Organic and Inorganic Low-Dimensional Crystalline Materials

Organic and Inorganic Low-Dimensional Crystalline Materials

Author: Pierre Delhaes

Publisher: Springer Science & Business Media

Published: 2013-12-01

Total Pages: 488

ISBN-13: 1489920919

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The research of unitary concepts in solid state and molecular chemistry is of current interest for both chemist and physicist communities. It is clear that due to their relative simplicity, low dimensional materials have attracted most of the attention. Thus, many non-trivial problems were solved in chain systems, giving some insight into the behavior of real systems which would otherwise be untractable. The NATO Advanced Research Workshop on "Organic and Inorganic Low-Dimensional Crystalline Materials" was organized to review the most striking electronic properties exhibited by organic and inorganic sytems whose space dimensionality ranges from zero (Od) to one (1d), and to discuss related scientific and technological potentials. The initial objectives of this Workshop were, respectively: i) To research unitary concepts in solid state physics, in particular for one dimensional compounds, ii) To reinforce, through a close coupling between theory and experiment, the interplay between organic and inorganic chemistry, on the one hand, and solid state physics on the other, iii) To get a salient understanding of new low-dimensional materials showing "exotic" physical properties, in conjunction with structural features.


Magnetic Molecular Materials

Magnetic Molecular Materials

Author: D. Gatteschi

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 413

ISBN-13: 9401132542

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One of the major challenges of science in the last few years of the second millennium is learning how to design materials which can fulfill specific tasks. Ambitious as it may be, the possibilities of success are not ne~li~ble provided that all the different expertises merge to overcome the limits of eXIsting disciplines and forming new paradigms science. The NATO Advanced Research Workshop on "Magnetic Molecular Materials" was organized with the above considerations in mind in order to determine which are the most appropriate synthetic strategies, experimental techniques of investigation, and theoretical models which are needed in order to develop new classes of magnetic materials which are based on molecules rather than on metallic or ionic lattices. Why molecules? The answer may be obvious: molecular chemistry in principle fine can tune the structures and the properties of complex aggregates, and nature already provides a large number of molecular aggregates which can perform the most disparate functions. The contributions collected in this book provide a rather complete view of the current research accomplishments of magnetic molecular materials. There are several different synthetic approaches which are followed ranging from purely organic to inorganic materials. Some encouraging successes have already been achieved, even if the critical temperatures below which magnetic order is observed still are in the range requiring liquid helium.


Lower-Dimensional Systems and Molecular Electronics

Lower-Dimensional Systems and Molecular Electronics

Author: Robert M. Metzger

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 729

ISBN-13: 1489920889

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This volume represents the written account of the NATO Advanced Study Institute "Lower-Dimensional Systems and Molecular Electronics" held at Hotel Spetses, Spetses Island, Greece from 12 June to 23 June 1989. The goal of the Institute was to demonstrate the breadth of chemical and physical knowledge that has been acquired in the last 20 years in inorganic and organic crystals, polymers, and thin films, which exhibit phenomena of reduced dimensionality. The interest in these systems started in the late 1960's with lower-dimensional inorganic conductors, in the early 1970's with quasi-one-dimensional crystalline organic conductors. which by 1979 led to the first organic superconductors, and, in 1977, to the fITSt conducting polymers. The study of monolayer films (Langmuir-Blodgett films) had progressed since the 1930's, but reached a great upsurge in . the early 1980's. The pursuit of non-linear optical phenomena became increasingly popular in the early 1980's, as the attention turned from inorganic crystals to organic films and polymers. And in the last few years the term "moleculw' electronics" has gained ever-increasing acceptance, although it is used in several contexts. We now have organic superconductors with critical temperatures in excess of 10 K, conducting polymers that are soluble and processable, and used commercially; we have films of a few monolayers that have high in-plane electrical conductivity, and polymers that show great promise in photonics; we even have a few devices that function almost at the molecular level.


Optical Switching in Low-Dimensional Systems

Optical Switching in Low-Dimensional Systems

Author: Hartmut Haug

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 374

ISBN-13: 146847278X

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This book contains all the papers presented at the NATO workshop on "Optical Switching in Low Dimensional Systems" held in Marbella, Spain from October 6th to 8th, 1988. Optical switching is a basic function for optical data processing, which is of technological interest because of its potential parallelism and its potential speed. Semiconductors which exhibit resonance enhanced optical nonlinearities in the frequency range close to the band edge are the most intensively studied materials for optical bistability and fast gate operation. Modern crystal growth techniques, particularly molecular beam epitaxy, allow the manufacture of semiconductor microstructures such as quantum wells, quantum wires and quantum dots in which the electrons are only free to move in two, one or zero dimensions, of the optically excited electron-hole pairs in these low respectively. The spatial confinement dimensional structures gives rise to an enhancement of the excitonic nonlinearities. Furthermore, the variations of the microstruture extensions, of the compositions, and of the doping offer great new flexibility in engineering the desired optical properties. Recently, organic chain molecules (such as polydiacetilene) which are different realizations of one dimensional electronic systems, have been shown also to have interesting optical nonlinearities. Both the development and study of optical and electro-optical devices, as well as experimental and theoretical investigations of the underlying optical nonlinearities, are contained in this book.


