Aimed at researchers and graduate students, this book provides up-to-date information for understanding electronic interactions that impact the optical properties of rare earth ions in solids. Its goal is to establish a connection between fundamental principles and the materials properties of rare-earth activated luminescent and laser optical materials. The theoretical survey and introduction to spectroscopic properties include electronic energy level structure, intensities of optical transitions, ion-phonon interactions, line broadening, and energy transfer and up-conversion. An important aspect of the book lies in its deep and detailed discussions on materials properties and the potential of new applications such as optical storage, information processing, nanophotonics, and molecular probes that have been identified in recent experimental studies. This volume will be a valuable reference book on advanced topics of rare earth spectroscopy and materials science.
Modern optical technology calls for new glasses with special properties for optical and optoelectronic devices. This text, based on modern quantum optical theories, aims to relate optical and spectroscopic properties to the composition and structure of glass-forming materials.
Provides a semi-quantitative approach to recent developments in the study of optical properties of condensed matter systems Featuring contributions by noted experts in the field of electronic and optoelectronic materials and photonics, this book looks at the optical properties of materials as well as their physical processes and various classes. Taking a semi-quantitative approach to the subject, it presents a summary of the basic concepts, reviews recent developments in the study of optical properties of materials and offers many examples and applications. Optical Properties of Materials and Their Applications, 2nd Edition starts by identifying the processes that should be described in detail and follows with the relevant classes of materials. In addition to featuring four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry, the book covers: optical properties of disordered condensed matter and glasses; concept of excitons; photoluminescence, photoinduced changes, and electroluminescence in noncrystalline semiconductors; and photoinduced bond breaking and volume change in chalcogenide glasses. Also included are chapters on: nonlinear optical properties of photonic glasses; kinetics of the persistent photoconductivity in crystalline III-V semiconductors; and transparent white OLEDs. In addition, readers will learn about excitonic processes in quantum wells; optoelectronic properties and applications of quantum dots; and more. Covers all of the fundamentals and applications of optical properties of materials Includes theory, experimental techniques, and current and developing applications Includes four new chapters on optoelectronic properties of organic semiconductors, recent advances in electroluminescence, perovskites, and ellipsometry Appropriate for materials scientists, chemists, physicists and electrical engineers involved in development of electronic materials Written by internationally respected professionals working in physics and electrical engineering departments and government laboratories Optical Properties of Materials and Their Applications, 2nd Edition is an ideal book for senior undergraduate and postgraduate students, and teaching and research professionals in the fields of physics, chemistry, chemical engineering, materials science, and materials engineering.
During the last fifteen years the field of the investigation of glasses has experienced a period of extremely rapid growth, both in the development of new theoretical ap proaches and in the application of new experimental techniques. After these years of intensive experimental and theoretical work our understanding of the structure of glasses and their intrinsic properties has greatly improved. In glasses we are con fronted with the full complexity of a disordered medium. The glassy state is characterised not only by the absence of any long-range order; in addition, a glass is in a non-equilibrium state and relaxation processes occur on widely different time scales even at low temperatures. Therefore it is not surprising that these complex and novel physical properties have provided a strong stimulus for work on glasses and amorphous systems. The strikingly different properties of glasses and of crystalline solids, e. g. the low temperature behaviour of the heat capacity and the thermal conductivity, are based on characteristic degrees of freedom described by the so-called two-level systems. The random potential of an amorphous solid can be represented by an ensemble of asymmetric double minimum potentials. This ensemble gives rise to a new class of low-lying excitations unique to glasses. These low-energy modes arise from tunneling through a potential barrier of an atom or molecule between the two minima of a double-well.
This book is devoted to the problem of the frequency dispersion of optical constants of inorganic glasses. It is the only source providing a comprehensive discussion of this topic on a unified physical and analytical basis. Optical Constants of Inorganic Glasses presents thorough descriptions of the underlying physical phenomena, analytical models for the optical constants dispersion, and detailed information on the optical constants and related optical characteristics of glasses. The broad scope of the book includes such topics as general relationships for the response of a solid to the effect of an electromagnetic field, and specific features of optical spectrum formation for a glass and the resulting constants. The text details methods for reconstructing the spectra of optical constants from raw experimental spectra of glasses, and provides data on the spectra of optical constants in the IR and VUV ranges and on the IR band parameters for inorganic glasses. It includes factors responsible for the behavior of the refractive index dispersion of glasses in the transparency range. The reference fully details the opportunities provided by the recent version of dispersion analysis for glasses based on the specific analytical model for the complex dielectric constant. Until now, this information was only available in Russian journals. A large quantity of never-before-published data on numerical values of optical constants in the medium and far IR and of IR band frequencies and intensities is given for a wide variety of inorganic glasses. For vitreous silica, data on the optical constants are also given for the broad wavelength range in the VUV. Optical Constants of Inorganic Glasses provides the only comprehensive review of available dispersion formulas and methods for interpolating and extrapolating the refractive indices of glasses in the transparency range. The volume is a valuable resource for researchers, practitioners in the fields of glass technology
Seven independently-authored chapters consider selected topics related to the rapidly growing interest in optical glass among scientists who were hitherto satisfied with opaque ceramics. They cover oxide, halide, and photochromic glasses; nonlinear optical properties; optical basicity; optical fiber
This book provides a concise and inexpensive introduction for an undergraduate course in glass science and technology. The level of the book has deliberately been maintained at the introductory level to avoid confusion of the student by inclusion of more advanced material, and is unique in that its text is limited to the amount suitable for a one term course for students in materials science, ceramics or inorganic chemistry. The contents cover the fundamental topics of importance in glass science and technology, including glass formation, crystallization, phase separation and structure of glasses. Additional chapters discuss the most important properties of glasses, including discussion of physical, optical, electrical, chemical and mechanical properties. A final chapter provides an introduction to a number of methods used to form technical glasses, including glass sheet, bottles, insulation fibre, optical fibres and other common commercial products. In addition, the book contains discussion of the effects of phase separation and crystallization on the properties of glasses, which is neglected in other texts. Although intended primarily as a textbook, Introduction to Glass Science and Technology will also be invaluable to the engineer or scientist who desires more knowledge regarding the formation, properties and production of glass.
Spectroscopic Properties of Inorganic and Organometallic Compounds: Techniques, Materials and Applications provides a unique source of information in an important area of chemistry.
This book presents a comprehensive introduction to the design of compact and broadband fiber and waveguide devices using active-ion-doped photonic glasses. Combining cutting-edge theory with new applications, it shows how the complementarity of emission spectra of different active ions can be used in broadband fiber amplifiers and optical fiber communication, and describes how the quantum cutting of active ions can improve the match between the solar spectrum and the responsiveness of silicon cells. Mathematical modeling is used to predict the performance of photonic fiber and waveguide devices, and experimental data from glass doped with rare-earth ions is included. Offering unique insights into the state-of-the-art of the field, this is an ideal reference for researchers and practitioners, and invaluable reading for students in optoelectronics, electrical engineering, and materials science.