Loaded with practical knowledge, Reactive Polymers Fundamentals and Applications: A Concise Guide to Industrial Polymers comprehensively presents the state-of-art of methods and materials for the formulation of polymeric resins. It is an indispensable tool for chemists, engineers, and manufacturers who use, formulate, and cure raw materials into final products. The text focuses on the chemical modification of properties during the final stage of part fabrication from plastics. Newer applications range from the small scale, such as dental fillings, to industrial processes for batch fabrication. The book covers resin groups in major use in industry and under active research and development.
Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones Offers an indispensable guide for engineers and advanced students alike Provides extensive literature and patent review Reflects a thorough review of all literature published in this area since 2014 Features revised and updated chapters to reflect the latest research in reactive polymers
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume One provides the principles and foundations for the design, development, manufacture and processing of reactive and functional polymers based primarily on biopolymers, polyesters and polyurenthanes. The text provides an in-depth review of updated sources on reactive resins and silicones. In this book, world-renowned researchers have participated, including Dr. Runcang Sun (Associate editor for the journal ‘Carbohydrate Polymers’). With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume Two considers the coupling, crosslinking and grafting reactions to improve the compatibility of reactive and functional polymer blends. In this book, world-renowned researchers have participated, including Dr. Sabu Thomas (Editor-in-chief for the journal ‘Nano-Structures & Nano-Objects’). With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
This volume of Macromolecular Symposia contains papers presented at the 1st International Symposium on "Reactive Polymers in Inhomogeneous Systems, in Melts and at Interfaces" held in Dresden Germany in July 2000. It includes 42 contributions from renowned scientists dealing with topics of current interest in the field of synthesis, characterization and application of reactive and functional polymers. The papers add significantly to the current understanding of the role of reactive polymers in phenomena such as adhesion, colloidal stability, corrosion resistance and biocompatibility - comprehension which is vital for improving the polymer technologies available today and for the development of new applications.
Chemical modification of polymers by reactive modifiers is no longer an academic curiosity but a commercial reality that has delivered a diverse range of speciality materials for niche markets: reactively grafted styrenic alloys, maleated polyolefins, super-tough nylons, silane modified and moisture-cured polyolefins, and thermoplastic elastomers, are but few exam ples of commercial successes. Although the approach of reactive modification of polymers has been largely achieved either in solution or in the solid state (through in situ reactions in polymer melts), it is the latter route that has attracted most attention in the last two decades owing to its flexibility and cost-effective ness. This route, referred to as reactive processing, focuses on the use of suitable reactive modifier(s) and the adoption of conventional polymer processing machinery, an extruder or a mixer, as a chemical reactor, to perform in situ targeted reactions for chemical modification of preformed polymers. This relatively simple, though scientifically highly challenging, approach to reactive modification offers unique opportunities in exploiting various reactive modifiers for the purpose of altering and transforming in a controlled manner the properties of preformed commercial polymers into new/speciality materials with tailor-made properties and custom-designed performance for target applications. Such an economically attractive route constitutes a radical diversion away from the traditional practices of manufacturing new polymers from monomers which involves massive in vestments in sophisticated technologies and chemical plants.
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume Three considers advanced polymeric materials such as electroactive polymers, multi-responsive polymers, shape memory polymers, stimuli responsive polymers, and active and intelligent polymers as topics for analysis. World renowned researchers from Argentina, Austria, China, Egypt, France, India, Iran, Japan, Pakistan, Romania and Spain have participated in this book. With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
Understanding the dynamics of reactive polymer processes allows scientists to create new, high-value, high-performance polymers. This book is an indispensable resource for researchers and practitioners working in this area. It includes coverage of thermoplastics, thermoset and reactive polymers, together with practical industrial processes and modern chemorheological models and tools.
Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume Four considers surface interactions, modifications and reactions, as well as reactive processes for recycling polymers and their biodegradability and compostability. World renowned researchers from Argentina, Austria, China, Egypt, France, Iran, Italy, Nepal and United States have participated in this book. With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.
Although several monographs and reviews have appeared on individual polymers of this type, and their applications and other technical aspects have also been discussed, this is apparently the first book to deal with the physical chemistry of water-soluble synthetic polymers as a group. This collective survey enables their properties and behaviour to be compared, and to be correlated with their molecular structures for predictive purposes. However, this has made it necessary to critically re-appraise much of the earlier fundamental work, so that current discussion of more recent work can be put on ta proper basis. Thus, of the 1800 or so references cited, the middle two-thirds related to the twenty-year period centred on about 1968. Nevertheless, sufficient key recent references have also been included so that the existing ‘state of the art is delineated.
