Mesoporous materials are a class of molecules with a large and uniform pore size, highly regular nanopores, and a large surface area. This book is devoted to all aspects and types of these materials and describes, in an in-depth and systematic manner, the step-by-step synthesis and its mechanism, as well as the characterization, morphology control, hybridization, and applications, of mesoporous molecular sieves. In so doing, it covers silicates, metal-doped silicates, nonsilicates, and organic-inorganic hybrids. Although the emphasis is on synthesis, the expert authors also discuss characterization and applications, ranging from catalysis and biochemistry to optics and the use of these materials as templates for nanomaterial synthesis. Both the fundamentals and the latest research results are covered, ensuring that this monograph serves as a reference for researchers in and newcomers to the field.
Zeolites are the most frequently used industrial catalysts. Their applications range from oil refining, petrochemistry and the synthesis of special chemicals to environmental catalysis. Rapid progress in basic research and the development of new processes has resulted in the first Federation of European Zeolite Associations (FEZA) School on Zeolites. Zeolites and Ordered Mesoporous Materials: Progress and Prospects reflects the programme of the first School on Zeolites, held in Prague on August 20-21, 2005. Readers gain insight into the synthesis of the ever-expanding spectrum of zeolites, zeotypes and ordered mesoporous materials including the use of zeolites and mesoporous materials as catalysts in organic conversions. These range from the fascinating ship-in-bottle systems via cascade reactions to bulk applications in oil-refining and petrochemistry. Contributions from world experts enhance the book, with select chapters on trends in the molecular sieves field, zeolite structures, ion-exchange properties of zeolites, advanced applications (with unique technologies and opportunities) and a chapter on natural zeolites.* Contains contributions from world experts in the field * Includes an account of the frontier topic of high-throughput techniques* Reviews the application of quantum-chemical methods to zeolite science to show the necessity of combining experimental and theoretical approaches
"Functional Materials textbook is not simply a review of the vast body of literature of the recent years, as it holds the focus upon various aspects of application. Moreover, it selects only a few topics in favor of a solid and thorough treatment of the relevant aspects. This book comes in a good time, when a large body of academic literature has been accumulated and is waiting for a critical inspection in the light of the real demands of application." Professor Gerhard Wegner, Max-Planck Institute for Polymer Research, Mainz, Germany The chapters cover three important fields in the development of functional materials: energy, environment, and biomedical applications. These topics are explained and discussed from both an experimental and a theoretical perspective. Functional organic and inorganic materials are at the center of most technological breakthroughs. Therefore, the understanding of material properties is fundamental to the development of novel functionalities and applications.
The developments in the area of ordered nanoporous solids have moved beyond the traditional catalytic and separation uses and given rise to a wide variety of new applications in different branches of chemistry, physics, material science, etc. The activity in this area is due to the outstanding properties of nanoporous materials that have attracted the attention of researchers from different communities. However, recent achievements in a specific field often remain out of the focus of collaborating communities. This work summarizes the latest developments and prospects in the area of ordered porous solids, including synthetic layered materials (clays), microporous zeolite-type materials, ordered mesoporous solids, metal-organic-framework compounds (MOFs), carbon, etc. All aspects, from synthesis via comprehensive characterization to the advanced applications of ordered porous materials, are presented. The chapters are written by leading experts in their respective fields with an emphasis on recent progress and the state of the art. - Summarizes the latest developments in the field of ordered nanoporous solids - Presents state-of-the-art coverage of applications related to porous solids - Incorporates 28 contributions from experts across the disciplines
Nanostructured materials with tailored properties are regarded as a fundamental element in the development of future science and technology. Research is still ongoing into the nanosized construction elements required to create functional solids. The recently developed technique, nanocasting, has great advantage over others in terms of the synthesis of special nanostructured materials by the careful choice of suitable elements and nanoengineering steps. This new book summarizes the recent developments in nanocasting, including the principles of nanocasting, syntheses of novel nanostructured materials, characterization methods, detailed synthetic recipes and further possible development in this area. The book focuses on the synthesis of porous solids from the viewpoint of methodology and introduces the science of nanocasting from fundamental principles to their use in synthesis of various materials. It starts by outlining the principles of nanocasting, requirements to the templates and precursors and the tools needed to probe matter at the nanoscale level. It describes how to synthesize nano structured porous solids with defined characteristics and finally discusses the functionalization and application of porous solids. Special attention is given to new developments in this field and future perspectives. A useful appendix covering the detailed synthetic recipes of various templates including porous silica, porous carbon and colloidal spheres is included which will be invaluable to researchers wanting to follow and reproduce nanocast materials. Topics covered in the book include: * inorganic chemistry * organic chemistry * solution chemistry * sol-gel and interface science * acid-base equilibria * electrochemistry * biochemistry * confined synthesis The book gives readers not only an overview of nanocasting technology, but also sufficient information and knowledge for those wanting to prepare various nanostructured materials without needing to search the available literature.
