Complexes [LnX(DMF)n][M(CN)4] (where X= Cl or NO3) with a Ln:M ratio of 1:1 have been synthesized and structurally characterized. The anion [Pt(CN)4]2− was not able to replace the nitrate ligand of [Ce(NO3)(DMF)5][Pt(CN)4]; however, the anion [Pt(CN)4]2− was able to replace the chloride ligand to produce [Ce(DMF)5]2[Pt(CN)4]3.
Early Earth Systems provides a complete history of the Earth from its beginnings to the end of the Archaean. This journey through the Earth's early history begins with the Earth's origin, then examines the evolution of the mantle, the origin of the continental crust, the origin and evolution of the Earth's atmosphere and oceans, and ends with the origin of life. Looks at the evidence for the Earth's very early differentiation into core, mantle, crust, atmosphere and oceans and how this differentiation saw extreme interactions within the Earth system. Discusses Archaean Earth processes within the framework of the Earth System Science paradigm, providing a qualitative assessment of the principal reservoirs and fluxes in the early Earth. “The book would be perfect for a graduate-level or upper level undergraduate course on the early Earth. It will also serve as a great starting point for researchers in solid-Earth geochemistry who want to know more about the Earth’s early atmosphere and biosphere, and vice versa for low temperature geochemists who want to get a modern overview of the Earth’s interior.” Geological Magazine, 2008
A practical guidebook illustrating the applications of spectroelectrochemistry to the understanding of redox reactions through identification of their intermediaries and products.
The main challenge in modern solvent extraction separation is that most techniques are mainly empirical, specific and particular for narrow fields of practice and require a large degree of experimentation. This concise and modern book provides a complete overview of both solvent extraction separation techniques and the novel and unified competitive complexation/solvation theory. This novel and unified technique presented in the book provides a key for a preliminary quantitative prediction of suitable extraction systems without experimentation, thus saving researchers time and resources. Analyzes and compares both classical and new competitive models and techniques Offers a novel and unified competitive complexation / solvation theory that permits researchers to standardize some parameters, which decreases the need for experimentation at R&D Presents examples of applications in multiple disciplines such as chemical, biochemical, radiochemical, pharmaceutical and analytical separation Written by an outstanding scientist who is prolific in the field of separation science
Photocatalysis is a hot topic because it is an environmentally friendly approach toward the conversion of light energy into chemical energy at mild reaction environments. Also, it is well applied in several major areas such as water splitting, bacterial inactivation, and pollutants elimination, which is a possible solution to energy shortage and environmental issues. The fundamental knowledge and the frontier research progress in typical photocatalytic materials, such as TiO2-based and non-TiO2-based photocatalysts, are included in this book. Methods to improve the photocatalytic efficiency and to provide a hint for the rational design of the new photocatalysts are covered.
