In current materials R&D, high priority is given to surface modification techniques to achieve improved surface properties for specific applications requirements. Plasma treatment and polymerization are important technologies for this purpose. This book provides a basic and thorough presentation of this subject. This is probably the first book
Plasma Polymer Films examines the current status of the deposition and characterization of fluorocarbon-, hydrocarbon- and silicon-containing plasma polymer films and nanocomposites, with plasma polymer matrix. It introduces plasma polymerization process diagnostics such as optical emission spectroscopy (OES, AOES), and describes special deposition techniques such as atmospheric pressure glow discharge. Important issues for applications such as degradation and stability are treated in detail, and structural characterization, basic electrical and optical properties and biomedical applications are discussed.
Plasma Deposition, Treatment, and Etching of Polymers takes a broad look at the basic principles, the chemical processes, and the diagnostic procedures in the interaction of plasmas with polymer surfaces. This recent technology has yielded a large class of new materials offering many applications, including their use as coatings for chemical fibers and films. Additional applications include uses for the passivation of metals, the surface hardening of tools, increased biocompatibility of biomedical materials, chemical and physical sensors, and a variety of micro- and optoelectronic devices. - Appeals to a broad range of industries from microelectronics to space technology - Discusses a wide array of new uses for plasma polymers - Provides a tutorial introduction to the field - Surveys various classes of plasma polymers, their chemical and morphological properties, effects of plasma process parameters on the growth and structure of these synthetic materials, and techniques for characterization - Interests scientists, engineers, and students alike
Polymer Surfaces - From Physics to Technology is divided into four main sections. Firstly the origins and physical principles governing the properties of polymer surfaces are considered. Next the authors discuss methods of characterization, particularly spectroscopic, and those connected to surface energetics.
Scanning tunneling microscopy (STM) and atomic force microscopy (AFM) are powerful tools for surface examination. In the past, many STM and AFM studies led to erroneous conclusions due to lack of proper theoretical considerations and of an understanding of how image patterns are affected by measurement conditions. For this book, two world experts, one on theoretical analysis and the other on experimental characterization, have joined forces to bring together essential components of STM and AFM studies: The practical aspects of STM, the image simulation by surface electron density plot calculations, and the qualitative evaluation of tip-force induced surface corrugations. Practical examples are taken from: * inorganic layered materials * organic conductors * organic adsorbates at liquid-solid interfaces * self-assembled amphiphiles * polymers This book will be an invaluable reference work for researchers active in STM and AMF as well as for newcomers to the field.
This edition updates the survey of the many rapidly developing subjects concerning the mapping of a variety of forces across surfaces, including basic theory, instrumentation, and applications. It also includes important new research in STM and a thoroughly revised bibliography.
The investigation and manipulation of matter on the atomic scale have been revolutionised by scanning tunnelling microscopy and related scanning probe techniques. This book is the first to provide a clear and comprehensive introduction to this subject. Beginning with the theoretical background of scanning tunnelling microscopy, the design and instrumentation of practical STM and associated systems are described in detail, as are the applications of these techniques in fields such as condensed matter physics, chemistry, biology, and nanotechnology. Containing 350 illustrations, and over 1200 references, this unique book represents an ideal introduction to the subject for final-year undergraduates in physics or materials science. It will also be invaluable to graduate students and researchers in any branch of science where scanning probe techniques are used.
