Propylene Production from Ethylene - Cost Analysis - Propylene E21A

Propylene Production from Ethylene - Cost Analysis - Propylene E21A

Author: Intratec

Publisher: Intratec

Published: 2017-06-01

Total Pages: 106

ISBN-13: 1641481269

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This report presents a cost analysis of Polymer Grade (PG) Propylene production from ethylene using two integrated processes: dimerization and metathesis The processes examined are similar to CB&I Lummus technologies: Ethylene Dimerization Technology and Olefins Conversion Technology (OCT). In these processes, ethylene is first dimerized into butenes, and then, Propylene is produced through a metathesis reaction of 2-butene and ethylene. This report was developed based essentially on the following reference(s): (1) US Patent 8440874, issued to Lummus Technology and BASF in 2013 (2) US Patent 4242531, issued to Phillips Petroleum Company in 1980 Keywords: PG Propylene, Olefins Dimerization, Olefins Disproportionation, Lummus OCT, Olefins Metathesis, Phillips Triolefin, Propene, Ethene, On-Purpose Propylene Production


Epichlorohydrin Production from Propylene - Cost Analysis - ECH E21A

Epichlorohydrin Production from Propylene - Cost Analysis - ECH E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 102

ISBN-13:

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This report presents a cost analysis of Epichlorohydrin production from propylene and chlorine. The process examined is a typical dehydrochlorination process. This process involves three main steps: (i) chlorination of propylene to allyl chloride; (ii) addition of hypochlorous acid to the allyl chloride formed yielding glycerol dichlorohydrins, and (iii) treatment of the glycerol – dichlorohydrin mixture with a base, yielding Epichlorohydrin product. 99.9 wt.% Epichlorohydrin is obtained. This report was developed based essentially on the following reference(s): Rowe, C.E., 'Chlorohydrins', Chemical Processing Handbook, 1993 Keywords: 3-Chloropropene, Hypochlorous Acid, HOCl, Chlorination


Butyl Acrylate Production from Propylene and Butanol - Cost Analysis - Butyl Acrylate E21A

Butyl Acrylate Production from Propylene and Butanol - Cost Analysis - Butyl Acrylate E21A

Author: Intratec

Publisher: Intratec

Published: 2017-06-01

Total Pages: 102

ISBN-13: 1641480602

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This report presents a cost analysis of n-Butyl Acrylate production from chemical grade propylene and n-butanol The process examined is a typical propylene oxidation, followed by a typical esterification process. In this process, propylene passes through a two-stage vapor phase oxidation to generate an acrylic acid-containing gas, from which acrylic acid is recovered via absorption in water. The aqueous acrylic acid solution is purified via light solvent extraction to ester-grade acrylic acid to be combined with n-butanol in a esterification reactor to generate crude a crude ester stream that is furhter purified to generate high-purity butyl acrylate. This report was developed based essentially on the following reference(s): (1) "Acrylic Acid", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition (2) "Acrylic Acid and Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, 5th edition Keywords: Propene, Air Oxidation, Propenoic Acid, Nippon Shokubai, Rohm & Haas, Dow, Esterification, Nippon Shokubai, Mitsubishi, BASF


Ethylene Production via Cracking of Ethane/Propane - Cost Analysis - Ethylene E21A

Ethylene Production via Cracking of Ethane/Propane - Cost Analysis - Ethylene E21A

Author: Intratec

Publisher: Intratec Solutions

Published: 2019-09-17

Total Pages: 102

ISBN-13:

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This report presents a cost analysis of polymer grade (PG) Ethylene production starting from an ethane/propane mixture at a volume ratio of 4:1. A typical steam cracking process with front-end demethanization is employed. In this process, a mix of 80 vol% ethane and 20 vol% propane is thermally cracked in pyrolysis furnaces. In addition to polymer grade Ethylene, the process also generates polymer grade propylene and hydrogen-rich gas. This report was developed based essentially on the following reference(s): "Ethylene", Ullmann's Encyclopedia of Industrial Chemistry, 7th edition Keywords: Ethene, Propene, Hydrocarbon Pyrolysis, Cracking Furnace, Lummus, KBR, Technip, Linde, S&W


Impact Polypropylene via Gas Process - Cost Analysis - PP E21A

Impact Polypropylene via Gas Process - Cost Analysis - PP E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 103

ISBN-13:

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This report presents a cost analysis of Polypropylene (PP) impact copolymer production from polymer grade (PG) propylene and ethylene using a gas phase polymerization process. The process examined is similar to LyondellBasell Spherizone process. This process is based on the polymerization of PG propylene and ethylene in a multi-zone circulating reactor. This report was developed based essentially on the following reference(s): Keywords: PG Propylene, Propene, Ethene, MZCR, Gas-Phase Reactor, Bimodal