Growth and Optical Properties of Wide-Gap II–VI Low-Dimensional Semiconductors

Growth and Optical Properties of Wide-Gap II–VI Low-Dimensional Semiconductors

Author: T.C. McGill

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 338

ISBN-13: 146845661X

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This volume contains the Proceedings of the NATO Advanced Research Workshop on "Growth and Optical Properties of Wide Gap II-VI Low Dimensional Semiconductors", held from 2 - 6 August 1988 in Regensburg, Federal Republic of Germany, under the auspices of the NATO International Scientific Exchange Programme. Semiconducting compounds formed by combining an element from column II of the periodic table with an element from column VI (so called II-VI Semiconductors) have long promised many optoelectronic devices operating in the visible region of the spectrum. However, these materials have encountered numerous problems including: large number of defects and difficulties in obtaining p- and n-type doping. Advances in new methods of material preparation may hold the key to unlocking the unfulfilled promises. During the workshop a full session was taken up covering the prospects for wide-gap II-VI Semiconductor devices, particularly light emitting ones. The growth of bulk materials was reviewed with the view of considering II-VI substrates for the novel epitaxial techniques such as MOCVD, MBE, ALE, MOMBE and ALE-MBE. The controlled introduction of impurities during non-equilibrium growth to provide control of the doping type and conductivity was emphasized.


Charge Density Waves in Solids

Charge Density Waves in Solids

Author: L.P. Gor'kov

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 495

ISBN-13: 0444600736

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The latest addition to this series covers a field which is commonly referred to as charge density wave dynamics.The most thoroughly investigated materials are inorganic linear chain compounds with highly anisotropic electronic properties. The volume opens with an examination of their structural properties and the essential features which allow charge density waves to develop.The behaviour of the charge density waves, where interesting phenomena are observed, is treated both from a theoretical and an experimental standpoint. The role of impurities in statics and dynamics is considered and an examination of the possible role of solitons in incommensurate charge density wave systems is given. A number of ways to describe charge density waves theoretically, using computer simulations as well as microscopical models, are presented by a truely international board of authors.


Interacting Electrons in Reduced Dimensions

Interacting Electrons in Reduced Dimensions

Author: Dionys Baeriswyl

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 400

ISBN-13: 1461305659

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As its name suggests, the 1988 workshop on "Interacting Electrons in Reduced Dimen the wide variety of physical effects that are associated with (possibly sions" focused on strongly) correlated electrons interacting in quasi-one- and quasi-two-dimensional mate rials. Among the phenomena discussed were superconductivity, magnetic ordering, the metal-insulator transition, localization, the fractional Quantum Hall effect (QHE), Peierls and spin-Peierls transitions, conductance fluctuations and sliding charge-density (CDW) and spin-density (SDW) waves. That these effects appear most pronounced in systems of reduced dimensionality was amply demonstrated at the meeting. Indeed, when concrete illustrations were presented, they typically involved chain-like materials such as conjugated polymers, inorganic CDW systems and organie conductors, or layered materials such as high-temperature copper-oxide superconductors, certain of the organic superconductors, and the QHE samples, or devices where the electrons are confined to a restricted region of sample, e. g. , the depletion layer of a MOSFET. To enable this broad subject to be covered in thirty-five lectures (and ab out half as many posters), the workshop was deliberately focused on theoretical models for these phenomena and on methods for describing as faithfully as possible the "true" behav ior of these models. This latter emphasis was especially important, since the inherently many-body nature of problems involving interacting electrons renders conventional effec tive single-particle/mean-field methods (e. g. , Hartree-Fock or the local-density approxi mation in density-functional theory) highly suspect. Again, this is particularly true in reduced dimensions, where strong quantum fluctuations can invalidate mean-field results.


Nuclear Spectroscopy on Charge Density Wave Systems

Nuclear Spectroscopy on Charge Density Wave Systems

Author: T. Butz

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 333

ISBN-13: 940151299X

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Nuclear magnetic resonance (NMR), nuclear quadrupole resonance (NQR), time differential perturbed angular correlations (TDPAC), and the Mössbauer effect (ME) have been applied to the study of charge density wave (CDW) systems. These hyperfine techniques provide unique tools to probe the structure and symmetry of commensurate CDWs, give a clear fingerprint of incommensurate CDWs, and are ideally suited for CDW dynamics. This book represents a new attempt in the series `Physics and Chemistry of Materials with Low-dimensional Structures' to bring together a consistent group of scientific results obtained by nuclear spectroscopy related to CDW phenomena in pseudo-one- and two-dimensional systems. The individual chapters contain: the theory of CDWs in chain-like transition metal tetrachalcogenides; NMR, NQR, TDPAC, and ME investigations of layered transition metal dichalcogenides; NMR studies of CDW-transport in chain-like NbSe3 and molybdenum bronzes; multinuclear NMR of KCP; high resolution NMR of organic conductors. This book is of interest to graduate students and all scientists who want to acquire a broader knowledge of nuclear spectroscopy techniques applied to CDW systems.