Remote C-H Bond Functionalizations
Remote C-H Bond Functionalizations

Author: Debabrata Maiti

Publisher: John Wiley & Sons

Published: 2021-04-26

Total Pages: 450

ISBN-13: 3527346678

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A guide to contemporary advancements in the field of distal C-H functionalizations An important and dynamic topic within the modern field of organic synthesis, selective functionalization of C-H bonds can be used in a variety of applications across the pharmaceutical and agrochemical industries. Remote C-H Bond Functionalizations presents an inclusive account of the most recent developments and potential applications of performing variegated functionalizations selectively at the distal positions of organic compounds. Featuring contributions by an international team of experts, this authoritative volume provides deep insight into distal functionalizations, including detailed discussion of mechanisms, the engineering of templates, and the design of strategies. The text covers a diverse range of topics including C-H functionalization of palladium/norbornene catalysis, ruthenium-catalyzed remote functionalization, the non-directed distal C(sp2)-H, functionalization, transition metal catalyzed distal para-selective C-H functionalization, and much more. Reviewing contemporary advancements in the field while laying the foundation for future research, this important resource: Provides the most recent research and thorough coverage of the subject available in a single volume Offers practical information on C-H functionalizations in various industries Includes an up-to-date introduction to distal C-H functionalizations Remote C-H Bond Functionalizations is a must-read for every synthetic chemist, including chemists working with organometallics, organic chemists and researchers, and industrial chemists.

Remote C-H Bond Functionalizations
Remote C-H Bond Functionalizations

Author: Debabrata Maiti

Publisher: John Wiley & Sons

Published: 2021-01-11

Total Pages: 450

ISBN-13: 3527824146

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A guide to contemporary advancements in the field of distal C-H functionalizations An important and dynamic topic within the modern field of organic synthesis, selective functionalization of C-H bonds can be used in a variety of applications across the pharmaceutical and agrochemical industries. Remote C-H Bond Functionalizations presents an inclusive account of the most recent developments and potential applications of performing variegated functionalizations selectively at the distal positions of organic compounds. Featuring contributions by an international team of experts, this authoritative volume provides deep insight into distal functionalizations, including detailed discussion of mechanisms, the engineering of templates, and the design of strategies. The text covers a diverse range of topics including C-H functionalization of palladium/norbornene catalysis, ruthenium-catalyzed remote functionalization, the non-directed distal C(sp2)-H, functionalization, transition metal catalyzed distal para-selective C-H functionalization, and much more. Reviewing contemporary advancements in the field while laying the foundation for future research, this important resource: Provides the most recent research and thorough coverage of the subject available in a single volume Offers practical information on C-H functionalizations in various industries Includes an up-to-date introduction to distal C-H functionalizations Remote C-H Bond Functionalizations is a must-read for every synthetic chemist, including chemists working with organometallics, organic chemists and researchers, and industrial chemists.

C-H Activation
C-H Activation

Author: Jin-Quan Yu

Publisher: Springer

Published: 2010-06-16

Total Pages: 400

ISBN-13: 3642123562

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Table of Contents - Synthesis in the Key of Catellani: Norbornene-Mediated ortho C–H Functionalization - Mechanistic Considerations in the Development and Use of Azine, Diazine and Azole N-Oxides in Palladium-Catalyzed Direct Arylation - Palladium and Copper Catalysis in Regioselective, Intermolecular Coupling of C–H and C–Hal Bonds - Pd-Catalyzed C–H Bond Functionalization on the Indole and Pyrrole Nucleus - Remote C–H Activation via Through-Space Palladium and Rhodium Migrations - Palladium-Catalyzed Aryl–Aryl Bond Formation Through Double C–H Activation - Palladium-Catalyzed Allylic C–H Bond Functionalization of Olefins - Ruthenium-Catalyzed Direct Arylations Through C–H Bond Cleavages - Rhodium-Catalyzed C–H Bond Arylationof Arenes - Cross-Dehydrogenative Coupling Reactions of sp3-Hybridized C–H Bonds - Functionalization of Carbon–Hydrogen Bonds Through Transition Metal Carbenoid Insertion - Metal-Catalyzed Oxidations of C–H to C–N Bonds