Butanol Production from Propylene and Syngas - Cost Analysis - Butanol E21A

Butanol Production from Propylene and Syngas - Cost Analysis - Butanol E21A

Author: Intratec

Publisher: Intratec Solutions

Published: 2016-05-01

Total Pages: 52

ISBN-13: 194532452X

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This report presents a cost analysis of n-Butanol production from propylene and syngas. The process examined is similar to the LP OXO technology jointly licensed by JM Davy and Dow, employing Selector 30 catalyst. In this process, the production ratio of n- to iso-butyraldehyde in the oxo reaction is about 30. The isobutyraldehyde is separated as a by-product and the n-butyraldehyde is hydrogenated to form n-Butanol as the final product. This report examines one-time costs associated with the construction of a United States-based plant and the continuing costs associated with the daily operation of such a plant. More specifically, it discusses: * Capital Investment, broken down by: - Total fixed capital required, divided in production unit (ISBL); infrastructure (OSBL) and contingency - Alternative perspective on the total fixed capital, divided in direct costs, indirect costs and contingency - Working capital and costs incurred during industrial plant commissioning and start-up * Production cost, broken down by: - Manufacturing variable costs (raw materials, utilities) - Manufacturing fixed costs (maintenance costs, operating charges, plant overhead, local taxes and insurance) - Depreciation and corporate overhead costs * Raw materials consumption, products generation and labor requirements * Process block flow diagram and description of industrial site installations (production unit and infrastructure) Keywords: Oxo Alcohol, Butyl Alcohol, n-Butanol, Johnson Matthey, Dow, LP Oxo, SELECTOR


Dimethyl Carbonate Production from Ethylene Carbonate - Cost Analysis - DMC E21A

Dimethyl Carbonate Production from Ethylene Carbonate - Cost Analysis - DMC E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 102

ISBN-13:

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This report presents a cost analysis of Dimethyl Carbonate (DMC) production from ethylene carbonate and methanol. The process examined is a typical transesterification process. In this process, ethylene carbonate and methanol are converted into dimethyl carbonate (DMC) and ethylene glycol in a reactive distillation column and purified DMC is obtained through an extractive distillation. Monoethylene glycol is generated as by-product. This report was developed based essentially on the following reference(s): Keywords: Transesteification, ethylene arbonate, DMC, methanol, MEG


Ethylene Dichloride Production from Ethylene and HCl - Cost Analysis - EDC E21A

Ethylene Dichloride Production from Ethylene and HCl - Cost Analysis - EDC E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 102

ISBN-13:

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This report presents a cost analysis of Ethylene Dichloride (EDC) production from ethylene and hydrogen chloride using an oxychlorination process. The process examined is similar to OxyVinyls process. This process involves an oxygen-based chlorination step, which is carried out in fluidized-bed reactors. This report was developed based essentially on the following reference(s): (1) US Patent 7585806, issued to OxyVinyls in 2009 (2) US Patent 5292703, originally issued to The Geon Company (assigned to OxyVinyls in 1999) Keywords: Ethene, 1,2-Dichloroethane, Mitsui, Fluidized-Bed Reactor


Ethylene Glycol Production from Carbon Dioxide - Cost Analysis - MEG E21A

Ethylene Glycol Production from Carbon Dioxide - Cost Analysis - MEG E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 101

ISBN-13:

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This report presents a cost analysis of Monoethylene Glycol (MEG) production from carbon dioxide (CO2) using an electrochemical process. The process examined is similar to Liquid Light process. In this process, CO2 is electrochemically converted to oxalic acid, which is then hydrogenated to MEG. This report was developed based essentially on the following reference(s): US Patents 20140221684 and 20140206895, both issued to Liquid Light in 2014 Keywords: Ethylene Glycol, Fiber Grade, Hydrogen Bromide, Bromine, 1,2-Ethanediol


Polytrimethylene Terephthalate Production - Cost Analysis - PTT E21A

Polytrimethylene Terephthalate Production - Cost Analysis - PTT E21A

Author: Intratec

Publisher: Intratec

Published: 2019-09-17

Total Pages: 102

ISBN-13:

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This report presents a cost analysis of Polytrimethylene Terephthalate (PTT) production starting from glucose syrup and terephthalic acid. The process examined combines a process similar to DuPont process for generating propanediol and a process similar to Degussa (now Evonik) process for producing PTT. In this process, a 70 wt% glucose-water syrup is used as raw material. This report was developed based essentially on the following reference(s): Keywords: 1,3-Polypropylene Terephthalate, TPA, Dimethyl Terephthalate, DMT, Bio-PDO, Trimethylene Glycol, PTT, Aerobic Fermentation