The Anomeric Effect and Associated Stereoelectronic Effects

The Anomeric Effect and Associated Stereoelectronic Effects

Author: Gregory Robert James Thatcher

Publisher: Washington, DC : American Chemical Society

Published: 1871

Total Pages: 716

ISBN-13:

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Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.


The Anomeric Effect

The Anomeric Effect

Author: Eusebio Juaristi

Publisher: CRC Press

Published: 1994-10-12

Total Pages: 248

ISBN-13: 9780849389412

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This book provides a comprehensive review of the structural, conformational, and chemical manifestations of the anomeric effect. In order to present a cogent discussion of this most fundamental and relevant phenomenon, three chapters examine our present understanding of the origin of this conformational effect, based upon a wealth of theoretical and physical data. Equally important, however, are three additional chapters that deal with the general consequences of the stereoelectronic interactions that are associated with the basis of the anomeric effect. The remainder of the book is devoted to new areas of development in the topic-such as differentiation of the endo and exo anomeric interactions, specific analysis of the enthalpic component of anomeric effects, critical evaluation of the kinetics and reverse anomeric effects, discovery of a new substantial effect in second- and lower-row anomeric segments, and others.


The Anomeric Effect and Associated Stereoelectronic Effects

The Anomeric Effect and Associated Stereoelectronic Effects

Author: Gregory Robert James Thatcher

Publisher: Washington, DC : American Chemical Society

Published: 1993

Total Pages: 328

ISBN-13:

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Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.


Stereoelectronic Effects

Stereoelectronic Effects

Author: Anthony John Kirby

Publisher: Oxford University Press, USA

Published: 1996

Total Pages: 108

ISBN-13:

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Stereoelectronic effects control the way molecules are put together an d account for the "rules of engagement" which operate when molecules m eet and react. Understanding these effects is the key to understanding molecular behavior, since the same basic three-dimensional interactio ns are responsible for both structure and reactivity. This concise and very accessible volume provides a comprehensive, intentionally non-ma thematical coverage of stereochemistry, along with an in-depth discuss ion of the main classes of organic reactions, promoting a logical and simple way of thinking about chemistry.


Stereoelectronic Effects

Stereoelectronic Effects

Author: Igor V. Alabugin

Publisher: John Wiley & Sons

Published: 2016-10-17

Total Pages: 404

ISBN-13: 1118906349

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Stereoelectronic Effects illustrates the utility of stereoelectronic concepts using structure and reactivity of organic molecules An advanced textbook that provides an up-to-date overview of the field, starting from the fundamental principles Presents a large selection of modern examples of stereoelectronic effects in organic reactivity Shows practical applications of stereoelectronic effects in asymmetric catalysis, photochemical processes, bioorganic chemistry and biochemistry, inorganic and organometallic reactivity, supramolecular chemistry and materials science


Steric and Stereoelectronic Effects in Organic Chemistry

Steric and Stereoelectronic Effects in Organic Chemistry

Author: Veejendra K. Yadav

Publisher: Springer Nature

Published: 2021-07-01

Total Pages: 262

ISBN-13: 303075622X

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In this second edition, the author has thoroughly updated each chapter and expanded the content with addition of three new chapters. This book comments on several key aspects of stereochemical control of organic reactions in measured detail to allow the reader easily grasp these concepts. In addition, emphasis is given to key information and important aspects of steric and stereoelectronic effects and their control on conformational profile and reactivity features. This book is not only an indispensable resource for advanced undergraduate and graduate students studying the stereochemical aspects of organic reactions, but also a good reference book for all organic chemists in both industry and academia.


Carbohydrates

Carbohydrates

Author: Momcilo Miljkovic

Publisher: Springer Science & Business Media

Published: 2009-09-18

Total Pages: 547

ISBN-13: 0387922652

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All essential areas of basic synthetic carbohydrate chemistry are covered and appropriately described. In addition, this book explains the basic reaction mechanisms while taking into account modern concepts such as stereoelectronic principles.


Stereochemistry and Organic Reactions

Stereochemistry and Organic Reactions

Author: Dipak Kumar Mandal

Publisher: Academic Press

Published: 2021-04-21

Total Pages: 640

ISBN-13: 0128240938

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Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. - Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes - Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs - Features novel rules and mnemonics to delineate product stereochemistry - Includes up-to-date coverage with over 1300 selective references