Ion-Radical Organic Chemistry

Ion-Radical Organic Chemistry

Author: Zory Vlad Todres

Publisher: CRC Press

Published: 2008-10-20

Total Pages: 496

ISBN-13: 9781420008395

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Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.


Reagents for Radical and Radical Ion Chemistry

Reagents for Radical and Radical Ion Chemistry

Author: David Crich

Publisher: John Wiley & Sons

Published: 2013-05-30

Total Pages: 1874

ISBN-13: 1118634896

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Radicals and radical ions are important intermediates with wide use in organic synthesis. The first book to concentrate on reagents for the creation and use of radicals and radical ions, this new volume in the Handbooks of Reagents for Organic Synthesis series compiles articles taken from the e-eros database, on reagents for use in radical and radical chemistry, to help the chemist in the lab choose the right reagents. Reflecting the enormous growth of radical chemistry over the past ten years, this is an essential guide for all synthetic chemists.


Radical Ionic Systems

Radical Ionic Systems

Author: Anders Lund

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 498

ISBN-13: 9401137501

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It is now more than 20 years since the book "Radical Ions" edited by Kaiser and Kevan appeared. It contained aspects regarding generation, identification, spin density determination and reactivity of charged molecules with an odd number of electrons. New classes of reactive ion radicals have been detected and characterised since then, most notably cation radicals of saturated organic compounds. Trapping of electrons has been found to occur not only in frozen glasses but also in organic crystals. The structure and reactions of anion radicals of saturated compounds have been clarified during the last 20 years. We have asked leading experts in the field to write separate chapters about cation radicals, anion radicals and trapped electrons as well as more complex systems of biological or technological interest. More attention is paid to recent studies of the ions of saturated compounds than to the older and previously reviewed work on aromatic ions. In the case of trapped electrons full coverage is out of the question, and focus is on recent efforts to characterise the solvation structure in ordered and disordered systems.


Electron Spin Resonance Spectroscopy of Organic Radicals

Electron Spin Resonance Spectroscopy of Organic Radicals

Author: Fabian Gerson

Publisher: John Wiley & Sons

Published: 2006-03-06

Total Pages: 479

ISBN-13: 352760524X

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Electron spin resonance spectroscopy is the method used to determine the structure and life expectancy of a number of radicals. Written by Fabian Gerson and Walter Huber, top experts in the field of electron spin resonance spectroscopy, this book offers a compact yet readily comprehensible introduction to the modern world of ESR. Thanks to its comprehensive coverage, ranging from fundamental theory right up to the treatment of all important classes of organic radicals and triplet-state molecules that can be analyzed using ESR spectroscopy, this unique book is suitable for users in both research and industry. Instead of using complex mathematical derivations, the authors present a readily understandable approach to the field by interpreting sample spectra and classifying experimental data. In short, the ideal book for newcomers to the subject and an absolute must-have for everyone confronted with ESR spectroscopy and wanting to become acquainted with this widely-used method of analysis.


Handbook of Computational Chemistry

Handbook of Computational Chemistry

Author: Jerzy Leszczynski

Publisher: Springer Science & Business Media

Published: 2012-01-13

Total Pages: 1451

ISBN-13: 9400707118

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The role the Handbook of Computational Chemistry is threefold. It is primarily intended to be used as a guide that navigates the user through the plethora of computational methods currently in use; it explains their limitations and advantages; and it provides various examples of their important and varied applications. This reference work is presented in three volumes. Volume I introduces the different methods used in computational chemistry. Basic assumptions common to the majority of computational methods based on molecular, quantum, or statistical mechanics are outlined and special attention is paid to the limits of their applicability. Volume II portrays the applications of computational methods to model systems and discusses in detail molecular structures, the modelling of various properties of molecules and chemical reactions. Both ground and excited states properties are covered in the gas phase as well as in solution. This volume also describes Nanomaterials and covers topics such as clusters, periodic, and nano systems. Special emphasis is placed on the environmental effects of nanostructures. Volume III is devoted to the important class of Biomolecules. Useful models of biological systems considered by computational chemists are provided and RNA, DNA and proteins are discussed in detail. This volume presents examples of calcualtions of their properties and interactions and reveals the role of solvents in biologically important reactions as well as the structure function relationship of various classes of Biomolecules.


