Miktoarm Star Polymers

Miktoarm Star Polymers

Author: Ashok Kakkar

Publisher: Royal Society of Chemistry

Published: 2017-04-13

Total Pages: 241

ISBN-13: 1788010426

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The term ‘miktoarm polymers’ refers to asymmetric branched macromolecules, a relatively new entry to the macromolecular field. Recent advances in their synthesis and intriguing supramolecular chemistry in a desired medium has seen a fast expansion of their applications. The composition of miktoarm polymers can be tailored and even pre-defined to allow a desired combination of functions, meaning polymer chemists can have complete control of the overall architecture of these macromolecules. By carefully selecting the composition, they can create supramolecular structures with intriguing properties, particularly for applications in biology. Miktoarm Star Polymers features chapters from experts actively working in this field, and provides the reader with a unique introduction to the fundamental principles of this exciting macromolecular system. Topics covered include the design, synthesis, characterization, self-assembly and applications of miktoarm polymers. The book is an excellent overview and up to date guide to those working in research in polymer chemistry, materials science, and polymers for medical applications.


Azo Polymers

Azo Polymers

Author: Xiaogong Wang

Publisher: Springer

Published: 2016-10-19

Total Pages: 238

ISBN-13: 366253424X

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This book explores functional polymers containing aromatic azo chromophores in side-chain, main-chain and other parts of their structures, known as azo polymers and which share common photoresponsive properties. It focuses on the molecular architecture of azo polymers, the synthetic methods and their most important functions, such as photoinduced birefringence and dichroism, surface-relief-grating (SRG) formation, and light-driven deformation of liquid crystal elastomers. It combines a general survey of the subject and in-depth discussions of each topic, including numerous illustrations, figures, and photographs. Offering a balance between an introduction to the core concepts and a snapshot of hot and emerging topics, it is of interest to graduate students and researchers working in this and related fields. Xiaogong Wang is a Professor at the Department of Chemical Engineering, Tsinghua University, China.


Materials Nanoarchitectonics

Materials Nanoarchitectonics

Author: Katsuhiko Ariga

Publisher: Elsevier

Published: 2023-12-07

Total Pages: 648

ISBN-13: 0323994733

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Materials Nanoarchitectonics: From Integrated Molecular Systems to Advanced Devices provides the latest information on the design and molecular manipulation of self-organized hierarchically structured systems using tailor-made nanoscale materials as structural and functional units. The book is organized into three main sections that focus on molecular design of building blocks and hybrid materials, formation of nanostructures, and applications and devices. Bringing together emerging materials, synthetic aspects, nanostructure strategies, and applications, the book aims to support further progress, by offering different perspectives and a strong interdisciplinary approach to this rapidly growing area of innovation. This is an extremely valuable resource for researchers, advanced students, and scientists in industry, with an interest in nanoarchitectonics, nanostructures, and nanomaterials, or across the areas of nanotechnology, chemistry, surface science, polymer science, electrical engineering, physics, chemical engineering, and materials science. - Offers a nanoarchitectonic perspective on emerging fields, such as metal-organic frameworks, porous polymer materials, or biomimetic nanostructures - Discusses different approaches to utilizing "soft chemistry" as a source for hierarchically organized materials - Offers an interdisciplinary approach to the design and construction of integrated chemical nano systems - Discusses novel approaches towards the creation of complex multiscale architectures


