This book covers various metallurgical topics, viz. roasting of sulfide minerals, matte smelting, slag, reduction of oxides and reduction smelting, interfacial phenomena, steelmaking, secondary steelmaking, role of halides in extraction of metals, refining, hydrometallurgy and electrometallurgy. Each chapter is illustrated with appropriate examples of applications of the technique in extraction of some common, reactive, rare or refractory metal together with worked out problems explaining the principle of the operation.
This updated, second edition retains its classroom-tested treatment of physical chemistry of metallurgical topics, such as roasting of sulfide minerals, matte smelting, converting, structure, properties and theories of slag, reduction of oxides and reduction smelting, interfacial phenomena, steelmaking, secondary steelmaking, role of halides in extraction of metals, refining, hydrometallurgy and electrometallurgy, and adds new data in worked-out examples as well as up-to-date references to the literature. The book further explains the physical chemistry of various metallurgical topics, steps involved in extraction of metals, such as roasting, matte smelting/converting, reduction smelting, steelmaking reactions, deoxidation, stainless steelmaking, vacuum degassing, refining, leaching, chemical precipitation, ion exchange, solvent extraction, cementation, gaseous reduction and electrowinning. Each topic is illustrated with appropriate examples of applications of the technique in extraction of some common, reactive, rare, or refractory metal together with worked out problems explaining the principle of the operation. The problems require imagination and critical analyses and also encourage readers for creative application of thermodynamic data in metal extraction. Updates and condenses text throughout the book by sequential arrangement of paragraphs in different chapters; Maximizes readers’ understanding of the physicochemical principles involved in extraction/production of common and rare/reactive metals by pyro- as well as hydrometallurgical routes; Reinforces concepts presented with worked examples in each chapter explaining the process steps; Explains the physical chemistry of various metallurgical steps, such as roasting, matte smelting/converting, and reduction smelting, steelmaking, aqueous processing etc. in extraction of metals; Collects and uniformly presents scattered information on physicochemical principles of metal production from various books and journals.
Chemical metallurgy is a well founded and fascinating branch of the wide field of metallurgy. This book provides detailed information on both the first steps of separation of desirable minerals and the subsequent mineral processing operations. The complex chemical processes of extracting various elements through hydrometallurgical, pyrometallurgical or electrometallurgical operations are explained. In the choice of material for this work, the author made good use of the synergy of scientific principles and industrial practices, offering the much needed and hitherto unavailable combination of detailed treatises on both compiled in one book.
In arid and semi-arid regions, where water demand exceeds water availability, water security is becoming a significant concern not only related to water availability but also to rigorous and costly requirements to remove conventional and emerging contaminants from effluents discharging into drinking water sources or as water reuse becomes an alternate water supply for communities in these regions. Water and wastewater treatment demands a great amount of energy and resources, highlighting the need for novel applications of the circular economy concept. Circular Economy Applications for Water Security examines knowledge gaps, avenues of future research, and challenges related to the potential of enhanced underutilized/waste materials as a transition to circular economy applications for ensuring the proper quality of water. This book includes fundamental information and practical examples that helps to better understand the concepts included. The circular economy concept is helpful to incept sustainability in the water treatment processes. Every chapter includes the identification of knowledge gaps, avenues for further research, and challenges that guide readers towards real state-of-the-art analysis. Contributors are experts in their areas and will commit to explaining concepts in a user-friendly way without missing scientific rigor.
This book offers various techniques for measurement of thermodynamic quantities of materials such as enthalpy, free energy, and entropy. Techniques described herein include calorimetry, chemical equilibria, vapour pressure, and electrochemical analysis. The book covers general and solution thermodynamics in Chapters 1 and 2, respectively, and highlights the significance of various thermodynamic quantities required for materials characterization and development in Chapter 3. The author goes on to discuss different thermodynamic measurement techniques in detail (Chapters 4-8) together with a set of more than fifty worked-out problems related to classical as well as solution thermodynamics and measurement techniques. (Chapter 9). Topics include but are not limited to the following: The significance of various thermodynamic data required for selection and characterization of materials. The physicochemical principles involved in various thermodynamic measurement and on the evaluation of thermodynamic data by phase diagram analyses. The unique combination of calorimetry and chemical equilibrium for simultaneous determination of partial molar enthalpy and partial molar free energy of hydrogen in metals and alloys. The special technique based on the combination of vapor pressure and electrical conductivity to study the effect of tellurium vapor pressure on the mode of conduction in polycrystalline cadmium telluride.
A circular and environment-friendly economy could displace the linear economy as it is in use around the world. This would involve enlarged life cycles for products, and an increase in the efficiency of electric and electronic devices. The generation of new materials will be essential, as well as materials recycling or conversion after use. This book discusses new ways of production, management, recycling and conversion of new and regular materials. Keywords: Microplastics, Lignocellulose-Based Materials, Food Packaging, Biorefinery, Solar Energy, Reused Materials, Recycling of Plastics, Biopolymers, Composites, Polymeric Systems, CO2 Capture, Anticorrosive Polymeric Coatings, Metallic Structures, Scrap for New Steel, Nanomaterials, Waste from Electronic Components, Future of Cars, Raw Materials, Biomaterials, Bioeconomy, Circular Bioeconomy, Polymeric Electrolytes, Fuel Cells.
This classic textbook has been reprinted by The Institute of Materials to provide undergraduates with a broad overview of metallurgy from atomic theory, thermodynamics, reaction kinetics and crystal physics, to elasticity and plasticity.
Originally published in 1985, this textbook provides a thorough and comprehensive coverage of a wide range of topics in stoichiometry and thermodynamics with special emphasis on applications to metallurgical processes. This book will be welcomed as a text for courses in elementary and advanced thermodynamics and stoichiometry.