Pergamon Texts in Inorganic Chemistry, Volume 2: The Chemistry of Arsenic, Antimony and Bismuth focuses on the physical and chemical properties of arsenic, antimony, and bismuth. This book discusses the alloys and intermetallic compounds; general aspects of the chemistry of arsenic; salts of antimony and bismuth; and organometallic compounds. The complexes of Arsenic(V), Antimony(V), and Bismuth(V), and mixed valency compounds and mechanisms of redox reactions are also elaborated. This text describes the chemical and physical properties of compounds, such as hydrides EH3, halides EX3, oxides E2O3, halides EX5, sulfides E2S5, oxides E2O5, and related oxyacids. This publication is intended for chemical engineering students and chemists researching on the characteristics of arsenic, antimony, and bismuth.
This book provides a detailed, wide ranging and up-to-date review of all aspects of the chemistry of the elements arsenic, antimony and bismuth. The chapters are written by an international team of authors each of whom is both active and expert in their particular field. The coverage includes chapters on general properties and periodicity, the elements themselves, inorganic derivatives of the elements, co-ordination and solution chemistry, organocompounds, organotransition metal compounds, environmental and medicinal aspects and analytical methods. This volume will be of particular value to graduate and postgraduate chemists and materials scientists in both industry and academia who are concerned with any aspect of the chemistry of these three elements and will also be an essential addition to the reference section of any chemistry library.
The organic synthetic chemistry of the Group V elements, arsenic, antimony and bismuth are dealt with in this volume in the respected Patai series. Internationally known contributors have written chapters on topics such as the analytical, theoretical, environmental and synthetic chemistry of the organometallic compounds of these elements.
Arsenic, antimony and bismuth, three related elements of group 15, are all found in trace quantities in nature and have interesting biological properties and uses. While arsenic is most well known as a poison - and indeed the contamination of groundwater by arsenic is becoming a major health problem in Asia - it also has uses for the treatment of blood cancer and has long been used in traditional chinese medicine. Antimony and bismuth compounds are used in the clinic for the treatment of parasitic and bacterial infections. Biological Chemistry of Arsenic, Antimony and Bismuth is an essential overview of the biological chemistry of these three elements, with contributions from an international panel of experts. Topics covered include: chemistry of As, Sb and Bi biological chemistry of arsenic biological chemistry of Sb and Bi arsenic and antimony speciation in environmental and biological samples arsenic in traditional chinese medicine arsenic in aquifers biomethylation of As, Sb and Bi uptake of metalloids by cells bismuth complexes of porphyrins and their potential in medical applications Helicobacter pylori and bismuth metabolism of arsenic trioxide in blood of the acute promyelocytic leukemia patients anticancer properties of As, Sb and Bi radio-Bi in cancer therapy genotoxicity of As, Sb and Bi metallomics as a new technique for As, Sb and Bi metalloproteomics for As, Sb and Bi Biological Chemistry of Arsenic, Antimony and Bismuth conveys the essential aspects of the bioinorganic chemistry of these three elements, making this book a valuable complement to more general bioinorganic chemistry texts and more specialized topical reviews. It will find a place on the bookshelves of practitioners, researchers and students working in bioinorganic chemistry and medicinal chemistry.
Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.
More and more possible applications of organometallic compounds in organic synthesis have been uncovered and a growing number of scientists are attracted to this area of research. This book presents an state-of-the-art account of the successful application of main- and transition metal mediated syntheses. It will stimulate new ideas and initiate further research in all areas of this fascinating chemistry.