This and its companion Volume 2 document the proceedings of the International Symposium on Physicochemical Aspects of Polymer Surfaces held under the auspices of the American Chemical Society in New York City, August 23-28, 1981. This event was sponsored by the Division of Colloid and Surface Chemistry and the Divisions of Organic Coatings and Plastics Chemistry, and Industrial and Engineering Chemistry were the cosponsors. The study of polymer surfaces is important from both funda mental and applied points of view. The applications of polymers are legion and wheresoever polymers are used, their surface char acteristics, inter alia, are of great concern and importance; and the areas where polymers find applications range from microelec tronics to prosthetics. In the last decade or so, the availabil ity of various sophisticated surface analytical techniques, par ticularly ESCA, has been a boon in enhancing our knowledge of polymer surfaces. This Symposium was designed to bring together scientists and technologists interested in all aspects of polymer surfaces, to provide a forum for discussion of various ramifications of poly mer surfaces, to discover the latest developments, to provide an opportunity for cross-pollination of ideas, and to highlight areas which are in astate of rapid development and those which need intensified efforts. If the comments from attendees is any barometer of the success of an event, then this Symposium was a grand success and the above objectives were amply fulfilled.
A small symposium on The Dynamic Aspects of Polymer Surfaces was held as part of the Rocky Mountain Regional American Chemical Society meeting, June, 1986, in Denver, Colorado. In view of the growing activity and interest in polymer surface dynamics, the participants agreed to publish their papers under the auspices of Plenum Press. The authors and participants join me in wishing that this volume will be of assistance to those studying and applying polymeric materials and that it will contribute to the growing awareness that polymer surfaces are indeed dynamic and undergo time- and temperature-dependent relaxations in response to changes in their local environment. J. D. Andrade Salt Lake City, Utah January 1987 CONTENTS Polymer Surface and Interface Dynamics: An Introduction ••••••••••••••• l J. D. Andrade Modeling of the Wilhelmy Contact Angle Method with Practical Sample Geometr i es •••••••••••••••••••••••••••••••••••••••••••••••• 9 P. Dryden, J. H. Lee, J. M. Park, and J. D. Andrade Contact Angles at Polymer~ater Interface; Temperature Dependence and Induced Deformation ••••••••••••••••••••••••. ••••• 25 M. S. Jhon and S. H. Yuk Orientation Phenomena at Polymer-Water Interfaces ••••••••••••••••••••• 45 L. Lavielle Dynamic Contact Angle Studies of N-Alkyl Derivatized Boro-Silicate Glass Surfaces •••••••••••••••••••••••••••••••••••• 67 J. M. Park and J. D. Andrade Surface Mobility and Structural Transitions of Poly(n-Alkyl Methacrylates) Probed by Dynamic Contact Angle Measurement •••••• 89 H. S. van Damme, A. H. Hogt, and J. Feijen Dynamic Wettability of Hydrophobic Polymers •••••••••••••••••••••••••• lOl M. J. OWen, T. M. Gentle, T. Orbeck, and D. E.
Since the publication of the first edition of this successful and popular book in 1970, the subject of lipid biochemistry has evolved greatly and this fifth up-to-date and comprehensive edition includes much new and exciting information. Lipid Biochemistry, fifth edition has been largely re-written in a user-friendly way, with chapters containing special interest topic boxes, summary points and lists of suggested reading, further enhancing the accessibility and readability of this excellent text. Contents include abbreviations and definitions used in the study of lipids, routine analytical methods, fatty acid structure and metabolism, dietary lipids and lipids as energy stores, lipid transport, lipids in cellular structures and the metabolism of structural lipids. The book provides a most comprehensive treatment of the subject, making it essential reading for all those working with or studying lipids. Upper level students of biochemistry, biology, clinical subjects, nutrition and food science will find the contents of this book invaluable as a study aid, as will postgraduates specializing in the topics covered in the book. Professionals working in research in academia and industry, including personnel involved in food and nutrition research, new product formulation, special diet formulation (including nutraceuticals and functional foods) and other clinical aspects will find a vast wealth of information within the book's pages. Michael Gurr was a Visiting Professor in Human Nutrition at the University of Reading, UK and at Oxford Brookes University, UK. John Harwood is a Professor of Biochemistry at the School of Biosciences, Cardiff University, UK. Keith Frayn is a Professor of Human Metabolism at the Oxford Centre for Diabetes, Endocrinology and Metabolism, University of Oxford, UK.
