Controlled and Living Polymerizations
Controlled and Living Polymerizations

Author: Krzysztof Matyjaszewski

Publisher: John Wiley & Sons

Published: 2009-09-28

Total Pages: 640

ISBN-13: 9783527324927

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Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis
Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis

Author: Jean-Marie Basset

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 340

ISBN-13: 9400929714

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Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.

Handbook of Transition Metal Polymerization Catalysts
Handbook of Transition Metal Polymerization Catalysts

Author: Ray Hoff

Publisher: John Wiley & Sons

Published: 2018-04-20

Total Pages: 895

ISBN-13: 1119242215

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Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Mesoporous Crystals and Related Nano-Structured Materials
Mesoporous Crystals and Related Nano-Structured Materials

Author: Osamu Terasaki

Publisher: Elsevier

Published: 2004-05-25

Total Pages: 307

ISBN-13: 0080536239

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Mesoporous Crystals and Related Nano-Structures Materials contains the invited lectures to be presented at the symposium on Mesoporous Crystals and Related Nano-Structures Materials, Stockholm, Sweden, June 1-2, 2004. This book highlights the core research that has led to such a fruitful and exciting field. Passing on, first hand, the synthesis of this novel material makes this book an important reference material to researchers young and old.* This book highlights the core research that has led to the fruitful and exciting field of mesoporous materials* It provides an overview of the studies which have led to the discovery of mesoporous materials as well as first preparations of mesoporous materials by researchers across the world* This book not only serves as important reference material but also as a source of scientific inspiration to all researchers working in the field of mesoporous materials

Interfacial Aspects of Multicomponent Polymer Materials
Interfacial Aspects of Multicomponent Polymer Materials

Author: David J. Lohse

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 304

ISBN-13: 1475755597

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In August, 1996, the ACS Division of Polymeric Materials: Science and Engineering hosted a symposium on Interfacial Aspects of Multicomponent Polymer Materials at the Orlando, Florida, American Chemical Society meeting. Over 50 papers and posters were presented. The symposium proper was preceded by a one-day workshop, where the. basics of this relatively new field were developed. This edited book is a direct outcome of the symposium and workshop. Every object in the universe has surfaces and interfaces. A surface is defined as that part of a material in contact with either a gas or a vacuum. An interface is defined as that part of a material in contact with a condensed phase, be it liquid or solid. Surfaces of any substance are different from their interior. The appearance of surface or interfacial tension is one simple manifestation. Polymer blends and composites usually contain very finely divided phases, which are literally full of interfaces. Because interfaces are frequently weak mechanically, they pose special problems in the manufacture of strong, tough plastics, adhesives, elastomers, coatings, and fibers. This book provides a series of papers addressing this issue. Some papers delineate the nature of the interface both chemically and physically. The use of newer instrumental methods and new theories are described. Concepts of interdiffusion and entanglement are developed. Other papers describe state-of-the-art approaches to improving the interface, via graft and block copolymers, direct covalent bonding, hydrogen bonding, and more.

Hairy Nanoparticles
Hairy Nanoparticles

Author: Zhiqun Lin

Publisher: John Wiley & Sons

Published: 2023-06-13

Total Pages: 469

ISBN-13: 3527835865

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Hairy Nanoparticles Authoritative reference summarizing comprehensive knowledge on hairy nanoparticles, their self-assembly, interfacial behavior, and applications in catalysis, biomedicine, lubricant technology, etc. Hairy Nanoparticles provides a comprehensive understanding of the subject, including hairy nanoparticles synthesis, self-assembly (both experiment and simulation), properties, functionalities, and applications. Rendering polymer hairs on the surface of nanoparticles enables hairy nanoparticles to carry a set of intriguing properties. Contributed to by experts in the field and edited by two highly qualified authors, Hairy Nanoparticles includes information on: Hairy nanoparticles via bulk microphase separation of block copolymers and self-assembly of block copolymers in solution Synthesis of monodisperse nanoparticles via block copolymer unimolecular micelles nanoreactors and application of polymer-capped nanoparticles Environmentally responsive well-defined binary mixed homopolymer brush-grafted silica particles and thermoresponsive polymer brush-grafted silica particles Self-assembled morphologies of well-defined binary mixed homopolymer brushes grafted on silica nanoparticles (MBNPs) and computer simulations of the self-assembled morphology of MBNPs Upper critical solution temperature (UCST)-type thermoresponsive poly(alkyl methacrylate)s in SpectraSynTM 4 PAO oil. Providing comprehensive coverage of the subject, Hairy Nanoparticles is an essential introductory resource for scientists and engineers in the fields of chemistry, materials science and engineering, polymer science and engineering, nanobiotechnology, and biomedicine, working in both academia and industry.