Polymeric Reagents and Catalysts

Polymeric Reagents and Catalysts

Author: Warren T. Ford

Publisher:

Published: 1986

Total Pages: 312

ISBN-13:

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Examines recent advances in the use of polymeric reagents and catalysts with a special emphasis on new compounds, synthetic methods, and industrial processes. Brings these advances to the attention of those who are involved in organic synthesis and desire a more thorough understanding of polymers and polymeric reagents. Contains comprehensive chapters devoted to polymeric oxidizing agents, Wittig reagents, and synthesis of cross-linked polymeric templates for chiral recognition. Presents opportunities for invention and use of many new polymeric reagents and catalysts.


Supported Catalysts and Their Applications

Supported Catalysts and Their Applications

Author: David C Sherrington

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 282

ISBN-13: 1847551963

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The need to improve both the efficiency and environmental acceptability of industrial processes is driving the development of heterogeneous catalysts across the chemical industry, including commodity, specialty and fine chemicals and in pharmaceuticals and agrochemicals. Drawing on international research, Supported Catalysts and their Applications discusses aspects of the design, synthesis and application of solid supported reagents and catalysts, including supported reagents for multi-step organic synthesis; selectivity in oxidation catalysis; mesoporous molecular sieve catalysts; and the use of Zeolite Beta in organic reactions. In addition, the two discrete areas of heterogeneous catalysis (inorganic oxide materials and polymer-based catalysts) that were developing in parallel are now shown to be converging, which will be of great benefit to the whole field. Providing a snapshot of the state-of-the-art in this fast-moving field, this book will be welcomed by industrialists and researchers, particularly in the agrochemicals and pharmaceuticals industries.


Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis

Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis

Author: Shinichi Itsuno

Publisher: John Wiley & Sons

Published: 2011-06-28

Total Pages: 674

ISBN-13: 1118063953

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This book reviews chiral polymer synthesis and its application to asymmetric catalysis. It features the design and use of polymer-immobilized catalysts and methods for their design and synthesis. Chapters cover peptide-catalyzed and enantioselective synthesis, optically-active polymers, and continuous flow processes. It collects recent advances in an important field of polymer and organic chemistry, with leading researchers explaining applications in academic and industry R & D.


Polymeric Materials in Organic Synthesis and Catalysis

Polymeric Materials in Organic Synthesis and Catalysis

Author: Michael R. Buchmeiser

Publisher: John Wiley & Sons

Published: 2006-03-06

Total Pages: 582

ISBN-13: 3527605681

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This is the first book to describe the synthesis and characterization of the materials used in polymer-supported synthesis. The authors cover not only the classical polymers and their use in homogeneous, heterogeneous and micellar catalysis, but also such new developments as "enzyme-labile linkers", illustrating how to simplify the purification process and avoid waste. The result is a wealth of useful information -- for beginners and experts alike - in one handy reference, removing the need for difficult and time-consuming research among the literature.


The Combinatorial Index

The Combinatorial Index

Author: Barry A. Bunin

Publisher: Elsevier

Published: 1998-04-15

Total Pages: 341

ISBN-13: 0080542409

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With the explosion of combinatorial solid-phase methods, access to information has become one of the main barriers facing a synthetic chemist who is contemplating a combinatorial approach to a medicinal chemistry problem. The Combinatorial Index is an answer to that problem. This compendium of methods from the primary literature provides quick and convenient access to reliable synthetic transformations as well as information on linkers and analytical methods. Each synthetic procedure is preceded by a section entitled"Points of Interest,"which highlights the strengths and weaknesses of the various studies. The index also covers the use of solution-based synthesis for the generation of molecular diversity. - Organized for rapid retrieval of published information on classes of synthetic transformations, linkers, and analytical methods - Serves as a laboratory manual for bench chemists - Includes a chapter on linkers to assist in choice of linking strategy - Discusses strengths and limitations of the various methods - Contains a structural index showing functional group transformations in solid-phase synthesis


