Physico-Chemical Analysis of Molten Electrolytes

Physico-Chemical Analysis of Molten Electrolytes

Author: Vladimir Danek †

Publisher: Elsevier

Published: 2006-09-14

Total Pages: 468

ISBN-13: 0080464963

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Physico-Chemical Analysis of Molten Electrolytes includes selected topics on the measurement and evaluation of physico-chemical properties of molten electrolytes. It describes the features, properties, and experimental measurement of different physico-chemical properties of molten salt systems used as electrolytes for different metal production, metallic layer deposition, as a medium for reactions in molten salts.The physico-chemical properties such as phase equilibria, density (molar volume), enthalpy (calorimetry), surface tension, vapor pressure, electrical conductivity, viscosity, etc. are the most important parameters of electrolytes needed for technological use. For each property the theoretical background, experimental techniques, as well as examples of the latest knowledge and the processing of most important salt systems will be given.The aim of Physico-Chemical Analysis of Molten Electrolytes is not only to present the state of the art on different properties of molten salts systems and their measurement, but also to present the possibilities of modeling molten salt systems, to be able to forecast the properties of an electrolyte mixture from the properties of the pure components in order to avoid experimentally demanding, and in most cases also expensive measurements.This book fills a substantial gap in this field of science. Also documententing the latest research in molten salts chemistry and brings new results and new insights into the study of molten salts systems using the results of X-ray diffraction and XAFS methods, Raman spectroscopy, and NMR measurements.* This book fills a substantial gap in this field of science* Serves as a invaluable reference for all people working in the field of molten salts chemistry* Describes fundamentals of the various properties of molten electrolytes


High Temperature Vapors

High Temperature Vapors

Author: John Hastie

Publisher: Academic Press

Published: 2012-12-02

Total Pages: 497

ISBN-13: 0323148131

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High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temperature vapor-phase chemistry, and the role of high-temperature vapors in materials science. The discussion then turns to gas-solid reactions with vapor products; chemical vapor transport and deposition; vapor-phase aspects of corrosion at high temperature; and flames and combustion. High-temperature vapor-phase processes associated with gas turbine systems are also considered. The final chapter is devoted to the chemistry of high-temperature species in space. This monograph should serve as a valuable reference for undergraduate and graduate students, as well as scientists in fields such as chemistry, physics, materials science, and metallurgy.


Physical Principles of Chemical Engineering

Physical Principles of Chemical Engineering

Author: Peter Grassmann

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 963

ISBN-13: 1483153843

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Physical Principles of Chemical Engineering covers the significant advancements in the understanding of the physical principles of chemical engineering. This book is composed of 12 chapters that describe chemical unit processes through analogy with the unit of operations of chemical engineering. The introductory chapters survey the concept and principles of mass and energy balances, as well as the application of entropy. The next chapters deal with the probability and kinetic theories of gases, the physical aspects of solids, the different dispersed systems, and the principles and application of fluid dynamics. Other chapters discuss the property dimension and model theory; heat, mass, and momentum transfer; and the characteristics of multiphase flow processes. The final chapters review the model of rheological bodies, the molecular-kinetic interpretations of rheological behavior, and the principles of reaction kinetics. This book will prove useful to chemical engineers.


Molten Salts Handbook

Molten Salts Handbook

Author: George J. Janz

Publisher: Elsevier

Published: 2013-06-11

Total Pages: 613

ISBN-13: 0323144837

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Molten Salts Handbook focuses on the features, properties, and structure of molten salts. This book presents several topics in annotated bibliographic table form, including phase equilibria, chemical syntheses, and molten salt electrolytes. Organized into six chapters, this book starts with a tabular presentation of data of the physical properties, thermodynamic properties, electrochemical properties, practical features, as well as spectroscopy and structure of molten salts. This text then illustrates the design features of different experimental assemblies and provides information on the technique through a liberally annotated bibliography. Other chapters provide a chemical index, which offers a ready guide to the status of data over the entire range of interests. This book presents as well the properties of viscosity, density, surface tension, refractive index, and electrical conductance for different compounds as single salt melts. This book is a valuable resource for scientists and researchers from diverse fields, including theoretical and applied electrochemistry, inorganic coordination chemistry, and transition metal chemistry.