Metal-Organic Framework Materials
Metal-Organic Framework Materials

Author: Leonard R. MacGillivray

Publisher: John Wiley & Sons

Published: 2014-09-19

Total Pages: 1210

ISBN-13: 1118931580

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Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

The Chemistry of Metal-Organic Frameworks
The Chemistry of Metal-Organic Frameworks

Author: Stefan Kaskel

Publisher: John Wiley & Sons

Published: 2016-06-16

Total Pages: 904

ISBN-13: 352769305X

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Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.

Functional Metal-Organic Frameworks
Functional Metal-Organic Frameworks

Author: Ali Morsali

Publisher: John Wiley & Sons

Published: 2021-01-13

Total Pages: 256

ISBN-13: 1119640431

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Owing to the extensive interest in construction of functional metal organic frameworks (FMOFs), this book discusses the roles of functional groups on the structure and application of metal organic frameworks (MOFs). The contents of the book are classified based on the structural and chemical properties of organic functions, in order to make readers able to compare the different effects of each function on the structure and application of the MOFs. In each chapter, the chemical properties of applied functional groups are gathered to give deeper insight into the roles of organic functions in the structure and application of MOFs. In the function-application properties, the authors discuss how a functional group can dominate the host-guest chemistry of the MOFs and how this host-guest chemistry can expand the effectiveness and efficiency of the material in different fields of applications. Finally, function-structure properties are discussed. In function-application properties, it is discussed how a functional group can affect the topology, porosity, flexibility and stability of the framework. The features of this subject are novel and are presented for the first time.

Metal Organic Frameworks
Metal Organic Frameworks

Author: Victoria Samanidou

Publisher: MDPI

Published: 2020-03-27

Total Pages: 198

ISBN-13: 303928486X

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Metal–organic frameworks are among the most promising novel materials. The concept of MOFs was first introduced in 1990. They were actually initially used in catalysis, gas separation, membranes, electrochemical sensors. Later on, they were introduced as SPE sorbents for PAHs (Polycyclic Aromatic Hydrocarbons) in environmental water samples, then the range expanded to the field of analytical chemistry, both in chromatographic separation and sample preparation, with great success in, e.g., SPE and SPME (Solid Phase Mico-extraction). Since then, the number of analytical applications implementing MOFs as sorbents in sorptive sample preparation approaches is increasing. Τhis is reinforced by the fact that, at least theoretically, an infinite number of structures can be designed and synthesized, thus making tuneability one of the most unique characteristics of MOF materials. Moreover, they have been designed in various shapes, such as columns, fibers, and films, so that they can meet more analytical challenges with improved analytical features.Their exceptional properties attracted the interest of analytical chemists who have taken advantage of the unique structures and properties and have already introduced them in several sample pretreatment techniques, such as solid phase extraction, dispersive SPE, magnetic solid phase extraction, solid phase microextraction, stir bar sorptive extraction, etc.

Flexible Metal–Organic Frameworks
Flexible Metal–Organic Frameworks

Author: Susumu Kitagawa

Publisher: Royal Society of Chemistry

Published: 2024-03-25

Total Pages: 430

ISBN-13: 1839166622

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Flexible metal–organic frameworks (MOFs) are a unique class of porous materials that feature stimuli-responsive flexible structures and dynamic structural transformation behaviours. Exhibiting structural changes in response to physical or chemical stimuli creates related functions that can be developed for practical applications. The specific components and architectures of flexible MOFs are key to their unique properties, so understanding their chemistry is of critical importance for more targeted construction and functional research. This book provides an accessible overview of the historical background of the chemistry of flexible MOFs and their features; in particular, design and synthesis, dynamic structure analysis, flexibility, function and theoretical treatment, and interpretation of the mechanisms as well as their applications. It gives readers a fundamental understanding of this chemistry and will be of great help to young researchers, as well as those already familiar with conventional porous materials in creating new materials.

Metal-Organic Frameworks for Biomedical Applications
Metal-Organic Frameworks for Biomedical Applications

Author: Masoud Mozafari

Publisher: Woodhead Publishing

Published: 2020-03-17

Total Pages: 584

ISBN-13: 0128169842

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Metal-Organic Frameworks for Biomedical Applications is a comprehensive, authoritative reference that offers a substantial and complete treatment of published results that have yet to be critically reviewed. It offers a summary of current research and provides in-depth understanding of the role of metal-organic frameworks in biomedical engineering. The title consists of twenty-two chapters presented by leading international researchers in the field. Chapters are arranged by target-application in biomedical engineering, allowing medical and pharmaceutic specialists to translate current materials and engineering science on metal-organic frameworks into their work. Presents the state-of-the art in metal-organic frameworks for biomedical applications Offers comprehensive treatment of metal-organic frameworks that is useful to pharmaceutic and medical experts who are non-specialists in materials science Helps materials scientists and engineers understand the needs of biomedical engineering Critically-reviews published results and current research in the field

Synthesis of Metal-Organic Frameworks via Water-Based Routes
Synthesis of Metal-Organic Frameworks via Water-Based Routes

Author: Yasser Azim

Publisher: Elsevier

Published: 2023-10-20

Total Pages: 334

ISBN-13: 0323959407

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Synthesis of Metal-Organic Frameworks via Water-Based Routes: A Green and Sustainable Approach describes a sustainable approach for the synthesis of metal-organic frameworks. Bringing together chapters on the aqueous synthesis and stability of metal-organic frameworks, as well as the applications of water stable metal-organic frameworks, this timely book shows how green processing technology utilizing water as a main solvent for the synthesis of metal-organic frameworks can eliminate solvent consumption, lower investment costs and reduce energy requirements. Providing quantitative descriptions and reliable guidelines, the book summarizes the fundamental approaches and principles to prepare metal-organic frame works, highlighting the most exciting preparations and applications. Includes the role of water in metal organic synthesis Describes various methods of metal-organic framework preparation Covers the industrial aspects of water-based metal-organic frameworks and potential applications