The Chemistry of Transition Metal Compounds Containing Sulfur-donor Ligands
Author: Denise M. Kelleher
Publisher:
Published: 2002
Total Pages:
ISBN-13:
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Author: Denise M. Kelleher
Publisher:
Published: 2002
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Patrick Quinlivan
Publisher:
Published: 2018
Total Pages:
ISBN-13:
DOWNLOAD EBOOKFor example, a mixture of [TmBut]ZnMe and Me2Cd form an equilibrium mixture with [TmBut]CdMe and Me2Zn. Furthermore, transfer of the [TmBut] ligand between the metal centers is possible too. This is demonstrated by the transfer of [TmBut] from mercury to zinc in the methyl system, [TmBut]HgMe/Me2Zn. Additionally, transfer of [TmBut] from zinc to mercury is also observed upon treatment of [TmBut]2Zn with HgI2 to afford [TmBut]HgI and [TmBut]ZnI, thereby indicating that the nature of the co-ligand has a profound effect on the thermodynamics of ligand exchange. Chapter 3 explores the coordination chemistry of the selenium donor ligand, H(sebenzimMe). H(sebenzimMe) is able to coordinate metal centers through the selenium atom in a dative fashion, and, depending upon the metal center, up to four H(sebenzimMe) ligands can coordinate the same metal. Additionally, H(sebenzimMe) can be deprotonated to form [sebenzimMe]–, allowing for the potential of an LX coordination mode, which results in bridging complexes for the metal compounds investigated.
Author: Th. Weber
Publisher: Springer Science & Business Media
Published: 2013-06-29
Total Pages: 357
ISBN-13: 9401735778
DOWNLOAD EBOOKHydrotreating catalysis with transition metal sulphides is one of the most important areas of industrial heterogeneous catalysis. The present book deals with the chemical and catalytic aspects of transition metal sulphides, focusing on their use in hydrotreating catalysis. The book¿s 12 chapters present reviews of solid-state, coordination and organometallic chemistry, surface science and spectroscopic studies, quantum chemical calculations, catalytic studies with model and real catalysts, as well as refinery processes. A presentation of state-of-the-art background to pertinent work in the field. Can be used as an introduction to the chemical and catalytic properties of transition metal sulphides as well as an advanced level reference.
Author: John Locke
Publisher:
Published: 1967
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: John C. Linehan
Publisher:
Published: 1986
Total Pages: 514
ISBN-13:
DOWNLOAD EBOOKAuthor: Edward I. Stiefel
Publisher:
Published: 1996
Total Pages: 380
ISBN-13:
DOWNLOAD EBOOKThis volume provides an overview of sulfur-coordinated transition metal complexes. It explores how studies of transition metal sulfur sites facilitate understanding of enzymatic and industrial catalytic systems, and it reviews recent research on synthetic analogs to nitrogenase and other transition metal sulfur enzymes relevant to industrial desulfurication. The volume examines synthesis, X-ray structures, and reactivity of transition metal sulfur complexes.
Author: Benjamin Peter Stormer
Publisher:
Published: 1973
Total Pages: 330
ISBN-13:
DOWNLOAD EBOOKAuthor: Charles M. Lukehart
Publisher: Thomson Brooks/Cole
Published: 1985
Total Pages: 472
ISBN-13:
DOWNLOAD EBOOKAuthor: Marcus Orrin Workman
Publisher:
Published: 1966
Total Pages: 326
ISBN-13:
DOWNLOAD EBOOKAuthor: Martha Sosa Torres
Publisher: Walter de Gruyter GmbH & Co KG
Published: 2020-04-06
Total Pages: 500
ISBN-13: 3110589753
DOWNLOAD EBOOKMetal-Sulfur clusters play an essential role in living organisms through the unique character of sulfur-metal bonding. The new volume in prestigious Metal Ions in Life Sciences explores different transition metal complexes with sulfur, their biosynthesis and biological functions in regulation of gene expression, catalysis of important metabolic reactions and protein structure arrangement.