Reaction Dynamics in the Gas Phase
Author:
Publisher:
Published: 2005
Total Pages: 152
ISBN-13:
DOWNLOAD EBOOKRead and Download eBook Full
Author:
Publisher:
Published: 2005
Total Pages: 152
ISBN-13:
DOWNLOAD EBOOKAuthor: Joel M. Bowman
Publisher:
Published: 2005
Total Pages: 152
ISBN-13:
DOWNLOAD EBOOKAuthor: V.N. Kondratiev
Publisher: Springer Science & Business Media
Published: 2012-12-06
Total Pages: 254
ISBN-13: 3642676081
DOWNLOAD EBOOKThe present monograph appears after the death of Professor V. N. Kondratiev, one of those scientists who have greatly contributed to the foundation of contem porary gas kinetics. The most fundamental idea of chemical kinetics, put for ward at the beginning of the twentieth century and connected with names such as W. Nernst, M. Bodenstein, N. N. Semenov, and C. N. Hinshelwood, was that the complex chemical reactions are in fact a manifestation of a set of simpler elementary reactions involving but a small number of species. V. N. Kondratiev was one of the first to adopt this idea and to start investigations on the elementary chemical reactions proper. These investigations revealed explicitly that every elementary reaction in turn consisted of many elementary events usually referred to as elementary processes. It took some time to realize that an elementary reaction, represented in a very simple way by a macroscopic kinetic equation, can be described on a microscopic level by a generalized Boltzmann equation. Neverheless, up to the middle of the twentieth century, gas kinetics was mainly concerned with the interpretation of complex chemical reactions via a set of elementary reactions. But later on, the situation changed drastically. First, the conditions for reducing microscopic cquations to macroscopic ones were clearly set up. These are essentially based on the fact that the small perturbations of the Maxwell-Boltzmann distribution are caused by the reaction proper.
Author: Ian W. M. Smith
Publisher: Butterworth-Heinemann
Published: 2013-10-22
Total Pages: 400
ISBN-13: 1483161994
DOWNLOAD EBOOKKinetics and Dynamics of Elementary Gas Reactions surveys the state of modern knowledge on elementary gas reactions to understand natural phenomena in terms of molecular behavior. Part 1 of this book describes the theoretical and conceptual background of elementary gas-phase reactions, emphasizing the assumptions and limitations of each theoretical approach, as well as its strengths. In Part 2, selected experimental results are considered to demonstrate the scope of present day techniques and illustrate the application of the theoretical ideas introduced in Part 1. This publication is intended primarily for working kineticists and chemists, but is also beneficial to graduate students.
Author: Mark Brouard
Publisher:
Published: 2023
Total Pages: 0
ISBN-13: 9780191992278
DOWNLOAD EBOOKThis text gives a concise account of the dynamics and kinetics of elementary reactions in the gas phase, and is structured to emphasize the relationship between thermal rate coefficients and the microscopic mechanisms of chemical reactions.
Author: Peter M. Rentzepis
Publisher: Springer Science & Business Media
Published: 2012-12-06
Total Pages: 608
ISBN-13: 9400947348
DOWNLOAD EBOOKThis book contains the formal lectures and contributed papers presented at the NATO Advanced Study Institute on. the Advances in Chemical Reaction Dynamics. The meeting convened at the city of Iraklion, Crete, Greece on 25 August 1985 and continued to 7 September 1985. The material presented describes the fundamental and recent advances in experimental and theoretical aspects of, reaction dynamics. A large section is devoted to electronically excited states, ionic species, and free radicals, relevant to chemical sys tems. In addition recent advances in gas phase polymerization, formation of clusters, and energy release processes in energetic materials were presented. Selected papers deal with topics such as the dynamics of electric field effects in low polar solutions, high electric field perturbations and relaxation of dipole equilibria, correlation in picosecond/laser pulse scattering, and applications to fast reaction dynamics. Picosecond transient Raman spectroscopy which has been used for the elucidation of reaction dynamics and structural changes occurring during the course of ultrafast chemical reactions; propagation of turbulent flames and detonations in gaseousĀ· energetic systems are also discussed in some detail. In addition a large portion of the program was devoted to current experimental and theoretical studies of the structure of the transition state as inferred from product state distributions; translational energy release in the photodissociation of aromatic molecules; intramolecu lar and intraionic dynamic processes.
Author: Sunita Satyapal
Publisher:
Published: 1990
Total Pages: 284
ISBN-13:
DOWNLOAD EBOOKAuthor: Niels E. Henriksen
Publisher: Oxford University Press, USA
Published: 2008
Total Pages: 391
ISBN-13: 0199203865
DOWNLOAD EBOOKThis book deals with a central topic at the interface of chemistry and physics - the understanding of how the transformation of matter takes place at the atomic level. Building on the laws of physics, the book focuses on the theoretical framework for predicting the outcome of chemical reactions. The style is highly systematic with attention to basic concepts and clarity of presentation. Molecular reaction dynamics is about the detailed atomic-level description of chemical reactions. Based on quantum mechanics and statistical mechanics or, as an approximation, classical mechanics, the dynamics of uni- and bi-molecular elementary reactions are described. The book features a detailed presentation of transition-state theory which plays an important role in practice, and a comprehensive discussion of basic theories of reaction dynamics in condensed phases. Examples and end-of-chapter problems are included in order to illustrate the theory and its connection to chemical problems.
Author: Heather Ann Sumner
Publisher:
Published: 2005
Total Pages: 358
ISBN-13:
DOWNLOAD EBOOKAuthor: A. Fontijn
Publisher: Elsevier
Published: 2017-05-04
Total Pages: 711
ISBN-13: 1483291219
DOWNLOAD EBOOKThe book brings together, for the first time, all aspects of reactions of metallic species in the gas phase and gives an up-to-date overview of the field. Reactions covered include those of atomic, other free radical and transient neutral species, as well as ions. Experimental and theoretical work is reviewed and the efforts to establish a closer link between these approaches are discussed. The field is mainly approached from a fundamental point-of-view, but the applied problems which have helped stimulate the interest are pointed out and form the major subject of the final chapters. These emphasize the competition between purely gas-phase and gas-surface reactions.