Statistical Modeling and Optimization of Nuclear Waste Vitrification

Statistical Modeling and Optimization of Nuclear Waste Vitrification

Author: Todd E. Combs

Publisher:

Published: 1997-03-01

Total Pages: 175

ISBN-13: 9781423568346

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This thesis describes the development of a methodology to minimize the cost of vitrifying nuclear waste. Pacific Northwest Laboratory (PNL) regression models are used as baseline equations for modeling glass properties such as viscosity, electrical conductivity, and two types of durability. Revised PNL regression models are developed that eliminate insignificant variables from the original models. The Revised PNL regression model for electrical conductivity is shown to better predict electrical conductivity than the original PNL regression model. Neural networks are developed for viscosity and the two types of durability, PCT-B and MCC-1 B. The neural network models are shown to outperform every PNL and Revised PNL regression model in terms of predicting property values for viscosity, PCT-B, and MCC-1 B. The combined Neural Network/Revised PNL 2nd order electrical conductivity models are shown to be the best classifiers of nuclear waste glass, i.e. they have the highest probability of classifying a vitrified waste form as glass when it actually did produce glass in the laboratory. Finally, five nonlinear programs are developed with constraints containing: (1) the PNL original 1st order models, (2) the PNL original 2nd order models, (3) the Revised PNL 1st order models, (4) the Revised PNL 2nd order models, and (5) the Neural Network/Revised PNL 2nd order electrical conductivity models. The Neural Network/Revised PNL 2nd order electrical conductivity nonlinear program is shown to minimize the total expected cost of vitrifying nuclear waste glass. This nonlinear program allows DOE to minimize its risk and cost of high-level nuclear waste vitrification.


Towards Optimization of Nuclear Waste Glass

Towards Optimization of Nuclear Waste Glass

Author:

Publisher:

Published: 1994

Total Pages: 11

ISBN-13:

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Vitrification of both low- and high-level wastes from 177 tanks at Hanford poses a great challenge to glass makers, whose task is to formulate a system of glasses that are acceptable to the federal repository for disposal. The enormous quantity of the waste requires a glass product of the lowest possible volume. The incomplete knowledge of waste composition, its variability, and lack of an appropriate vitrification technology further complicates this difficult task. A simple relationship between the waste loading and the waste glass volume is presented and applied to the predominantly refractory (usually high-activity) and predominantly alkaline (usually low-activity) waste types. Three factors that limit waste loading are discussed, namely product acceptability, melter processing, and model validity. Glass formulation and optimization problems are identified and a broader approach to uncertainties is suggested.


Statistical Sensitivity Analysis of a Simple Nuclear Waste Repository Model

Statistical Sensitivity Analysis of a Simple Nuclear Waste Repository Model

Author:

Publisher:

Published: 1980

Total Pages:

ISBN-13:

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This report represents a preliminary step in what should be a comprehensive sensitivity analysis of the modeling of a nuclear waste repository. The purpose of the complete analysis will be to determine which modeling parameters and physical data are most important in determining key design performance criteria and then to obtain the uncertainty in the design for safety considerations. The theory for a statistical screening design methodology is developed for later use in the overall program. The theory was applied to the test case of determining the relative importance of the sensitivity of near field temperature distribution in a single-level salt repository to modeling parameters. The exact values of the sensitivities to these physical and modeling parameters were then obtained using direct methods of recalculation. The sensitivity coefficients found to be important for the sample problem were thermal loading, distance between the spent fuel canisters and their radius. Other important parameters were those related to salt properties at a point of interest in the repository. In particular, the screening methodology singled out four parameters related to the salt as having high sensitivities: salt conductivity, heat capacity, and density, and initial temperature of salt at the point of interest. These predictions of the screening theory were confirmed by direct recalculations which also reveal the time behavior of these sensitivities. It was found that the sensitivities of thermal loading, distance between the fuel canisters, their radius and salt density and heat capacity increase (in absolute value) during the 50-year period studied. The sensitivity of the initial temperature decreases (in absolute value) whereas the sensitivity of the salt conductivity is important at the time the temperature of the salt is equal to the response temperature. It was found that nonlinearity effects of the input parameters on the responses are negligible.


