Kinetics of soil chemical reactions. Methods of obtaining and analyzin kinetic data. Relaxation methods for studying kinetics of soil chemical phenomena. Kinetics of ion sorptionon humic substances. Kinetics of sorption/desorption processes in soils. Modelling nonequilibrium reactions of inorganic solutes in soil columns. Sorption kinetics of organic chemicals: methods, models, and mechanisms.
The kinetics of reactions in soil and aquatic environments is a topic of extreme importance and interest. To properly understand the fate of applied fertilizers, pesticides, and organic pollutants with time, and to thus improve nutrient availability and the quality of our groundwater, one must study kinetics. This is the first compre Demonstrates different kinetic methodologies Shows how reactions on soil and soil constituents can be measured by utilizing different techniques Describes rates and mechanisms of interactions with pesticides and organic pollutants with soil Covers the kinetics of chemical weathering Discusses how to use mathematical modeling and computer simulation to model kinetic reactions
This book develops a unified, comprehensive account of the important chemical processes in soils that can be described by reactions. The perspective taken is that of chemical thermodynamics and kinetics applied to soil systems in detail in order to provide an understanding of phenomena ranging from complexation reactions to colloidal flocculation. Problem sets are included at the end of each chapter.
The topic of this book is the quantitative characterization of the chemical reactions taking place in the soil, as well as the properties of main soil components. The book outlines the physico-chemical and colloid-chemical regularities necessary to the evaluation of soil chemical process; then, the individual reaction types and the mechanism of material transport are discussed in detail. The volume also focuses attention on the properties and rules of soil colloids, the mechanism of the absorption of ion exchange, the chemical and colloid chemical interpretation of soil acidity, the evaluation of the acid-base buffer capacity of the soils, as well as on the principles and methods of the modeling the salt-and ion transport in soils.
Soil Formation deals with qualitative and quantitative aspects of soil formation (or pedogenesis) and the underlying chemical, biological, and physical processes. The starting point of the text is the process - and not soil classification. Effects of weathering and new formation of minerals, mobilisation, transport, and breakdown or immobilisation of dissolved and suspended compounds are discussed. Soil processes and profiles are discussed in relation to the landscape, the geosphere, and the biosphere. Emphasis lies on the universality of soil-forming processes in past and present, and on the soil as a dynamic entity that forms part of the total environment. Complexity of genetic processes in time and space is given much attention. The text gives many examples from literature and places some in a new light. The reader is guided through the subject matter by a large number of questions and problems to help understand and synthesis the material. Answers to all questions are included. This second edition has been updated to reflect recent discoveries. Printing errors have been corrected, and new photographs support the text.
As the author states in his Preface, this book is written at a time when scientific and lay communities recognize that knowledge of environmental chemistry is fundamental in understanding and predicting the fate of pollutants in soils and waters, and in making sound decisions about remediation of contaminated soils. Environmental Soil Chemistry presents the fundamental concepts of soil science and applies them to environmentally significant reactions in soil. Clearly and concisely written for undergraduate and beginning graduate students of soil science, the book is likewise accessible to all students and professionals of environmental engineering and science. Chapters cover background information useful to students new to the discipline, including the chemistry of inorganic and organic soil components, soilacidity and salinity, and ion exchange and redox phenomena. However, discussion also extends to sorption/desorption, oxidation-reduction of metals and organic chemicals, rates of pollutant reactions as well as technologies for remediating contaminated soils. Supplementary reading lists, sample problems, and extensive tables and figures make this textbook accessible to readers. Provides students with both sound contemporary training in the basics of soil chemistry and applications to real-world environmental concerns Timely and comprehensive discussion of important concepts including: Sorption/desorption, Oxidation-reduction of metals and organics, Effects of acidic deposition and salinity on contaminant reactions Boxed sections focus on sample problems and explanations of key terms and parameters Extensive tables on elemental composition of soils, rocks and sediments, pesticide classes, inorganic minerals, and methods of decontaminating soils Clearly written for all students and professionals in environmental science and environmental engineering as well as soil science
Learn the secrets of soil chemistry and its role in agriculture and the environment. Examine the fundamental laws of soil chemistry, how they affect dissolution, cation and anion exchange, and other reactions. Explore how water can form water-bridges and hydrogen bonding, the most common forces in adsorption, chelation, and more. Discover how elect
