Synthetic and Kinetic Studies Towards the Acceleration of Macrocyclic Metal Complex Formation
Author: Anne Kathleen McCasland
Publisher:
Published: 1999
Total Pages: 460
ISBN-13:
DOWNLOAD EBOOKRead and Download eBook Full
Author: Anne Kathleen McCasland
Publisher:
Published: 1999
Total Pages: 460
ISBN-13:
DOWNLOAD EBOOKAuthor: Andrew Mark Danby
Publisher:
Published: 1996
Total Pages: 0
ISBN-13:
DOWNLOAD EBOOKAuthor: J.H. Zagal
Publisher: Springer Science & Business Media
Published: 2006-07-19
Total Pages: 828
ISBN-13: 038728429X
DOWNLOAD EBOOKIn response to significant developments in sensor science and technology, this book offers insight into the various extended applications and developments of N4 macrocycle complexes in biomimetic electrocatalysis. Covers chemical properties of electrocatalysts, use of specific species, and analytical applications.
Author:
Publisher:
Published: 2000
Total Pages: 830
ISBN-13:
DOWNLOAD EBOOKAuthor: Francesco Ciardelli
Publisher: Springer Science & Business Media
Published: 2012-12-06
Total Pages: 333
ISBN-13: 3642609864
DOWNLOAD EBOOKThe first concise overview on the topic, spanning the spectrum from fundamentals to new application areas. The synthesis, kinetics and thermodynamics of these complexes are covered in detail, while much emphasis is placed on special properties such as gas transport, charge transport, catalysis and light-induced processes. Furthermore, the authors treat the actual working areas for new application methods. In all, a very helpful tool for polymer and materials scientists, as well as organic and physical chemists working in these fields.
Author: Rayees Sheikh
Publisher: LAP Lambert Academic Publishing
Published: 2012-07
Total Pages: 156
ISBN-13: 9783659146572
DOWNLOAD EBOOKThis book presents the important facts about the synthesis and biological studies of macrocyclic transition metal complexes. A detailed synthetic discussion of the reaction steps in each mechanism and their relationship with transition metal complexes has been considered. Macrocyclic ligands and their transition metal complexes depends upon the nature of reactants and the corresponding metal ion. The macrocyclic ligand are a growing class of compounds with varying chemistry a wide range of different molecular topologies and set of donor atoms. Aza type ligands appear as very promising to be used as antifertile, antibacterial, antifungal and other biological properties. Macrocyclic metal complexes play a central role in the construction of molecular materials, which display magnetic properties and find applications in material and supramolecular chemistry and biochemistry. It is believed that the present book will provide a succinct and clear introduction to synthesis, characterization and biological studies macrocyclic ligands with transition metal complexes that meets the needs of researchers at a variety of levels in several disciplines.
Author:
Publisher:
Published: 1999
Total Pages: 848
ISBN-13:
DOWNLOAD EBOOKAuthor: Kenichi Endo
Publisher: Springer
Published: 2021-04-02
Total Pages: 80
ISBN-13: 9789811611629
DOWNLOAD EBOOKThis book describes novel synthetic methodologies for two kinds of structurally elaborate metal complexes: a heterometallic complex and a tetrahedral chiral-at-metal complex. The book provides the tools and inspiration to chemists for development of metal complexes with wide structural diversity than had previously been possible. For each of the two topics, existing synthetic methods for similar compounds are discussed first, and then new strategies are presented, followed by the demonstration of the synthesis of novel compounds supported by experimental results. Both of the final products in this research, a Co–Ni heterometallic complex covered in the first topic and a tetrahedral chiral-at-metal complex in the second one are difficult to obtain by using common synthetic methods for thermodynamic reasons. This research achieved highly selective syntheses of these compounds using newly designed strategies that enable precise kinetic control. Such an approach will be useful for synthesizing other new metal complexes. Since the last century, organic chemistry has flourished with the development of a variety of synthetic techniques that make precise kinetic control possible. Coordination chemistry of 3d or main-group transition metals has been mainly based on simple one-step reactions that yield only thermodynamic products. The publication of this book helps pave the way to kinetically controlled precise syntheses of various metal complexes.
Author: N. V. Gerbeleu
Publisher: Wiley-VCH
Published: 2008-07-11
Total Pages: 574
ISBN-13: 3527613811
DOWNLOAD EBOOKThe synthesis of macrocycles is an art in itself. Template-controlled synthesis provides elegant access to fascinating macrocyclic structures. Polyazamacrocycles, crown ethers, cryptands, rotaxanes, knots -- the range of macrocyclic compounds is as broad as their potential application as molecular switches, in ion exchange, electron transfer or catalysis. This book provides authoritative information on all aspects of template-controlled macrocyclizations. It covers in depth the current state of research on template processes - novel synthetic techniques and mechanistic approaches. The critical discussion of the diverse synthetic routes includes the detailed characterization of the broad variety of macrocyclic products. References to applications of macrocyclic compounds and over 1,500 citations make this handbook an indispensable tool for chemists in academia and industry. Researchers in organic and supramolecular chemistry, biotechnology, and inorganic chemistry will find inspiration for the design, synthesis, and myriad uses of new synthetic macrocycles.