Radical Reactions in Organic Synthesis

Radical Reactions in Organic Synthesis

Author: Samir Z. Zard

Publisher: Oxford Chemistry Masters

Published: 2003

Total Pages: 280

ISBN-13: 9780198502418

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Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.


Advanced Free Radical Reactions for Organic Synthesis

Advanced Free Radical Reactions for Organic Synthesis

Author:

Publisher: Elsevier

Published: 2004-01-14

Total Pages: 271

ISBN-13: 0080524257

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Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature


Stereochemistry of Radical Reactions

Stereochemistry of Radical Reactions

Author: Dennis P. Curran

Publisher: John Wiley & Sons

Published: 2008-09-26

Total Pages: 294

ISBN-13: 3527615229

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As little as a decade ago, radicals were regarded as interesting reactive intermediates with little synthetic use. However, recent results show that radicals have an enormous potential for applications in stereoselective reactions - it's all a matter of knowing what method to use and how to apply it. Three world experts in the field have combined their expertise and present the concepts to understand and even to predict the course of stereoselective radical reactions. In addition, guidelines are established which will enable the readers to plan and carry out their own stereoselective syntheses with radicals. A comprehensive list of references provides an easy access to the primary literature. The Stereochemistry of Radical Reactions is a highly topical introduction to this burgeoning field of research. Both advanced students and researchers active in the field will welcome this book as a source of concepts and ideas.


Free Radical Chain Reactions in Organic Synthesis

Free Radical Chain Reactions in Organic Synthesis

Author: William B. Motherwell

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 289

ISBN-13: 0080924956

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Written for both the experienced practitioner and the newcomer, this book provides essential guidance to the practical aspects of free radical chain reactions. The book presents tried and tested synthetic schemes as well as a selection of recently developed methods describing rationally designed, highly efficient syntheses giving high yield interconversions of functional groups and carbon*b1carbon bond formation under mild, neutral conditions. Written by two experienced practitioners in the field, this volume explodes the myth that free radicals are highly reactive, non-selective intermediates. Contains an extensive introduction discussing principles, advantages, and disadvantages of radical chain reactions Demonstrates functional group interconversions by radical chain reactions Lists carbon*b1carbon bond formations Presents inter- and intramolecular radical chain reactions Includes many examples and experimental details selected by experienced practitioners in this field


Radical Reactions in Aqueous Media

Radical Reactions in Aqueous Media

Author: V. Tamara Perchyonok

Publisher: Royal Society of Chemistry

Published: 2010

Total Pages: 142

ISBN-13: 1849730008

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Radical Reactions in Aqueous Media provides a step-wise introduction, taking students from the basic principles of radical reactions through to their applications in industry and their role in biological and environmental processes."--Jacket.


Radical Reactions in Organic Synthesis

Radical Reactions in Organic Synthesis

Author: Guerino Sacripante

Publisher:

Published: 1986

Total Pages: 256

ISBN-13:

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"$ alpha$-Bromo- and $ alpha{,} alpha$-dibromoazetidinones were converted stereoselectively to the $ alpha$-alkylazetidinones 149 and 153, or to $ beta$-alkylazetidinones 151, 154 and 159 by a free radical addition onto olefins 148 or allyltributyltin." --


Domino Reactions in Organic Synthesis

Domino Reactions in Organic Synthesis

Author: Lutz F. Tietze

Publisher: John Wiley & Sons

Published: 2006-12-13

Total Pages: 631

ISBN-13: 3527608680

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Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecological benign synthesis. A definite must for every organic chemist.


Ion-Radical Organic Chemistry

Ion-Radical Organic Chemistry

Author: Zory Vlad Todres

Publisher: CRC Press

Published: 2008-10-20

Total Pages: 496

ISBN-13: 9781420008395

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Consolidating knowledge from a number of disciplines, Ion-Radical Organic Chemistry: Principles and Applications, Second Edition presents the recent changes that have occurred in the field since the publication of the first edition in 2003. This volume examines the formation, transformation, and application of ion-radicals in typical conditions of organic synthesis. Avoiding complex mathematics, the author explains the principles of ion-radical organic chemistry and presents an overview of organic ion-radical reactions. He reviews methods of determining ion-radical mechanisms and controlling ion-radical reactions. Wherever applicable, the text addresses issues relating to ecology and biomedical concerns as well as inorganic participants of the ion-radical organic reactions. After reviewing the nature of organic ion-radicals and their ground-state electronic structure, the book discusses their formation, the relationship between electronic structure and reactivity, mechanism and regulation of reactions, stereochemical aspects, synthetic opportunities, and practical applications. Additional topics include electronic and opto-electronic devices, organic magnets and conductors, lubricants, other materials, and reactions of industrial or biomedical importance. The book concludes by providing an outlook on possible future development in this field. Researchers and practitioners engaged in active work on synthetic or mechanistic organic chemistry and its practical applications will find this text to be invaluable in both its scope and its depth.