C-H Bond Activation and Catalytic Functionalization I
C-H Bond Activation and Catalytic Functionalization I

Author: Pierre H. Dixneuf

Publisher: Springer

Published: 2015-12-18

Total Pages: 269

ISBN-13: 3319246305

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The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Arene Chemistry
Arene Chemistry

Author: Jacques Mortier

Publisher: John Wiley & Sons

Published: 2015-11-30

Total Pages: 992

ISBN-13: 1118754980

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Organized to enable students and synthetic chemists to understand and expand on aromatic reactions covered in foundation courses, the book offers a thorough and accessible mechanistic explanation of aromatic reactions involving arene compounds. • Surveys methods used for preparing arene compounds and their transformations • Connects reactivity and methodology with mechanism • Helps readers apply aromatic reactions in a practical context by designing syntheses • Provides essential information about techniques used to determine reaction mechanisms

Remote C-H Bond Functionalizations
Remote C-H Bond Functionalizations

Author: Debabrata Maiti

Publisher: John Wiley & Sons

Published: 2021-01-05

Total Pages: 448

ISBN-13: 352782412X

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A guide to contemporary advancements in the field of distal C—H functionalization Remote C—H Bond Functionalizations provides a comprehensive overview on the most recent developments in the field of distal C—H functionalization. The text explores how distal C—H functionalization can be applied in various pharmaceutical and agrochemical industries. With contributions from a noted panel of experts on the topic, the book offers a coherent and comprehensive discussion about different strategies. The contributors cover a broad range of topics including C—H functionalization of palladium/norbornene catalysis, ruthenium-catalyzed remote functionalization, the non-directed distal C(sp2)—H, functionalization, transition metal catalyzed distal para-selective C—H functionalization, and much more. The book also includes information on effective strategies as well as the engineering of templates. Throughout the book, the authors lay the foundations for future research. This important book: Contains the most recent research on one of the most important topics in organic synthesis Provides a broad overview on contemporary advancements in the field of distal C—H functionalization Includes deep insights into distal C—H functionalizations Offers information on applications in various industries Written for organic chemists, chemists working with organometallics, and industrial chemists, Remote C—H Bond Functionalizations presents a systematic compilation of the field.

Synthetic Applications
Synthetic Applications

Author: Rajender S. Varma

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2022-05-09

Total Pages: 454

ISBN-13: 3110730359

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Magnetic nanocatalysts are an important tool for greener catalytic processes due to the ease of their removal from a reaction medium. This book explores different magnetic nanocatalysts, their use in synthesis, and their recyclability. Topics covered include magnetic nanocatalysts for S-S bond formation, N-hetercycle formation, C-heteroatom bond formation, silica-supported catalysts, multicomponent reactions, and their recyclability.

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides
Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides

Author: Anant R. Kapdi

Publisher: Elsevier

Published: 2018-06-04

Total Pages: 360

ISBN-13: 012811293X

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Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties. - Provides synthetic routes for useful nucleoside molecules, information otherwise found only through time-consuming literature searches - Covers metal-mediated and metal-catalyzed cross coupling processes of nucleosides and related compounds - Includes Suzuki-Miyaura, Stille and Sonogashira reactions, as well as C-H bond functionalization - Highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist

Rhodium Catalysis
Rhodium Catalysis

Author: Carmen Claver

Publisher: Springer

Published: 2017-12-15

Total Pages: 291

ISBN-13: 3319666657

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The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbrev iated as Top Organomet Chem and cited as a journal.

Dienamine Catalysis for Organic Synthesis
Dienamine Catalysis for Organic Synthesis

Author: Kengadarane Anebouselvy

Publisher: Royal Society of Chemistry

Published: 2018-03-02

Total Pages: 220

ISBN-13: 1782620907

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In the last decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis. High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis. Building on the momentum of this rapidly expanding research area, Dienamine catalysis for organic synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.