Organic Syntheses Based on Name Reactions and Unnamed Reactions

Organic Syntheses Based on Name Reactions and Unnamed Reactions

Author: Alfred Hassner

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 462

ISBN-13: 1483287343

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Synthetically useful organic reactions or reagents are often referred to by the name of the discoverer(s) or developer(s). Older name reactions are described in text books, but more recently developed synthetically useful reactions that may have been associated occasionally with a name are not always well known. For neither of the above are experimental procedures or references easy to find. In this monograph approximately 500 name reactions are included, of which over 200 represent newer name reactions and modern reagents. Each of these reactions are extremely useful for the contemporary organic chemistry researcher in industry or academic institutions. This book provides the information in an easily accessible form. In addition to seminal references and reviews, one or more examples for each name reaction are provided and a complete typical experimental procedure is included, to enable the student or researcher to immediately evaluate reaction conditions. Besides an alphabetical listing of reactions and reagents, cross references permit the organic practitioner to find those name reactions or reagents that enable specific transformations, such as, conversion of amines to nitriles, stereoselective reduction, fluoroalkylation, phenol alkynylation, asymmetric syntheses, allylic alkylation, nucleoside synthesis, cyclopentanation, hydrozirconation, to name a few. Emphasis has been placed on stereoselective and regioselective transformations as well as on enantioselective processes. The listing of reactions and reagents is supported by four indexes.


Catalytic Olefin Polymerization

Catalytic Olefin Polymerization

Author: T. Keii

Publisher: Elsevier

Published: 1990-09-12

Total Pages: 597

ISBN-13: 0080887546

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Recent development of a new generation of Ziegler-Natta Catalysts using either magnesium dichloride as carrier or methylaluminoxane as cocatalyst has markedly stimulated the research activity in the field of olefin polymerization. These discoveries have not only yielded economical processes for polyolefin production but also opened the way to a new generation of novel polymers. Moreover, the nature of active species is being clarified well by the effort to simplify catalyst systems. The present volume includes 38 papers from the 31 lectures and 18 posters presented at the symposium on `Recent Developments in Olefin Polymerization Catalysts', which covered the following topics: Overview of super-active homogeneous and heterogeneous catalysts, kinetic profile of olefin polymerization including copolymerization, characterization of catalysts and polymers, methods for the determination of active center concentration, role of Lewis bases on the catalysts isospecificity, polymerization mechanisms, and synthetic pathways for functionalized polyolefins. The contents are well balanced between fundamental research and application as well as between homogeneous and heterogeneous catalyst systems.


Functionalized Polymers

Functionalized Polymers

Author: Narendra Pal Singh Chauhan

Publisher: CRC Press

Published: 2021-05-14

Total Pages: 304

ISBN-13: 1000291111

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Functionalized polymers are macromolecules to which chemically bound functional groups are attached which can be used as catalysts, reagents, protective groups, etc. Functionalized polymers have low cost, ease of processing and attractive features for functional organic molecules. Chemical reactions for the introduction of functional groups in polymers and the conversion of functional groups in polymers depend on different properties. Such properties are of great importance for functionalization reactions for possible applications of reactive polymers. This book deals with the synthesis and design of various functional polymers, the modification of preformed polymer backbones and their various applications.


Immobilized Catalysts

Immobilized Catalysts

Author: Andreas Kirschning

Publisher: Springer Science & Business Media

Published: 2004-11-22

Total Pages: 354

ISBN-13: 9783540209157

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R. Haag, S. Roller: Polymeric Supports for the Immobilisation of Catalysts .- J. Horn, F. Michalek, C.C. Tzschucke, W. Bannwarth: Non-Covalently Solid-Phase Bound Catalysts for Organic Synthesis .- Y. Uozumi: Recent Progress in Polymeric Palladium Catalysts for Organic Synthesis .- D.E. Bergbreiter, J. Li: Applications of Catalysts on Soluble Supports .- B. Desai, C.O. Kappe: Microwave-Assisted Synthesis Involving Immobilized Catalysts .- A. Kirschning, G. Jas: Applications of Immobilized Catalysts in Continuous Flow Processes .- N. End, K.-U. Schöning: Immobilized Catalysts in Industrial Research and Application .- N. End, K.-U. Schöning: Immobilized Biocatalysts in Industrial Research and Production