Seawater metal-air batteries (SMABs) are promising energy storage technologies for their advantages of high energy density, intrinsic safety, and low cost. However, the presence of such chloride ions complex components in seawater inevitably has complex effects on the air electrode process, including oxygen reduction and oxygen evolution reactions (ORR and OER), which requires the development of highly-active chloride-resistant electrocatalysts. In this review, we first summarized the developing status of various types of SMABs, explaining their working principle and comparing the battery performance. Then, the reported chlorine-resistant electrocatalysts were classified. The composition and structural design strategies of high-efficient chlorine-resistant ORR/OER electrocatalysts in seawater electrolytes were comprehensively summarized. Finally, the main challenges to be overcome in the commercialization of SMABs were discussed.
The Encyclopedia of Electrochemical Power Sources is a truly interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With a focus on the environmental and economic impact of electrochemical power sources, this five-volume work consolidates coverage of the field and serves as an entry point to the literature for professionals and students alike. Covers the main types of power sources, including their operating principles, systems, materials, and applications Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers Incorporates nearly 350 articles, with timely coverage of such topics as environmental and sustainability considerations
Metal–air and metal–sulfur batteries (MABs/MSBs) represent one of the most efficient-energy storage technologies, with high round trip efficiency, a long life cycle, fast response at peak demand/supply of electricity, and decreased weight due to the use of atmospheric oxygen as one of the main reactants. This book presents an overview of the main MABs/MSBs from fundamentals to applications. Recent technological trends in their development are reviewed. It also offers a detailed analysis of these batteries at the material, component, and system levels, allowing the reader to evaluate the different approaches of their integration. The book provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Each chapter focuses on a particular battery type including zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, and vanadium–air redox flow batteries, and metal–sulfur batteries. Features the most recent advances made in metal–air/metal–sulfur batteries. Describes cutting-edge materials and technology for metal–air/metal–sulfur batteries. Includes both fundamentals and applications, which can be used to guide and promote materials as well as technology development for metal–air/metal–sulfur batteries. Provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Covers a variety of battery types in depth, such as zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, vanadium–air redox flow batteries, and metal–sulfur batteries.
Metal-Air Batteries: Principles, Progress, and Perspectives covers the entire spectrum of metal-air batteries, their working principles, recent advancement, and future perspectives. Leading international researchers address materials design, electrochemistry, and architectural aspects. The fundamentals of metal-air materials for cathode and anode, their synthetic approaches, chemistries to modify their properties to provide high energy and power densities, along with long life and stable electrochemical characteristics are detailed. Key Features: Covers materials, chemistry, and technologies for metal-air batteries Reviews state-of-the-art progress and challenges in metal-air batteries Provides fundamentals of the electrochemical behavior of various metal-air batteries Offers insight into tuning the properties of materials to make them suitable for metal-air batteries Provides new direction and a better understanding to scientists, researchers, and students working in diverse fields This is a unique offering and a valuable resource for a wide range of readers including those in academia and industries worldwide.
Simulation of Battery Systems: Fundamentals and Applications covers both the fundamental and technical aspects of battery systems. It is a solid reference on the simulation of battery dynamics based on fundamental governing equations of porous electrodes. Sections cover the fundamentals of electrochemistry and how to obtain electrochemical governing equations for porous electrodes, the governing equations and physical characteristics of lead-acid batteries, the physical characteristics of zinc-silver oxide batteries, experimental tests and parameters necessary for simulation and validation of battery dynamics, and an environmental impact and techno-economic assessment of battery systems for different applications, such as electric vehicles and battery energy storage. The book contains introductory information, with most chapters requiring a solid background in engineering or applied science. Battery industrial companies who want to improve their industrial batteries will also find this book useful. - Includes carefully selected in-text problems, case studies and illustrative examples - Features representative chapter-end problems, along with practical systems and applications - Covers various numerical methods, including those based on CFD and optimization, also including free codes and databases
The electrochemical storage of energy has become essential in assisting the development of electrical transport and use of renewable energies. French researchers have played a key role in this domain but Asia is currently the market leader. Not wanting to see history repeat itself, France created the research network on electrochemical energy storage (RS2E) in 2011. This book discusses the launch of RS2E, its stakeholders, objectives, and integrated structure that assures a continuum between basic research, technological research and industries. Here, the authors will cover the technological advances as well as the challenges that must still be resolved in the field of electrochemical storage, taking into account sustainable development and the limited time available to us.
Metal-air is a promising battery system that uses inexpensive metals for its negative electrode while unlimited, free and non-toxic oxygen is used for its positive electrode, however, only primary systems have been commercialized so far. Electrochemical Power Sources: Fundamentals, Systems, and Applications – Metal–Air Batteries: Present and Perspectives offers a comprehensive understanding of metal-air batteries as well as the solutions to the issues for overcoming the related difficulties of the secondary (rechargeable) system. Although metal-air batteries are widely studied as low-cost high-energy systems, their commercialization is limited to primary ones due to currently limited cycle life and insufficient reliability. For realization of the secondary systems, this book offers comprehensive understanding of metal-air batteries, including the details of both electrodes, electrolyte, cell/system, modelling and applications. Electrochemical Power Sources: Fundamentals, Systems, and Applications – Metal–Air Batteries: Present and Perspectives provides researchers, instructors, and students in electrochemistry, material science and environmental science; industry workers in cell manufacturing; and government officials in energy, environmental, power supply, and transportation with a valuable resource covering the most important topics of metal-air batteries and their uses. - Outlines the general characteristics of metal-air compared with conventional batteries - Offers a comprehensive understanding of various metal-air, featuring zinc, and lithium - Contains comparisons and issues among various metal-air batteries and research efforts to solve them - Includes applications and market prospects
Corrosion and Corrosion Protection of Wind Power Structures in Marine Environments: Volume 2: Corrosion Protection Measures offers the first comprehensive review on corrosion and corrosion protection of offshore wind power structures. The book extensively discusses corrosion phenomena and corrosion types in different marine corrosion zones, including the modeling of corrosion processes and interactions between corrosion and structural stability. The book addresses important design issues, namely materials selection relevant to their performance in marine environments, corrosion allowance, and constructive design. Active and passive corrosion protection measures are emphasized, with special sections on cathodic corrosion protection and the use of protective coatings. Seawater related issues associated with cathodic protection, such as calcareous deposit formation, hydrogen formation, and fouling, are discussed. With respect to protective coatings, the book considers, for the first time, complete loading scenarios, including corrosive loads, mechanical loads, and special loads, and covers a wide range of coating materials. Problems associated with fouling and bacterial-induced corrosion are extensively reviewed. The book closes with a chapter on recent developments in maintenance strategies, inspection techniques, and repair technologies. The book will be of special interest to materials scientists, materials developers, corrosion engineers, maintenance engineers, civil engineers, steel work designers, mechanical engineers, marine engineers, chemists, and coating specialists. Offshore wind power is an emerging renewable technology and a key factor for a cleaner environment. Offshore wind power structures are situated in a demanding and challenging marine environment. The structures are loaded in a complex way, including mechanical loads and corrosive loads. Corrosion is one of the major limiting factors to the reliability and performance of the technology. Maintenance and repair of corrosion protection systems are particularly laborious and costly. - Explores the literature between 1950 and 2020 and contains over 2000 references - Offers the most complete monograph on the issue - Covers all aspects of corrosion protection in detail, including coatings, cathodic protection, corrosion allowance, constructive design, as well as maintenance and repair - Delivers the most complete review on corrosion of metals in marine/offshore environments - Focuses on all aspects of offshore wind power structures, namely foundations, towers, internal sections, connection flanges, and transformation platforms