Self-Assembly of Nanostructures

Self-Assembly of Nanostructures

Author: Stefano Bellucci

Publisher: Springer Science & Business Media

Published: 2011-10-27

Total Pages: 278

ISBN-13: 1461407427

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This is the third volume in a series of books on selected topics in Nanoscale Science and Technology based on lectures given at the well-known Istituto Nazionale di Fisica Nucleare (INFN) schools of the same name. The present set of notes stems in particular from the participation and dedication of prestigious lecturers, such as Nunzio Motta, Fulvia Patella, Alexandr Toropov, and Anna Sgarlata. All lectures have been carefully edited and reworked, taking into account extensive follow-up discussions. A tutorial lecture by Motta et al. presents the analysis of the Poly(3-hexylthiophene) self assembly on carbon nanotubes and discusses how the interaction between the two materials forms a new hybrid nanostructure, with potential application to future solar cells technology. In their contribution, Patella et al. review quantum dots of III-V compounds, which offer appealing perspectives for more sophisticated applications in new generation devices such as single-photon emitters for nano-photonics and quantum computing. Focusing on self-assembled quantum dots, the chapter by Alexandr Toropov et al. provides a comprehensive review of some important aspects in the formation of quantum dots and presents the results of the authors’ extensive investigation of the features of droplet epitaxy. The fourth contribution, by Sgarlata et al., focuses on recent progress toward controlled growth of self-assembled nanostructures, dealing with the shaping, ordering and localization in Ge/Si heteroepitaxy and reviewing recent results on the self-organization of Ge nanostructures at Si surfaces.


Amphiphilic Block Copolymers

Amphiphilic Block Copolymers

Author: P. Alexandridis

Publisher: Elsevier

Published: 2000-10-18

Total Pages: 449

ISBN-13: 0080527108

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It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.


Out-of-Equilibrium (Supra)molecular Systems and Materials

Out-of-Equilibrium (Supra)molecular Systems and Materials

Author: Nicolas Giuseppone

Publisher: John Wiley & Sons

Published: 2021-03-30

Total Pages: 448

ISBN-13: 3527821988

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A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.


Self-Assembled Structures

Self-Assembled Structures

Author: Jingcheng Hao

Publisher: CRC Press

Published: 2016-04-19

Total Pages: 250

ISBN-13: 1439840849

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Self-assembly is a process in which a disordered system forms an organized structure without external direction. Examples include the formation of molecular crystals, lipid bilayers, and polymer brushes. This book reviews the fabrication and use of various self-assembled materials. In particular, the author pays special attention to self-assembled structures when in solution and in contact with surfaces, as such interactions can have a pronounced impact on their properties and applications. The text covers bulk solution and surfaces, assembled structures, colloid particles, polymer capsules, carbon nanotubes, as well as layer-by-layer assembly techniques.


Self-Healing Polymers

Self-Healing Polymers

Author: Wolfgang H. Binder

Publisher: John Wiley & Sons

Published: 2013-03-29

Total Pages: 638

ISBN-13: 3527670203

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Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.


Nanotechnology and Functional Materials for Engineers

Nanotechnology and Functional Materials for Engineers

Author: Yaser Dahman

Publisher: Elsevier

Published: 2017-01-13

Total Pages: 284

ISBN-13: 0323524664

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Nanotechnology and Functional Materials for Engineers focuses on key essentials and examples across the spectrum of nanomaterials as applied by engineers, including nanosensors, smart nanomaterials, nanopolymers, and nanotubes. Chapters cover their synthesis and characteristics, production methods, and applications, with specific sections exploring nanoelectronics and electro-optic nanotechnology, nanostructures, and nanodevices. This book is a valuable resource for interdisciplinary researchers who want to learn more about how nanomaterials are used in different types of engineering, including electrical, chemical, and biomedical. - Offers in-depth information on a variety of nanomaterials and how they are used for different engineering applications - Provides an overview of current research and suggests how this will impact future applications - Explores how the unique properties of different nanomaterials make them particularly suitable for specific applications


Self-Assembly of Polymers

Self-Assembly of Polymers

Author: Dmitry Volodkin

Publisher: MDPI

Published: 2020-04-22

Total Pages: 186

ISBN-13: 3039285068

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Nowadays, polymer self-assembly has become extremely attractive for both biological (drug delivery, tissue engineering, scaffolds) and non-biological (packaging, semiconductors) applications. In nature, a number of key biological processes are driven by polymer self-assembly, for instance protein folding. Impressive morphologies can be assembled from polymers thanks to a diverse range of interactions involved, e.g., electrostatics, hydrophobic, hots-guest interactions, etc. Both 2D and 3D tailor-made assemblies can be designed through modern powerful techniques and approaches such as the layer-by-layer and the Langmuir-Blodgett deposition, hard and soft templating. This Special Issue highlights contributions (research papers, short communications, review articles) that focus on recent developments in polymer self-assembly for both fundamental understanding the assembly phenomenon and real applications.