Founded on the work of the renowned Advanced Combustion Engineering Research Center, the authors document and integrate current knowledge of the organic and inorganic structure of coal and its reaction processes. With the urgent need for cleaner, more efficient use of this worldwide fuel, their work will set a clear course for future research.
Coal Science, Volume 3 presents and evaluates selected fundamental scientific areas on coal structure, reactivity, and utilization. This book describes the organic geochemistry of coal, role of oxygen functionality in coal and coal liquids reactivity, chemistry of hydrocarbon syntheses from carbon monoxide and hydrogen, and chemistry of coal in carbon monoxide/water systems. Other topics discussed include intermediates and mechanisms of the FTS of hydrocarbons; synthesis of oxygenates; and structural features of vitrinite macerals. The molecular weight determination for coal derivatives; thermal reactions of oxygen compounds; and alternative methods for removing oxygen compounds from coal-derived liquids are also elaborated. This publication likewise covers the aqueous coal conversions and conversion mechanism. This volume serves as a valuable source of information and guide to scientists and researchers interested in the coal literature.
Providing an overview of the latest computational approaches to estimate rate constants for thermal reactions, this book addresses the theories behind various first-principle and approximation methods that have emerged in the last twenty years with validation examples. It presents in-depth applications of those theories to a wide range of basic and applied research areas. When doing modeling and simulation of chemical reactions (as in many other cases), one often has to compromise between higher-accuracy/higher-precision approaches (which are usually time-consuming) and approximate/lower-precision approaches (which often has the advantage of speed in providing results). This book covers both approaches. It is augmented by a wide-range of applications of the above methods to fuel combustion, unimolecular and bimolecular reactions, isomerization, polymerization, and to emission control of nitrogen oxides. An excellent resource for academics and industry members in physical chemistry, chemical engineering, and related fields.
Since the early decades of the last century, some eminent European scientists have contributed to the creation of a new perspective of our planet Earth. Some outstanding scientific articles were published in the journal Geologische Rundschau (now International Journal of Earth Sciences), mostly in German. These milestones of geoscientific research are available in English for the first time and are presented in this volume. Famous authors include for example Alfred Wegener, a pioneer of modern geology, Gustav Steinmann, Alexander Du Toit, Wolfgang Schott, Hans Cloos and Carl W. Correns. The reader will find a wealth of information about how new insights in specific fields have influenced the development of geoscientific research.
Coal, Oil Shale, Natural Bitumen, Heavy Oil and Peat is a component of Encyclopedia of Energy Sciences, Engineering and Technology Resources in the global Encyclopedia of Life Support Systems (EOLSS), which is an integrated compendium of twenty one Encyclopedias. The Theme on Coal, Oil Shale, Natural Bitumen, Heavy Oil and Peat with contributions from distinguished experts in the field discusses matters of great relevance to our world such as: Coal, Oil Shale, Natural Bitumen, Heavy Oil and Peat; Coal Geology and Geochemistry; Coal Technology; Oil Shale; Natural Bitumen (Tar Sands) and Heavy Oil; Peat and Peatland. These two volumes are aimed at the following five major target audiences: University and College students Educators, Professional practitioners, Research personnel and Policy analysts, managers, and decision makers and NGOs.
For many years, the subject matter encompassed by the title of this book was largely limited to those who were interested in the two most economically important organic materials found buried in the Earth, namely, coal and petroleum. The point of view of any discussions which might occur, either in scientific meetings or in books that have been written, was, therefore, dominated largely by these interests. A great change has occurred in the last decade. This change had as its prime mover our growing knowledge of the molecular architecture of biological systems which, in turn, gave rise to a more legitimate asking of the question: "How did life come to be on the surface of the Earth?" A second motivation arose when the possibilities for the exploration of planets other than the Earth-the moon, Mars, and other parts of the solar system-became a reality. Thus the question of the possible existence of life elsewhere than on Earth conceivably could be answered.
This work is a broad, integrated treatment of the fundamentals of coal combustion and gasification. Most of the authors are recognized professionals in the field and all are conducting research work in the Advanced Combustion Engineering Research Center. The focus of the book is on clean and efficient use of coal. Practical chapters on coal processes, including coal technology projects and on acid rain formation control, lay a foundation for the fundamental treatment. The book is comprehensive in its treatment with over 1000 world-wide references, most of which are from the past five years.
This book provides insights into the development and usage of coal in chemical engineering. The reactivity of coal in processes such as pyrolysis, gasification, liquefaction, combustion and swelling is related to its structural properties. Using experimental findings and theoretical analysis, the book comprehensively answers three crucial issues that are fundamental to the optimization of coal chemical conversions: What is the structure of coal? How does the underlying structure determine the reactivity of different types of coal? How does the structure of coal alter during coal conversion? This book will be of interest to both individual readers and institutions involved in teaching and research into chemical engineering and energy conversion technologies. It is aimed at advanced- level undergraduate students. The text is suitable for readers with a basic knowledge of chemistry, such as first-year undergraduate general science students. Higher-level students with an in-depth understanding of the chemistry of coal will also benefit from the book. It will provide a useful reference resource for students and university-level teachers, as well as practicing engineers.
This book covers the origin and chemical structure of sedimentary organic matter, how that structure relates to appropriate chemical reaction models, how to obtain reaction data uncontaminated by heat and mass transfer, and how to convert that data into global kinetic models that extrapolate over wide temperature ranges. It also shows applications for in-situ and above-ground processing of oil shale, coal and other heavy fossil fuels. It is essential reading for anyone who wants to develop and apply reliable chemical kinetic models for natural petroleum formation and fossil fuel processing and is designed for course use in petroleum systems modelling. Problem sets, examples and case studies are included to aid in teaching and learning. It presents original work and contains an extensive reanalysis of data from the literature.
