the physical and chemical properties of phosphorus. This book discusses phosphorus compounds, such as phosphorus hydrides and phosphonium compounds; phosphorus halides and phosphorus pseudohalides; thiophosphoryl halides and thiophosphoryl pseudohalides; phosphorus oxides; and phosphorus-nitrogen compounds. The pyrophosphates, tripolyphosphates, polyphosphates, cyclic metaphosphates, and ultraphosphates are also covered in this text. This publication is intended for chemical engineering students and chemists researching on the characteristics of phosphorus.


Synthesis of Carbon-Phosphorus Bonds

Synthesis of Carbon-Phosphorus Bonds

Author: Robert Engel

Publisher: CRC Press

Published: 2003-12-18

Total Pages: 200

ISBN-13: 0203998243

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Synthesis of Carbon-Phosphorus Bonds, Second Edition is a working guide for the laboratory, incorporating classical approaches with the recent developments of carbon-phosphorus (C-P) bond formation. These advances include the preparation of phosphoranes - specifically in the use of transient oxophosphoranes as intermediates in organophosphorus comp


Introduction to Phosphorous Chemistry

Introduction to Phosphorous Chemistry

Author: Harold Goldwhite

Publisher: Cambridge University Press

Published: 1981-04-30

Total Pages: 132

ISBN-13: 9780521229784

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This 1981 introduction to the chemistry of a single element, phosphorus, covers many of the major themes of chemistry. Important in inorganic and organic chemistry and in biochemistry, phosphorus is also of considerable economic significance and plays a vital role in the biosphere. By presenting a detailed treatment of selected topics, this book provides a concise account of phosphorus chemistry suitable for anyone with an interest in the field. The book provides a survey of phosphorus compounds by structural and bond types, a review of physical methods in phosphorus chemistry, a review of basicity and co-ordination chemistry of phosphorus donors, a discussion of phosphorus in its group, and a chapter on reagents containing phosphorus in general chemistry. A critical bibliography introduces the reader to the advanced literature. S. I. Units are used throughout, but c.g.s units are also given when appropriate.


Synthesis of Silicon-Nitrogen-Phosphorus Compounds Including a New Synthesis of Phosphazenes

Synthesis of Silicon-Nitrogen-Phosphorus Compounds Including a New Synthesis of Phosphazenes

Author: Robert H. Neilson

Publisher:

Published: 1979

Total Pages: 5

ISBN-13:

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This research under ARO sponsorship has been directed toward the synthesis, characterization, structural isomerization, and thermal decomposition reactions of new silicon-nitrogen-phosphorus compounds. Some of these compounds undergo smooth decomposition when heated to afford phosphazenes, oligomeric materials of general formula (NPRR')n.


Plenary Lectures Presented at the Second Symposium on Inorganic Phosphorus Compounds

Plenary Lectures Presented at the Second Symposium on Inorganic Phosphorus Compounds

Author: W. Wanék

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 362

ISBN-13: 1483284808

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Inorganic Phosphorus Compounds—2 provides information pertinent to the fundamental aspects of inorganic phosphorus compounds. This book discusses the chemistry, bonding, properties, and synthesis in inorganic phosphorus compounds. Organized into 16 chapters, this book begins with an overview of the chemistry of phosphorus triiodide and diiodide. This text then examines the status of inorganic phosphate chemistry as well as the influence of phase transitions upon the physical properties of condensed phosphates. Other chapters consider the synthesis of a large number of simple as well as review the complex polymetaphosphate glasses of alkali metals. This book discusses as well the synthesis of phosphoric triamide under different conditions and condensation by hydrogen chloride. The final chapter deals with the general trend in the development of the production of industrial fertilizers as well as its further prospects. This book is a valuable resource for organic, inorganic, physical, and theoretical chemists.


Phosphorus-Nitrogen Compounds

Phosphorus-Nitrogen Compounds

Author: H Allcock

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 513

ISBN-13: 0323147518

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Phosphorus-Nitrogen Compounds: Cyclic, Linear, and High Polymeric Systems concerns itself with the chemistry of compounds containing alternating phosphorus - nitrogen atoms in the skeleton. The monograph aims to be an introduction to phosphorus-nitrogen chemistry, a review of advances in the field, and reference work. The text is divided into three parts. Part I covers the introduction, historical background, and nomenclature of phosphorus-nitrogen compounds and the theories in bonding and structure of phosphazenes and phosphazanes. Part II deals with reactions such as the synthesis of the phosphorus-nitrogen skeleton, hydrolysis of phosphazenes and phosphazanes, and the aminolysis of halophosphazenes. Part III discusses polymer chemistry and includes topics such as polymerization, depolymerization, and phosphazene polymers. The book is recommended for students and practitioners in the field of chemistry, especially those concerned with phosphorus nitrogen compounds and polymeric systems.


New Aspects in Phosphorus Chemistry I

New Aspects in Phosphorus Chemistry I

Author: Jean-Pierre Majoral

Publisher: Springer

Published: 2003-07-01

Total Pages: 250

ISBN-13: 3540457313

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Undoubtedly the chemistry of phosphorus appears more and more attractive in the sense that phosphorus presents an extraordinary versatile behaviour that allows the synthesis of a large number of different phosphorus reagents usable for applications in different fields, from biology to material science without f- getting key applications in catalysis. The full maturity of this topic of research can be explained by all the acquired knowledge over these twenty last years. Organic and inorganic chemistries of P , P and P species have been the s- in ]V v ject of thousands of publications while the chemistry of low coordinated ph- phorus derivatives experienced its hour of glory from the 1970s to the early 1990s. In parallel, interactions between phosphorus compounds and transition metals afforded many complexes, a lot of which present fascinating properties as catalysts. The interest in all these themes really is not decreasing, indeed some fas- nating areas of research are emerging or are the subject of many investigations: the medicinal chemistry of bisphosphonates, the role of phosphorus in biology, phosphorus ligands in radiopharmaceutical chemistry, phosphorus in material science, new polymers and dendrimers incorporating phosphorus, and as- metric catalysis to name but a few. Indeed researchers, benefitting from their background in basic phosphorus chemistry are developing many new fields of research.