Chemistry In Microtime: Selected Writings On Flash Photolysis, Free Radicals, And The Excited State

Chemistry In Microtime: Selected Writings On Flash Photolysis, Free Radicals, And The Excited State

Author: George Porter

Publisher: World Scientific

Published: 1997-04-01

Total Pages: 558

ISBN-13: 1783262702

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This volume contains a selection of the pioneering papers by Nobel Laureate George Porter. It outlines his work on fast reactions, occurring in times from milliseconds to femtoseconds, in photochemistry, photosynthesis and solar energy, and includes the papers which led to the award of the Nobel Prize in Chemistry in 1967 for his work on flash photolysis. Lord Porter, President of the Royal Society from 1985 to 1990, is Chairman of the Centre for Photomolecular Sciences, Imperial College, and Emeritus Professor of Chemistry of the Royal Institution of Great Britain.This book is divided into 11 chapters, each covering an area of Lord Porter's work. Each chapter will contain an introduction by Lord Porter, a selection of his most important papers in that field and a list of his other relevant papers.


Radicals

Radicals

Author: Nonhebel

Publisher: Cambridge University Press

Published: 1979-06-07

Total Pages: 220

ISBN-13: 9780521220040

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Chemical and Biochemical Physics, Kinetics and Thermodynamics

Chemical and Biochemical Physics, Kinetics and Thermodynamics

Author: Gennadiĭ Efremovich Zaikov

Publisher: Nova Publishers

Published: 2007

Total Pages: 272

ISBN-13: 9781604560244

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This book includes new and important research on antioxidants for chemistry and biology, kinetics and mechanisms of molecular, radical and ion reactions in chemistry and biochemistry, chemistry of ozone (reactions of ozone with organic and inorganic compounds, action of antiozonants), application of electron magnetic resonance and nuclear magnetic resonance in chemistry and biology, investigations of the structure and properties of nanocomposites (nanotubes, particularly), investigations on the structure and properties of nanocomposites (nanotubes, particularly), investigations of heterogeneous-heterophases mechanisms of reaction in polymer matrix, preparation and using of organic papanagnets for investigation of radical reactions in chemistry and biology, investigation of kinetic parameters in biochemical reactions, new designs for processing, mechanisms of oxidation and stabilisation of organic compounds (including polymers), polymer blends, composites and filled polymers (preparation, properties and application), and information about genetic construction, reactions with participants of enzymes.


Photochemistry of Organic Compounds

Photochemistry of Organic Compounds

Author: Petr Klán

Publisher: John Wiley & Sons

Published: 2009-01-28

Total Pages: 582

ISBN-13: 1444300008

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Photochemistry of Organic Compounds: From Concepts toPractice provides a hands-on guide demonstrating the underlyingprinciples of photochemistry and, by reference to a range oforganic reaction types, its effective use in the synthesis of neworganic compounds and in various applications. The book presents a complete and methodical approach to thetopic, Working from basic principles, discussing key techniques andstudies of reactive intermediates, and illustrating syntheticphotochemical procedures. Incorporating special topics and case studies covering variousapplications of photochemistry in chemistry, environmentalsciences, biochemistry, physics, medicine, and industry. Providing extensive references to the original literature andto review articles. Concluding with a chapter on retrosynthetic photochemistry,listing key reactions to aid the reader in designing their ownsynthetic pathways. This book will be a valuable source of information andinspiration for postgraduates as well as professionals from a widerange of chemical and natural sciences.


Reactive Intermediate Chemistry

Reactive Intermediate Chemistry

Author: Robert A. Moss

Publisher: John Wiley & Sons

Published: 2004-01-07

Total Pages: 1088

ISBN-13: 9780471233244

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Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.