Use of polymers in product design has continued to grow at a rate unrivalled by conventional materials such as metal, ceramics or glass. More polymeric materials are becoming available to the designer, and this report highlights the need for caution in new design work, for careful use of new materials, and for awareness of the product environment. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database gives useful references for further reading.
Plastics and rubbers together make up the most adaptable and varied class of materials available to product designers. They may be transparent or opaque, rigid or flexible, lightweight, insulating, and weatherproof. They are used in almost every industry, and in every part of the home. Applications range from the humble hot water bottle to the sheathing on a high voltage cable, and from a simple scrubbing brush to a tank for storing hydrochloric acid. Products may be disposable (e.g. packaging goods) or intended to last for decades, such as a buried sewage pipe. However, it is this very diversity which makes materials selection so difficult, and appropriate design so important. Indeed the one thing that all these particular products have in common is their presence in this book of failures. Failures due to degradation may result from exposure to the weather or an aggressive operating environment. Alternatively they may be caused by the introduction of an external agent unforeseen by the product designer. They may be rapid or very slow, and they may result from a combination of factors. In this book Dr. Wright describes the following mechanisms of polymer degradation, and then illustrates each failure mechanism with a number of case studies: Thermo-oxidation, Photo-oxidation, Degradation due to ionising radiation, Chemical attack, Environmental stress cracking, Other miscellaneous effects, including treeing, electrochemical degradation and biodegradation. Many of the case studies are based on Dr. Wrights own experiences whilst working at Rapra. In each case he describes the circumstances of the failure, and discusses both the consequences of the failure and the lessons that may be learned from it. Most of the failed products are familiar to us all, and his style is both readable and informative. Photographs are included where available. The book will be essential reading for designers, engineers, product specifiers and forensic engineers. Materials suppliers and processors will also benefit from the pragmatic analysis and advice it contains. It will also be of value to all students of polymer science and technology, providing an essential insight into the practical application of plastics and rubbers and the potential problems. Finally, it will be of interest to a much broader readership, including anyone who ever wondered why things break, and it should become a standard reference work in all technical libraries. This book was written with the support of the UK Department of Trade and Industry. It is intended to raise awareness of the causes and consequences of polymer product failures, in order to reduce the future incidences of such failures, and their considerable costs to industry
Ein Praxisleitfaden der Polymeranalyse für alle, die sich in Polymerlabors mit Analytik, Qualitätskontrolle oder Produktentwicklung beschäftigen. Der Autor erläutert, aus seinem umfangreichen Erfahrungsschatz, welche Probleme in welchen Situationen auftreten können. Viele Fallstudien helfen bei der Anwendung der Erkenntnisse im Laboralltag. Mit einer umfangreichen Datensammlung zu physikalischen Eigenschaften von Polymeren! (07/00)
Fractography in Failure Analysis of Polymers provides a practical guide to the science of fractography and its application in the failure analysis of plastic components. In addition to a brief background on the theory of fractography, the authors discuss the various fractographic tools and techniques used to identify key fracture characteristics. Case studies are included for a wide range of polymer types, applications, and failure modes, as well as best practice guidelines enabling engineers to apply these lessons to their own work. Detailed images and their appropriate context are presented for reference in failure investigations. This text is vital for engineers who must determine the root causes of failure when it occurs, helping them further study the ramifications of product liability claims, environmental concerns, and brand image. Presents a comprehensive guide to applied fractography, enabling improved reliability and longevity of plastic parts and products Includes case studies that demonstrate material selection decisions and how to reduce failure rates Provides best practices on how to analyze the cause of material failures, along with guidelines on improving design and manufacturing decisions
Degradation reactions grouped under the heading chemical attack include oxidation hydrolysis, halogenation and other reactions. They also include some purely physical interactions between materials and fluids, dominated by the absorption of fluid into the material or vice versa. One particular mechanism described in some detail is acid induced stress corrosion cracking, which is the most frequent cause of premature failure of GRP products, and where the principle degradation reaction is between the fluid and the glass fibres. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database gives useful references for further reading.