The Zeolites and Mesporous Materials at the Dawn of the 21st Century Proceedings are the expression of the oral and poster communications which where presented during the 13th International Zeolite Conference (IZC). They are subdivided into 32 thematic sessions starting from the genesis of materials to their applications through their characterisation. The paper volume contains the full texts of the 5 plenary and 6 keynote lectures and informative summaries of 150 oral and 540 poster presentations. These contributions have been selected among the 903 submissions received from a total of 57 countries! In order to gather all the communications in a handy document, the full texts of oral and poster presentations are available in CD-ROM. Besides the fields of zeolite science always represented at IZC (synthesis, characterisation, catalysis, etc¿), some subjects strengthened their position (mesoporous materials, theory and modelling), new areas emerge (advanced materials, environmental and life sciences) and older ones regain interest (natural zeolites). The understanding and development of the unique properties of porous materials relies on a unique blend of multidisciplinary knowledge: material science, with the implication of organic and colloid chemistry, to prepare micro- and mesoporous materials, surface and adsorption science sustained by theory and modelling to understand the peculiar behaviour of molecules in confined systems, special branches of catalysis, physics, chemical engineering and life science to design novel applications. The gathering of these elements is at the basis of a fruitful and evolutionary zeolite science, as it is hopefully reflected by these proceedings.
Widely used in adsorption, catalysis and ion exchange, the family of molecular sieves such as zeolites has been greatly extended and many advances have recently been achieved in the field of molecular sieves synthesis and related porous materials. Chemistry of Zeolites and Related Porous Materials focuses on the synthetic and structural chemistry of the major types of molecular sieves. It offers a systematic introduction to and an in-depth discussion of microporous, mesoporous, and macroporous materials and also includes metal-organic frameworks. Provides focused coverage of the key aspects of molecular sieves Features two frontier subjects: molecular engineering and host-guest advanced materials Comprehensively covers both theory and application with particular emphasis on industrial uses This book is essential reading for researches in the chemical and materials industries and research institutions. The book is also indispensable for researches and engineers in R&D (for catalysis) divisions of companies in petroleum refining and the petrochemical and fine chemical industries.
The original properties of mesoporous molecular sieves are so unique that the design of most existing catalysts could be reconsidered. It might indeed be of interest to introduce MMS either as a support or as the active phase, merely on the basis of their high surface areas, narrow pore size distribution and flexibility in composition. The recent literature provides examples of MMS based catalysts of many types such as acid-base solids, supported metals and supported oxides, mixed oxides, anchored complexes and clusters, grafted organic functional groups and others. Examples of all these developments are documented in the present proceedings including some spectacular new proposals. The new metallic (Pt) mesophases are specially worth mentioning because they represent a new approach to producing non-supported highly dispersed metals.In these proceedings the reader will find feature articles and regular papers from many worldwide groups, covering all aspects of synthesis, physical characterization and catalytic reactivity of MMS and their chemically modified forms. It is actually remarkable that this recent development brought together an even broader spectrum of scientists from traditionally unrelated fields such as those of liquid crystals, surfactants, sol-gels, amorphous oxides and mixed oxides, solid state, adsorbents and heterogeneous catalysts. Obviously, this is a fast-growing research area which triggers the imagination and creativity at the cross-road between material design, molecular surface tailoring and catalytic applications.
This book follows up an Advanced Research Workshop dedicated to the subject of adsorption. It presents an up-to-date review of the latest achievements in the synthesis, characterization and applications of hybrid organic-inorganic materials and of carbon and combined adsorbents. The modeling of the adsorption process, including the simulation of carbon masks used for both civil and military protection purposes is also addressed. Includes applications in environmental, military and post-disaster situations.
Porous materials are of scientific and technological importance because of the presence of voids of controllable dimensions at the atomic, molecular, and nanometer scales, enabling them to discriminate and interact with molecules and clusters. Interestingly the big deal about this class of materials is about the “nothingness” within — the pore space. International Union of Pure and Applied Chemistry (IUPAC) classifies porous materials into three categories — micropores of less than 2 nm in diameter, mesopores between 2 and 50 nm, and macropores of greater than 50 nm. In this book, nanoporous materials are defined as those porous materials with pore diameters less than 100 nm.Over the last decade, there has been an ever increasing interest and research effort in the synthesis, characterization, functionalization, molecular modeling and design of nanoporous materials. The main challenges in research include the fundamental understanding of structure-property relations and tailor-design of nanostructures for specific properties and applications. Research efforts in this field have been driven by the rapid growing emerging applications such as biosensor, drug delivery, gas separation, energy storage and fuel cell technology, nanocatalysis and photonics. These applications offer exciting new opportunities for scientists to develop new strategies and techniques for the synthesis and applications of these materials.This book provides a series of systematic reviews of the recent developments in nanoporous materials. It covers the following topics: (1) synthesis, processing, characterization and property evaluation; (2) functionalization by physical and/or chemical treatments; (3) experimental and computational studies on fundamental properties, such as catalytic effects, transport and adsorption, molecular sieving and biosorption; (4) applications, including photonic devices, catalysis, environmental pollution control, biological molecules separation and isolation, sensors, membranes, hydrogen and energy storage, etc./a
