This revised and updated Second Edition of the best-selling reference/text is essential reading for students and scientists who seek a thorough and practical introduction to the field of polymer spectroscopy. Eleven chapters cover the fundamental aspects and experimental applications of the primary spectroscopic methods. The advantages and disadvantages of the various techniques for particular polymer systems are also discussed. The goal of the author is not to make the reader an expert in the field, but rather to provide enough information about the different spectroscopic methods that the reader can determine how the available techniques can be used to solve a particular polymer problem. This Second Edition contains new and updated information on techniques in IR and NMR, as well as an all-new chapter on Mass Spectrometry.
Based on the authors ́ extensive experimental experience, NMR Spectroscopy of Polymers explains the practical use of NMR spectroscopy in polymer chemistry.
Spectroscopy of Polymer Nanocomposites covers all aspects of the spectroscopic characterization of polymer nanocomposites. More than 25 spectroscopy characterization techniques – almost all used in materials science – are treated in the book, with discussion of their potentialities and limitations. By comparing the techniques with each other and presenting the techniques together with their specific application areas, the book provides scientists and engineers the information needed for solving specific problems and choosing the right technique for analyzing the material structure. From this, the dispersion structure of fillers, property relations and filler-polymer interactions can be determined, and, ultimately, the right materials can be chosen for the right applications. Besides the techniques and structure-property relations, aspects covered include: phase segregation of filler particles, filler agglomeration and deagglomeration, filler dispersion, filler-polymer interactions, surfaces and interfaces. The book also examines recent developments, as well as unresolved issues and new challenges, in the characterization of surfaces and interfaces in polymer nanocomposites. This handpicked selection of topics, and the combined expertise of contributors from industry, academia, government and private research organizations across the globe, make this survey an outstanding reference source for anyone involved in the field of polymer nanocomposites in academia or industry. - Provides comprehensive coverage of spectroscopy techniques for analyzing polymer nanocomposites - Enables researchers and engineers to choose the right technique and make better materials decisions in research and a range of industries - Presents the fundamentals, information on structure-property relations, and all other aspects relevant for understanding spectroscopic analyses of nanoreinforced polymers and their applications
An insightful exploration of cutting-edge spectroscopic techniques in polymer characterization In Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications, a team of distinguished chemists delivers a comprehensive exploration of the vast potential of spectroscopic characterization techniques in polymer research. The book offers a concise outline of the principles, advantages, instrumentation, experimental techniques, and noteworthy applications of cutting-edge spectroscopy. Covering a wide range of polymers, from nylon to complex polymeric nanocomposites, the author presents recent developments in polymer science to polymer, analytical, and material chemists, assisting them in keeping track of the progress in modern spectroscopy. Spectroscopic Techniques for Polymer Characterization contains contributions from pioneers in modern spectroscopic techniques from around the world. The included materials bridge the gap between spectroscopists, polymer scientists, and engineers in academia and industry. The book also offers: A thorough introduction to the progress in spectroscopic techniques, including polymer spectroscopy and near-infrared spectroscopy Comprehensive explorations of topical polymers studied by spectroscopy, including polymer thin films, fluoropolymers, polymer solutions, conductive polymers Practical discussions of infrared imaging, near-infrared imaging, two-dimensional correlation spectroscopy, and far-ultraviolet spectroscopy In-depth examinations of spectroscopic studies of weak hydrogen bonding in polymers Spectroscopic Techniques for Polymer Characterization: Methods, Instrumentation, Applications is a must-read reference for polymer, analytical, and physical chemists, as well as materials scientists and spectroscopists seeking a one-stop resource for polymer characterization using spectroscopic analyses.
Describes the theory and practice of infrared and Raman spectroscopy as applied to the study of the physical and chemical characteristics of polymers. Its purpose is to give the beginning researcher in the field a firm foundation and a starting point for the study of more advanced literature. To this end the book concentrates on the fundamentals of the theory and nomenclature, and on the discussion of well-documented illustrations of these fundamental principles, including many now-classic studies in the subject. No previous knowledge of either polymers or vibrational spectroscopy is assumed.
Applications of Polymer Spectroscopy focuses on the use of spectroscopy for the determination of polymer structure. This book is divided into three general areas of spectroscopy: nuclear magnetic resonance (NMR) spectroscopy, infrared spectroscopy, and mass spectroscopy. This text is comprised of 16 chapters and begins with a discussion on the applications of NMR spectroscopy, including carbon-13 NMR, proton NMR, and fluorine-19 NMR. The next section considers infrared spectroscopy, with special consideration to the Fourier transform method and the dynamic method of handling the examination of ...
In this book, measurements using vibrational spectroscopy techniques for both the chemical and physical characteristics of polymers are described, alongside chapters covering spectra-structure correlations and spectra calculation. Special chapters deal with composites and conducting polymers, while others discuss the role of vibrational spectroscopy in understanding polymer weathering and degradation, and determining the optical, dielectric and solar and thermal properties of polymers. Dichroism measurement methods, important in understanding product performance, are covered, as well as practical methods for determining molecular orientation; linear, biaxial and trichroic determinations for polymers, as are dynamic measurement systems.
Thirty years ago, Zavoisky, in Moscow (USSR), reported the first successful experi mental observations of the ESR phenomenon. Its application to polymer problems began about 20 years ago. ESR belongs to the most specific and useful methods in the study of polymer reactions. The main purpose of this book is to collect the present available information on the applications of electron spin resonance (ESR) spectroscopy in polymer research. The book has been written both for those who want an introduction to this field, and for those who are aheady familiar with ESR and are interested in application to polymers. Therefore, the fundamental principles of ESR spectroscopy are first out lined, the experimental methods including computer applications are described in more detail, and the main emphasis is on the application of ESR methods to polymer problems. Many results obtained are only briefly treated for lack of space. The authors hope that this book will provide a useful source of information by giving a coherent treatment and extensive references to original papers, reviews, and discussions in monographs and books. In this way we hope to encourage polymer chemists, organic chemists, biochemists, physicists, and material scientists to apply ESR methods to their research problems.
This resource on the primary spectroscopic methods of polymer characterization is written by a polymer expert with 25 years of teaching and research experience. The book offers a background in the fundamental and experimental aspects and applications of vibrational and NMR techniques.
A collection of infrared and Raman spectra of 500 natural and synthetic polymers of industrial importance is presented in this book. A large variety of compounds are included, starting with linear polyolefins and finishing with complex biopolymers and related compounds. The spectra were registered using Infrared Fourier Transform Spectrometers in the laboratory of the All-Russia Institute of Forensic Sciences. The IR and Raman spectra are presented together on the same sheet. The accompanying data include general and structure formulae, CAS register numbers, and sample preparation conditions.Features of this book:• Continues the long tradition of publishing specific and standard data of new chemical compounds.• For low-molecular weight substances, complementary IR and Raman spectra are featured on the same sample and printed on the same page. This "fingerprint" data allows the substance of the sample to be identified without doubt.• An important feature of this unique collection of data is the increase in the identification precision of unknown substances.• Peak tables are available in digital (ASCII) format, on a diskette delivered with the book. This allows the user to search for unknowns.• All the spectra in the collection are base-line corrected.This book will be of interest to scientists involved in the synthesis of new polymeric materials, polymer identification, and quality control. Libraries of scientific institutes, research centers, and universities involved in vibrational spectroscopy will also find this collection invaluable.