The growing use of polymer composites is leading to increasing demand for fractographic expertise. Fractography is the study of fracture surface morphologies and it gives an insight into damage and failure mechanisms, underpinning the development of physically-based failure criteria. In composites research it provides a crucial link between predictive models and experimental observations. Finally, it is vital for post-mortem analysis of failed or crashed polymer composite components, the findings of which can be used to optimise future designs.Failure analysis and fractography of polymer composites covers the following topics: methodology and tools for failure analysis; fibre-dominated failures; delamination-dominated failures; fatigue failures; the influence of fibre architecture on failure; types of defect and damage; case studies of failures due to overload and design deficiencies; case studies of failures due to material and manufacturing defects; and case studies of failures due to in-service factors.With its distinguished author, Failure analysis and fractography of polymer composites is a standard reference text for researchers working on damage and failure mechanisms in composites, engineers characterising manufacturing and in-service defects in composite structures, and investigators undertaking post-mortem failure analysis of components. The book is aimed at both academic and industrial users, specifically final year and postgraduate engineering and materials students researching composites and industry designers and engineers in aerospace, civil, marine, power and transport applications. Examines the study of fracture surface morphologies in uderstanding composite structural behaviour Discusses composites research and post-modern analysis of failed or crashed polymer composite components Provides an overview of damage mechanisms, types of defect and failure criteria
The selection and application of engineered materials is an integrated process that requires an understanding of the interaction between materials properties, manufacturing characteristics, design considerations, and the total life cycle of the product. This reference book on engineering plastics provides practical and comprehensive coverage on how the performance of plastics is characterized during design, property testing, and failure analysis. The fundamental structure and properties of plastics are reviewed for general reference, and detailed articles describe the important design factors, properties, and failure mechanisms of plastics. The effects of composition, processing, and structure are detailed in articles on the physical, chemical, thermal, and mechanical properties. Other articles cover failure mechanisms such as: crazing and fracture; impact loading; fatigue failure; wear failures, moisture related failure; organic chemical related failure; photolytic degradation; and microbial degradation. Characterization of plastics in failure analysis is described with additional articles on analysis of structure, surface analysis, and fractography.
Fractography in Failure Analysis of Polymers, Second Edition, provides a practical guide to the science of fractography and its application in the failure analysis of plastic components. In addition to a brief background on the theory of fractography, the authors discuss the various fractographic tools and techniques used to identify key fracture characteristics. The Second Edition includes additional material related to polymer life prediction testing and analysis. Case studies have been expanded, including a wide range of polymer types, new technologies, applications, and failure modes, as well as best practice guidelines enabling engineers to apply these lessons to their own work. Detailed images and their appropriate context are presented for reference in failure investigations. This text is vital for engineers who must determine the root causes of failure when it occurs, helping them further study the ramifications of product liability claims, environmental concerns, and brand image. This is also a valuable resource for all plastics professionals, including manufacturers, product designers, and consultants, forensic investigators, as well as educators in materials science. Presents comprehensive coverage of applied fractography, enabling improved reliability and longevity of plastic parts and products Includes case studies that demonstrate material selection decisions and how to reduce failure rates Provides best practice on how to analyze the cause of material failures, along with guidelines on improving design and manufacturing decisions
The combined effects of oxidising media and heat result in degradation by thermo-oxidation. The principles and cases described in this review emphasise long term degradation in service. Two additional phenomena that influence thermo-oxidation are also described: catalysis by certain metal ions, and the influence of stress. An additional indexed section containing several hundred abstracts from the Polymer Library gives useful references for further reading.
Written by Puck's pupil and appointed successor Martin Knops, this book presents Alfred Puck ́s failure model, which, among several other theories, predicts fracture limits best and describes the failure phenomena in FRP most realistically – as confirmed within the "World-wide Failure Exercise". Using Puck ́s model the composite engineer can follow the gradual failure process in a laminate and deduce from the results of the analysis how to improve the laminate design.
