Integrating Black Liquor Gasification with Pulping -- Process Simulation, Economics and Potential Benefits

Integrating Black Liquor Gasification with Pulping -- Process Simulation, Economics and Potential Benefits

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Published: 2004

Total Pages:

ISBN-13:

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Gasification of black liquor could drastically increase the flexibility and improve the profit potential of a mature industry. The continuous efforts made in the area of black liquor gasification (BLG) are bringing this technology closer to commercial realization and potential wide-spread implementation. Research exploring the integration of BLG into the kraft process and the potential of BLG enabled modified pulping technologies on modern pulping operations is important to support this effort. The following effort is focused on such research, utilizing laboratory pulping experiments and process simulation. The separation of sodium and sulfur achieved through gasification of recovered black liquor can be utilized in processes like modified continuous cooking, split sulfidity and green liquor pretreatment pulping, and polysulfide-anthraquinone pulping to improve pulp yield and properties. Laboratory pulping protocols have been developed for these modified pulping technologies and different process options evaluated. The process simulation work around BLG has led to the development of a WinGEMS module for the low temperature MTCI steam reforming process, and case studies comparing a simulated conventional kraft process to different process options built around the implementation of a BLG unit operation into the kraft recovery cycle. The implementation of gasification, functioning as the core of wood pulping recovery operations in a biorefinery, would enable the application of modified pulping technologies while creating a synthetic product gas that could be utilized in the production of value added products in addition to wood pulp. The evaluated modified pulping technologies have indicated the potential of yield increases of 1-3% points with improved product quality, and the potential for capital and operating cost savings relative to the conventional kraft process. Process simulation work has shown that the net variable operating cost for a pulping process using BLG.


Black Liquor Gasification

Black Liquor Gasification

Author: Pratima Bajpai

Publisher: Elsevier

Published: 2014-03-06

Total Pages: 103

ISBN-13: 0081000154

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Black Liquor Gasification (BLG) is a first of its kind to guide chemical engineers, students, operators of paper plants, technocrats, and entrepreneurs on practical guidelines and a holistic techno-enviro-economic perspective applicable to their future or existing projects based on the treatment of black liquor for energy production. BLG describes the gasification process as a more efficient alternative to current processes for the conversion of black liquor biomass into energy. BLG operates largely in sync with other methods to improve pulp-making efficiency. This book explains how BLG offers a way to generate electricity and to reclaim pulping chemicals from black liquor, and why BLG would replace the Tomlinson recovery boiler for the recovery of spent chemicals and energy. Describes the utilization of black liquor as a source of energy Provides a detailed account of black liquor gasification processes for the production of energy and chemicals from black liquor Provides guidelines to chemical engineers for the treatment of black liquor


Biermann's Handbook of Pulp and Paper

Biermann's Handbook of Pulp and Paper

Author: Pratima Bajpai

Publisher: Elsevier

Published: 2018-05-17

Total Pages: 670

ISBN-13: 0128142413

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Biermann's Handbook of Pulp and Paper: Raw Material and Pulp Making, Third Edition is a comprehensive reference for industry and academia covering the entire gamut of pulping technology. This book provides a thorough introduction to the entire technology of pulp manufacture; features chapters covering all aspects of pulping from wood handling at the mill site through pulping and bleaching and pulp drying. It also includes a discussion on bleaching chemicals, recovery of pulping spent liquors and regeneration of chemicals used and the manufacture of side products. The secondary fiber recovery and utilization and current advances like organosolv pulping and attempts to close the cycle in bleaching plants are also included. Hundreds of illustrations, charts, and tables help the reader grasp the concepts being presented. This book will provide professionals in the field with the most up-to-date and comprehensive information on the state-of- the-art techniques and aspects involved in pulp making. It has been updated, revised and extended. Alongside the traditional aspects of pulping and papermaking processes, this book also focuses on biotechnological methods, which is the distinguishing feature of this book. It includes wood-based products and chemicals, production of dissolving pulp, hexenuronic acid removal, alternative chemical recovery processes, forest products biorefinery. The most significant changes in the areas of raw material preparation and handling, pulping and recycled fiber have been included. A total of 11 new chapters have been added. This handbook is essential reading for all chemists and engineers in the paper and pulp industry. Provides comprehensive coverage on all aspects of pulp making Covers the latest science and technology in pulp making Includes traditional and biotechnological methods, a unique feature of this book Presents the environmental impact of pulp and papermaking industries Sets itself apart as a valuable reference that every pulp and papermaker/engineer/chemist will find extremely useful


Advancement of High Temperature Black Liquor Gasification Technology

Advancement of High Temperature Black Liquor Gasification Technology

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Published: 2008

Total Pages:

ISBN-13:

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Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.


High-solids Black Liquor Firing in Pulp and Paper Industry Kraft Recovery Boilers

High-solids Black Liquor Firing in Pulp and Paper Industry Kraft Recovery Boilers

Author:

Publisher:

Published: 1997

Total Pages: 207

ISBN-13:

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This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a pilot-scale unit based on the selected technology, and using that unit, develop the precompetitive data necessary to make commercialization attractive. (3) Develop and deploy a first-of-a-kind (FOAK) commercial unit in a kraft pulp mill. Phase I, which evaluated the high-solids advanced combustion option, was concluded in 1995. Results of that project phase were reported previously. This report describes the work conducted in Phase Ia. The work is described in Sections 1 through 4 and six appendices provide additional detail.