Transition Metal Complexes

Transition Metal Complexes

Author: Umendra Kumar

Publisher: LAP Lambert Academic Publishing

Published: 2011-10

Total Pages: 216

ISBN-13: 9783846529928

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This book deals with some modern methods used in the synthesis and characterization of transition metal complexes. It is written primarily to stimulate the interest of students in metallo-organic chemistry and spectroscopy as well. The book is contained much useful spectral data in the form of tables and spectra. It contains a number of electronic, IR and EPR spectra, so the reader who is not familiar with these techniques can see how the spectra actually appear. It begins with a general introduction of applications of transition metal complexes in different fields. In subsequent chapters the detailed study regarding the synthesis and physicochemical characterization of bivalent transition metal ions [Cr(III), Mn(II), Co(II), Ni(II) and Cu(II)] complexes derived from 2-methylcyclohexanone semicarbazone and thiosemicarbazone using modern techniques like elemental analysis, magnetic moments and conductance measurements and spectroscopic (Electronic, IR, EPR ) studies is discussed. The geometry of synthesized complexes is emphasized. The book is intended to be useful to new metallo-organic researchers.


Synthesis of Physico-Chemical Properties of Metal Oximes, Hydrazones and Semicarbazones

Synthesis of Physico-Chemical Properties of Metal Oximes, Hydrazones and Semicarbazones

Author: Dr. P. M. Dahikar

Publisher: Ashok Yakkaldevi

Published: 2022-04-28

Total Pages: 133

ISBN-13: 1458310361

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The most amazing field of modern inorganic chemistry is co-ordination chemistry. From last four decades, co-ordination chemistry created its own identity in the Inorganic chemistry. The co-ordinate compounds also referred as complexes is a combination of ligand or chelating agent with metal ions through co-ordinate bonds. Ligands are covalent bonded organic molecules containing lone pair or lone pairs of electrons on heteroatom in the organic moiety. As metal ions are electron deficient so these form co-ordinate bonding between metal ion and ligand. The behaviour of metal ion with different ligands depends upon the sterric hindrance, structure, various substituent and nature of bonding present in ligands as well as screening effect, Kernal effect, atomic number oxidation state of metal ion. It was also observed in complexes that there are primary as well as secondary valencies.