The Catalytic Chemistry of Nitrogen Oxides

The Catalytic Chemistry of Nitrogen Oxides

Author: Richard Klimisch

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 337

ISBN-13: 1461587417

DOWNLOAD EBOOK

This book contains the papers and discussions from the sympo!,ium on "The Catalytic Chemistry of Nitrogen Oxides" held at the General Motors Research Laboratories on October 7-8, 1974. This symposium is the eighteenth in the annual series presented by the Research Laboratories. The topics for these symposiums have covered a broad range. Each topic was selected to be of intense current interest and of significant technical importance. There is no question that the subject of the 1974 Symposium satisfies these two criteria. The control of automotive nitrogen oxides has been perhaps the most difficult and controversial area of automotive emissions both in terms of what is necessary and in terms of what is technically feasible. This area has been a source of considerable discussion not only in the technical community but also in governments both in the U. S. and abroad. This meeting brought together scientists working in surface chemistry with engineers working on system design. It also brought together representatives of government, academia and industry. We feel that an important side benefit of the meeting was the improved understanding that was developed between these groups. Participants came from Europe and Japan as well as Canada and the United States. The technical papers spanned the range from fundamental interactions of NO on surfaces through bench scale kinetic and mechanistic studies and ended with catalytic applications. Although the emphasis was on automotive NO removal, stack gas NO x x control was also covered.


Catalysts for low temperature conversion of nitrogen oxides

Catalysts for low temperature conversion of nitrogen oxides

Author: Martin Busch

Publisher: Cuvillier Verlag

Published: 2015-06-02

Total Pages: 174

ISBN-13: 3736949901

DOWNLOAD EBOOK

Nitrogen oxides are a major threat to human health and largely released by Diesel engines. The present book describes the preparation and characterization of appropriate catalyst systems for low temperature removal (150 - 400°C) and conversion of nitrogen oxides. The presented catalysts include commercially available activated carbon and zeolite supports, infiltrated with iron, copper, manganese and their oxides. The investigated catalysts adsorb and convert nitrogen dioxide almost completely and convert it quickly subsequently into the less toxic nitric oxide and nitrous oxide. Some eventually release nitrogen and oxygen, thus outperforming even the well-known Cu-ZSM-5 catalyst at low temperature. Stickoxide zählen zu den wichtigsten Umweltgiften und werden zu einem großen Anteil durch Dieselmotoren freigesetzt. Dieses Buch beschreibt die Herstellung und Charakterisierung von Katalysatorsysteme für die Niedertemperatur-Umsetzung (150 - 400°C) von Stickoxiden. Zu den vorgestellten Katalysatoren gehören kommerziell verfügbare Aktivkohle und Zeolith-Materialien, welche mit Eisen, Kupfer, Mangan und deren Oxiden infiltriert wurden. Alle untersuchten Katalysatorsysteme absorbieren Stickoxide rasch und setzen diese anschließend fast vollständig in die weit weniger toxischen Gase Stickstoffmonoxid und Distickstoffmonoxid um. Einige der untersuchten Katalysatorsystemen setzen schließlich Sauerstoff und Stickstoff frei und zeigen bei niedrigen Temperaturen sogar eine bessere Performance als der bereits gut bekannte Cu-ZSM-5 Katalysator.


Selective Catalytic Reduction of NOx

Selective Catalytic Reduction of NOx

Author: Oliver Kröcher

Publisher: MDPI

Published: 2018-12-14

Total Pages: 281

ISBN-13: 3038973645

DOWNLOAD EBOOK

This book is a printed edition of the Special Issue "Selective Catalytic Reduction of NOx" that was published in Catalysts


NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines

NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines

Author: B. Ashok

Publisher: Elsevier

Published: 2021-11-09

Total Pages: 488

ISBN-13: 0128242280

DOWNLOAD EBOOK

NOx Emission Control Technologies in Stationary and Automotive Internal Combustion Engines: Approaches Toward NOx Free Automobiles presents the fundamental theory of emission formation, particularly the oxides of nitrogen (NOx) and its chemical reactions and control techniques. The book provides a simplified framework for technical literature on NOx reduction strategies in IC engines, highlighting thermodynamics, combustion science, automotive emissions and environmental pollution control. Sections cover the toxicity and roots of emissions for both SI and CI engines and the formation of various emissions such as CO, SO2, HC, NOx, soot, and PM from internal combustion engines, along with various methods of NOx formation. Topics cover the combustion process, engine design parameters, and the application of exhaust gas recirculation for NOx reduction, making this book ideal for researchers and students in automotive, mechanical, mechatronics and chemical engineering students working in the field of emission control techniques. Covers advanced and recent technologies and emerging new trends in NOx reduction for emission control Highlights the effects of exhaust gas recirculation (EGR) on engine performance parameters Discusses emission norms such as EURO VI and Bharat stage VI in reducing global air pollution due to engine emissions


Past and Present in DeNOx Catalysis: From Molecular Modelling to Chemical Engineering

Past and Present in DeNOx Catalysis: From Molecular Modelling to Chemical Engineering

Author: Pascal Granger

Publisher: Elsevier

Published: 2007-12-15

Total Pages: 419

ISBN-13: 0080554059

DOWNLOAD EBOOK

This book offers an overview of the state of the art in the field of DeNOx catalysis in order to focus novel orientations, new technological developments, from laboratory to industrial scale. A particular attention has been paid towards the implementation of catalytic processes for minimising NOx emissions either from stationary or mobile sources under lean condition to meet future standard regulations of NOx emissions. In the first part of this book, critical aspects reported in the literature which usually make difficult the achievement of efficient catalytic technologies in those conditions are summarised and analysed in order two separate new perspectives. The second part deals with fundamental aspects at molecular level. A better understanding of the reactions involved under unsteady-state conditions is probably a pre-requisite step for improving the performances of the actual processes or developing original ones. The development of powerful in situ spectroscopic techniques is of fundamental interest for kinetic modelling. Correlations between spectroscopic and kinetic data with those obtained from theoretical calculations are reported. Some illustrations emphasise the fact that these comparisons may help in determining the nature of the catalytic active sites and building predictive tools for simulations under running conditions. The latter part of this book will be illustrated by different practical approaches covering various aspects related to the catalysts preparation and the development of alternative technologies which include industrial considerations. - New technological developments for investigating catalytic reactions in transient conditions (in situ and operando spectroscopic techniques) - Concerted approaches in DeNOx catalysis - How academic aspects (kinetic, in situ spectroscopic measurements) can provide useful information for practical applications - Comparison of different approaches provided by academic and industrial partners