This is the first book to address the hot topic of functional silica gels and their applications. Originally used mainly in chromatography, specialized silica gels have evolved into crucially important functional nanomaterials suitable for use in, amongst other things, chemical synthesis, analysis, purification, surface protection and drug release. It is estimated that the world's current 1 billion dollar market for sol-gels (mostly silica-based) will grow by more than 5% per year from 2006 to 2011. Actually, as many revolutionary products are now reaching the market, it will increase much faster. Commercial applications include glasses, paints, catalysts and fragrances. Medical uses include the delivery of vitamins, hormones and acne treatments and the synthesis of the powerful anticancer drug, taxol. Sol-gel technology also forms the basis of the MetaChip, thanks to which potential new drugs can be identified rapidly and simultaneously. With content relevant to both scientific and commercial viewpoints, the book will interest researchers and undergraduates as well as managers and consultants in the chemical industry. Those from an industrial background will gain a clear picture of what this technology is all about and how it can be used to solve their specific problems. All readers will benefit from the clear, concise style and consistent treatment of topics. The book demonstrates how chemists synthesize, from the bottom-up, tailor-made (nano)materials of immense practical importance spanning the fields of chemistry, physics, materials science, engineering, biology and medicine. It also shows how the versatility of silica gels results from their physical and chemical properties. An updated outlook on new commercial products, and the companies which make them, greatly adds relevance and practical value to the text.
Chemistry of Silica and Zeolite-Based Materials covers a wide range of topics related to silica-based materials from design and synthesis to applications in different fields of science and technology. Since silica is transparent and inert to the light, it is a very attractive host material for constructing artificial photosynthesis systems. As an earth-abundant oxide, silica is an ideal and basic material for application of various oxides, and the science and technology of silica-based materials are fundamentally important for understanding other oxide-based materials. The book examines nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, photonics, photosensors, photovoltaics, energy, environmental sciences, drug delivery, and health. Written by a highly experienced and internationally renowned team from around the world, Chemistry of Silica and Zeolite-Based Materials is ideal for chemists, materials scientists, chemical engineers, physicists, biologists, biomedical sciences, environmental scientists, toxicologists, and pharma scientists. --- "The enormous versatility of silica for building a large variety of materials with unique properties has been very well illustrated in this book.... The reader will be exposed to numerous potential applications of these materials – from photocatalytic, optical and electronic applications, to chemical reactivity in confined spaces and biological applications. This book is of clear interest not only to PhD students and postdocs, but also to researchers in this field seeking an understanding of the possible applications of meso and microporous silica-derived materials." - Professor Avelino Corma, Institute of Chemical Technology (ITQ-CSIC) and Polytechnical University of Valencia, Spain - Discusses the most important advances in various fields using silica materials, including nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, and other topics - Written by a global team of experts from a variety of science and technology disciplines - Ideal resource for chemists, materials scientists, and chemical engineers working with oxide-based materials
This book is the second volume of two volumes on cyclodextrins published in the series Environmental Chemistry for a Sustainable World. This volume focuses on cyclodextrin applications. The first chapter by Divya Arora and Sundeep Jaglan presents cyclodextrin-based carriers for delivery of dietary phytochemicals. The second chapter by Éva Fenyvesi et al. describes the interactions of steroids with cyclodextrins and their applications to pharmaceuticals, food, biotechnology and environment. Nazli Erdoğar and Erem Bilensoy discuss cyclodextrin-based nanosystems in targeted cancer therapy. Miriana Kfoury et al. review the use of cyclodextrins for essential oils applications in chapter 4. Hiroshi Ikeda demonstrates in chapter 5 that chromophore-appended cyclodextrins are effective for chemosensors to detect organic molecules by fluorescence or absorbance changes. Then Grégorio Crini et al. describe silica materials-containing cyclodextrin for pollutant removal. The final chapter by Chang-Chun Ling et al. summarizes the synthesis and characterization of supramolecular liquid crystals based on cyclodextrins and their applications.
Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.
Offering a materials science point of view, the author covers the theory and practice of adsorption and diffusion applied to gases in microporous crystalline, mesoporous ordered, and micro/mesoporous amorphous materials. Examples used include microporous and mesoporous molecular sieves, amorphous silica, and alumina and active carbons, akaganeites, prussian blue analogues, metal organic frameworks and covalent organic frameworks. The use of single component adsorption, diffusion in the characterization of the adsorbent surface, pore volume, pore size distribution, and the study of the parameters characterizing single component transport processes in porous materials are detailed.
The development of nanomaterials plays a fundamental role in current and future technology applications, particularly nanomaterials that have multiple functionalities. This book provides a broad overview of the effect of nanostructuring in the multifunctionality of different widely studied nanomaterials. This book is divided into four sections constituting a road map that groups materials sharing certain types of nanostructuring, including nanoporous, nanoparticled, 2D laminar nanomaterials, and computational methods for characterizations of nanostructures. This structured approach in nanomaterials research will serve as a valuable reference material for chemists, (bio)engineers, physicists, nanotechnologists, undergraduates, and professors.
The current textbook is an excellent inroduction to the chemistry of the non-metallic elements. The book begins by reviewing the key theoretical concepts of chemical bonding and the properties of different bonding types. Subsequent chapters are focused on reactions, structures and applications of the non-metallic compounds. Combining careful pedagogy and clear writing style, the textbook is a must-have for students studying inorganic chemistry.
Functionalized nanomaterials have extremely useful properties, which can outperform their conventional counterparts because of their superior chemical, physical, and mechanical properties and exceptional formability. They are being used for the development and innovation in a range of industrial sectors. However, the use of functionalized nanomaterials is still in its infancy in many industrial settings. Functionalized nanomaterials have the potential to create cheaper and more effective consumer products and industrial processes. However, they also could have adverse effects on the environment, human health, and safety, and their sustainability is questionable, if used incorrectly. This book discusses the opportunities and challenges of using functionalized nanomaterials in a variety of major industrial sectors. Handbook of Functionalized Nanomaterials for Industrial Applications provides a concise summary of the major applications of functionalized nanomaterials in industry today. It covers the enhancements in industrial techniques and processes, due to functionalized nanomaterials, showing how they substantially improve the performance of existing procedures, and how they can deliver exciting consumer products more cheaply. Emphasis is given to greener approaches, leading to more sustainable products and devices. The legal, economical, and toxicity aspects of functionalized nanomaterials are also discussed in detail.