Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production
Supported Layered Double Hydroxides as CO2 Adsorbents for Sorption-enhanced H2 Production

Author: Diana Iruretagoyena Ferrer

Publisher: Springer

Published: 2016-07-15

Total Pages: 234

ISBN-13: 3319412760

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This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.

Integrating Green Chemistry and Sustainable Engineering
Integrating Green Chemistry and Sustainable Engineering

Author: Shahid Ul Islam

Publisher: John Wiley & Sons

Published: 2019-04-01

Total Pages: 634

ISBN-13: 1119509823

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This groundbreaking book covers the recent advances in sustainable technologies and developments, and describes how green chemistry and engineering practices are being applied and integrated in various industrial sectors. Over the past decade, the population explosion, rise in global warming, depletion of fossil fuel resources and environmental pollution have been the major driving force for promoting and implementing the principles of green chemistry and sustainable engineering in all sectors ranging from chemical to environmental sciences. It plays a growing role in the chemical processing industries. Green chemistry and engineering are relatively new areas focused on minimizing generations of pollution by utilizing alternative feedstocks, developing, selecting, and using less environmentally harmful solvents, finding new synthesis pathways, improving selectivity in reactions, generating less waste, avoiding the use of highly toxic compounds, and much more. In an effort to advance the discussion of green chemistry and engineering, this book contains 19 chapters describing greener approaches to the design and development of processes and products. The contributors describe the production of third generation biofuels, sustainable and economic production of hydrogen by water splitting using solar energy, efficient energy harvesting, mechanisms involved in the conversion of biomass, green nanocomposites, bio-based polymers, ionic liquids as green solvents, sustainable nitrogen fixation, bioremediation, and much more. The book aims at motivating chemists and engineers, as well as postgraduate and PhD students and postdocs to pay attention to an acute need for the implementation of green chemistry principles in the field of chemical engineering, biomedical engineering, agriculture, environmental engineering, chemical processing and material sciences.

Sorption Enhanced Reaction Processes
Sorption Enhanced Reaction Processes

Author: Alirio Egidio Rodrigues

Publisher: World Scientific

Published: 2017-08-16

Total Pages: 365

ISBN-13: 1786343584

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This book investigates the development of sorption enhanced reaction processes (SERPs) with detailed modelling and simulation, design and operation of units. SERPs are processes intensified by combining adsorption and reaction, reaction and membranes or reaction/adsorption/membranes in a single unit in order to overcome thermodynamic limitations of conversion in reversible reactions. The focus here is on gas phase and liquid phase processes involving different technologies, including pressure swing adsorptive reactors, membrane reactors and simulated moving bed reactors. Emphasis is also given to presenting data and practical applications of SERP products.Sorption Enhanced Reaction Processes provides undergraduate and graduate students of chemistry and chemical engineering, researchers and industrial engineers with a clear path towards process development of SERP, whatever the area of application.

Resource Recovery and Recycling from Waste Metal Dust
Resource Recovery and Recycling from Waste Metal Dust

Author: Daniel Ogochukwu Okanigbe

Publisher: Springer Nature

Published: 2023-03-15

Total Pages: 327

ISBN-13: 3031224922

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This book examines resource recovery and recycling from waste metal dust, including currently used techniques for waste processing and recycling and their applications, with practical examples and economic potentials of the processes. The focus of this book is on resource recovery by suitable treatments and techniques, including those of recovery by-products. For the first time, this book provides a comprehensive, one-stop reference including seminal principles and methods, the advantages and disadvantages of the processes discussed, and the economics of the technology. It will serve as a technical reference for working scientists and engineers, while serving as an educational reference to students studying the waste recovery of metals.

Advances in Bioenergy
Advances in Bioenergy

Author: Peter D. Lund

Publisher: John Wiley & Sons

Published: 2015-12-07

Total Pages: 560

ISBN-13: 1118957865

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The increasing deployment of bioenergy frequently raises issues regarding the use of land and raw materials, infrastructure and logistics. In light of these sometimes conflicting interests Advances in Bioenergy provides an objective and wide-ranging overview of the technology, economics and policy of bioenergy. Offering an authoritative multidisciplinary summary of the opportunities and challenges associated with bioenergy utilization, with international researchers give up-to-date and detailed information on key issues for biomass production and conversion to energy. Key features: *Discusses different bioenergy uses such as transportation fuels, electricity and heat production. *Assesses emerging fields such as bio-based chemicals and bio-refineries. *Debates conditions for the mobilization of sustainable bioenergy supply chains and outlines governance systems to support this mobilization. * Dedicated chapters to sustainability governance and emerging tools such as certification systems and standards supporting growth of a sustainable bioenergy industry. *Considers the political, environmental, social and cultural context related to the demand for energy resources, the impact of this demand on the world around us, and the choices and behaviours of consumers. This book will be a vital reference to engineers, researchers and students that need an accessible overview of the bioenergy area. It will also be of high value for politicians, policymakers and industry leaders that need to stay up to date with the state-of-the-art science and technology in this area.