Process Simulation and Statistical Approaches for Validating Waste Form Qualification Models

Process Simulation and Statistical Approaches for Validating Waste Form Qualification Models

Author:

Publisher:

Published: 1989

Total Pages:

ISBN-13:

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This report describes recent progress toward one of the principal objectives of the Nuclear Waste Treatment Program (NWTP) at the Pacific Northwest Laboratory (PNL): to establish relationships between vitrification process control and glass product quality. during testing of a vitrification system, it is important to show that departures affecting the product quality can be sufficiently detected through process measurements to prevent an unacceptable canister from being produced. Meeting this goal is a practical definition of a successful sampling, data analysis, and process control strategy. A simulation model has been developed and preliminarily tested by applying it to approximate operation of the West Valley Demonstration Project (WVDP) vitrification system at West Valley, New York. Multivariate statistical techniques have been identified and described that can be applied to analyze large sets of process measurements. Information on components, tanks, and time is then combined to create a single statistic through which all of the information can be used at once to determine whether the process has shifted away from a normal condition.


Strategy and Methodology for Radioactive Waste Characterization

Strategy and Methodology for Radioactive Waste Characterization

Author: International Atomic Energy Agency

Publisher: IAEA

Published: 2007

Total Pages: 188

ISBN-13:

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Over the past decade significant progress has been achieved in the development of waste characterization and control procedures and equipment as a direct response to ever-increasing requirements for quality and reliability of information on waste characteristics. Failure in control procedures at any step can have important, adverse consequences and may result in producing waste packages which are not compliant with the waste acceptance criteria for disposal, thereby adversely impacting the repository. The information and guidance included in this publication corresponds to recent achievements and reflects the optimum approaches, thereby reducing the potential for error and enhancing the quality of the end product. -- Publisher's description.


Introduction to Applied Optimization

Introduction to Applied Optimization

Author: Urmila Diwekar

Publisher: Springer Science & Business Media

Published: 2013-03-09

Total Pages: 342

ISBN-13: 1475737459

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This text presents a multi-disciplined view of optimization, providing students and researchers with a thorough examination of algorithms, methods, and tools from diverse areas of optimization without introducing excessive theoretical detail. This second edition includes additional topics, including global optimization and a real-world case study using important concepts from each chapter. Introduction to Applied Optimization is intended for advanced undergraduate and graduate students and will benefit scientists from diverse areas, including engineers.


An Introduction to Nuclear Waste Immobilisation

An Introduction to Nuclear Waste Immobilisation

Author: Michael I. Ojovan

Publisher: Elsevier

Published: 2010-07-07

Total Pages: 334

ISBN-13: 0080455719

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Safety and environmental impact is of uppermost concern when dealing with the movement and storage of nuclear waste. The 20 chapters in 'An Introduction to Nuclear Waste Immobilisation' cover all important aspects of immobilisation, from nuclear decay, to regulations, to new technologies and methods. Significant focus is given to the analysis of the various matrices used in transport: cement, bitumen and glass, with the greatest attention being given to glass. The last chapter concentrates on the performance assessment of each matrix, and on new developments of ceramics and glass composite materials, thermochemical methods and in-situ metal matrix immobilisation. The book thoroughly covers all issues surrounding nuclear waste: from where to locate nuclear waste in the environment, through nuclear waste generation and sources, treatment schemes and technologies, immobilisation technologies and waste forms, disposal and long term behaviour. Particular attention is paid to internationally approved and worldwide-applied approaches and technologies.* Each chapter focuses on a different matrix used in nuclear waste immobilisation: Cement, bitumen, glass and new materials.* Keeps the most important issues surrounding nuclear waste – such as treatment schemes and technologies, and disposal - at the forefront.