Stereochemical and Stereophysical Behaviour of Macrocycles
Stereochemical and Stereophysical Behaviour of Macrocycles

Author: Bozzano G Luisa

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 257

ISBN-13: 044459700X

DOWNLOAD EBOOK

Stereochemical and Stereophysical Behavior of Macrocycles deals with the stereochemical and stereophysical properties of macrocyclic ligands and their coordination compounds. More specifically, the stereochemistry of metallic macrocyclics is discussed, along with the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates. The stereochemical aspects of the macrocycles of second and third row transition elements are also examined. Comprised of three chapters, this volume begins with an introduction to the stereochemistry of metallic macrocyclics as well as their structure, together with the conformation of their chemical rings and the steric effects of their coordination geometry. The next chapter considers the relationship between the thermodynamics and stereochemistry of macrocyclics and cryptates, with particular reference to the macrocyclic and cryptate effect. Cation-ligand interactions and solvent effects upon complex formation are described, along with macrocyclic and macrobicyclic ligands having different donor atoms. The final chapter is devoted to the stereochemical aspects of the macrocycles of transition metal ions, with additional comments on the stereochemistry of copper and nickel in unusual oxidation states. This book will be of interest to inorganic chemists.

Stereochemistry of Coordination Compounds
Stereochemistry of Coordination Compounds

Author: Alexander von Zelewsky

Publisher: John Wiley & Sons

Published: 1996-06-03

Total Pages: 272

ISBN-13: 9780471955993

DOWNLOAD EBOOK

This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.

Macrocyclic Compounds in Analytical Chemistry
Macrocyclic Compounds in Analytical Chemistry

Author: Yu A. Zolotov

Publisher: Wiley-Interscience

Published: 1997-07-15

Total Pages: 456

ISBN-13:

DOWNLOAD EBOOK

Macrocycles are an important class of reagents in modern analytical chemistry because of their high selectivity. Macrocyclic chemistry is still a relatively new field, but as research progresses, the volume of data about macrocycles and their analytical applications continues to grow at a breathtaking pace. Written for analytical chemists who need to keep abreast of state-of-the-art applied macrocyclic chemistry, this groundbreaking volume presents the findings of chemists from around the world who have devoted themselves to the study of macrocycles. Macrocyclic Compounds in Analytical Chemistry covers all classes of macrocyclic compounds. Two chapters that will be of general interest across all analytical specialties are those treating the synthesis of macrocyclic compounds and complexation and selectivity. Other topics covered in detail are: Solvent extractionseparation and subsequent determination of elementsfrom crown ethers and alkali cations to porphyrins and transition metals Sorption and chromatographyincludes examples from most chromatographic techniques Ion-selective electrodes Separation and determination of organic compoundscovers both fundamental and analytical uses of host-guest complexation Macrocyclic Compounds in Analytical Chemistry is a valuable reference for research and practicing analytical chemists as well as inorganic chemists specializing in hydrometallurgy and extraction. It will also be of interest to organic and theoretical chemists interested in the practical applications of organic, synthetic macrocyles. This is the first book devoted to the macrocyclic chemistry research conducted between the 1960s and the 1990s. Covering all classes of macrocyclic compounds, this groundbreaking volume presents the findings of chemists from around the world who have devoted themselves to the study of macrocycles. An indispensable reference for research and practicing analytical chemists, Macrocyclic Compounds in Analytical Chemistry reports previously unpublished findings concerning a wide range of topics, including: Macrocyclic synthesis Complexation and selectivity Solvent extraction and separation Sorption and chromatography Ion-selective electrodes Separation and determination of organic compounds