Adsorption through Advanced Nanoscale Materials
Adsorption through Advanced Nanoscale Materials

Author: Chandrabhan Verma

Publisher: Elsevier

Published: 2023-08-22

Total Pages: 729

ISBN-13: 0443184577

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Adsorption through Advanced Nanoscale Materials: Applications in Environmental Remediation brings together the latest developments in the utilization of advanced nanoadsorbents in wastewater treatment, pollution control, removal and remediation, gas separation and other environmental applications. The book begins by providing an overview of absorption, adsorbents and nanoadsorbents, introducing properties, classification, synthesis, characterization, enhancement of adsorption capabilities, principles and advantages and disadvantages of nanoadsorbents. Other sections cover the preparation of advanced nanoadsorbents based on specific materials for wastewater treatment, including adsorbents incorporating carbon nanotubes, graphene and graphene oxide, carbon dots and fullerene, polymer nanocomposites, metal oxides, nanoclay, nanofillers, and filtration membranes. Final sections examine the role of nanoadsorbents in broader environmental applications, including areas such as pollution control and removal and gas separation. Finally, other important considerations are studied, including toxicity and health impact, ecotoxicological effects, commercialization and economic issues, challenges and research gaps, trends, and future opportunities. - Provides in-depth coverage of nanoadsorbents for a range of targeted environmental applications - Covers, in detail, fundamentals such as synthesis methods, characterization and inhibition mechanisms - Addresses key areas such as toxicity, health impact, research gaps, trends and commercialization

Advanced Biofuels
Advanced Biofuels

Author: Juan Carlos Serrano-Ruiz

Publisher: CRC Press

Published: 2015-05-27

Total Pages: 324

ISBN-13: 1771882212

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This title includes a number of Open Access chapters.Sustainability demands that we meet the needs of our present world without compromising the needs of future generations. As a result, sources and methodologies for renewable energy are being urgently investigated. Biomassoffers one of the most readily implemented, low-cost alternatives to fossil

Carbon Nanomaterial-Based Adsorbents for Water Purification
Carbon Nanomaterial-Based Adsorbents for Water Purification

Author: Suprakas Sinha Ray

Publisher: Elsevier

Published: 2020-06-27

Total Pages: 422

ISBN-13: 0128219602

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The deterioration of water quality and unavailability of drinkable water are pressing challenges worldwide. The removal of toxic organic and inorganic pollutants from water is vital for a clean environment, as a response to water scarcity. Adsorption-based water technologies are among the most widely used because of their high efficiency and low cost, without relying on a complex infrastructure. In recent years, carbon nanomaterials (CNMs), such as graphene and derivatives, carbon nanotubes, carbon nanofibers, nanoporous carbon, fullerenes, graphitic carbon nitride, and nanodiamonds have been extensively exploited as adsorbents due to their extraordinary surface properties, ease of modification, large surface area, controlled structural varieties, high chemical stability, porosity, low density, ease of regeneration, and reusability. This book provides a thorough overview of the state of the art in carbon nanomaterials as they are used for adsorption applications in water purifications, as well as addressing their toxicological challenges. This volume primarily explores the fundamentals of adsorption, its mechanical aspects, synthesis and properties of CNMs, and adsorption performances of CNMs and their nanocomposites with organic and inorganic materials. Structural engineering and activation processes produce materials with enhanced adsorptive properties and separation efficiencies. Furthermore, the formation of CNMs with 2D and 3D macro-and microstructures and high porosities is a potential approach to improve adsorption performances and extend CNM use at the industrial level. The book also addresses important issues regarding these adsorbents that potentially affect future research and industrial applications of carbon-based nanoadsorbents in water security. - Presents advances in multifunctional 3D superstructures of carbon nanomaterials and their composites for adsorption applications - Outlines the fundamentals on synthesis and characterization techniques of carbon-based nanostructures and their composites - Assesses the major toxicological challenges in using nanostructured materials as adsorbents for water purification

Applications of Layered Double Hydroxides
Applications of Layered Double Hydroxides

Author: Rajib Lochan Goswamee

Publisher: Nova Science Publishers

Published: 2021-11-29

Total Pages: 407

ISBN-13: 9781685073817

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"Currently, Layered Double Hydroxides (LDH) is a hot area of research on inorganic layered materials. The present book, Applications of Layered Double Hydroxides, edited by Dr. Rjib Lochan Goswamee and Dr. Pinky Saikia, is a collection of articles from various researchers from different parts of the world mainly on structure and property relationships of various types of LDH and their related application prospects. How these application prospects can be related to the most pressing problems of humanity like drug delivery, global warming, green catalysis, electrochemical energy storage and generation etc. are clearly discussed in the articles inside. The book provides a thorough up-to-date review of recent literature on applications of LDH available in the global scientific and technical media. For example, the book lucidly describes the behaviour of LDH nanocarriers in biological fluids, their low cytotoxicity and high levels of cellular internalization, and high drug loading capacity. Similarly, the book examines why hybrid nanocomposites of LDH-MOF are considered promising materials due to their diverse functionality, flexible properties and tailored end-use properties. Likewise, application of LDH in secondary batteries and electro-chemical supercapacitors with a thorough up-to-date review is included in the book. Also, basic research articles on structural properties and measurements of a special class of unique LDH Li-Al-LDHs are included. Editors also have written their own articles on their findings on the prospective application of dispersions of LDH nanocomposites on structured catalysts for green-house gas emission. Overall, the book gives a short glimpse of wonderful opportunities that LDH can provide in solving many global socio-economic problems of today"--