Nitrones, Nitronates and Nitroxides Updates

Nitrones, Nitronates and Nitroxides Updates

Author: Eli Breuer

Publisher:

Published: 1989-03-22

Total Pages: 456

ISBN-13:

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The structure of nitrones and the role in synthesis of nitronic acid derivatives are among the many related topics discussed in this collection of essays, focusing on the latest experimentation in nitrone research.


Synthetic Chemistry of Stable Nitroxides

Synthetic Chemistry of Stable Nitroxides

Author: L. B. Volodarsky

Publisher: CRC Press

Published: 2017-11-22

Total Pages: 287

ISBN-13: 1351357417

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This important book is devoted to covering the synthetic aspects of nitroxide chemistry. The problems of application and physicochemical properties of nitroxides are considered in the context of the choice of necessary radical structures, convenient precursors, and strategy of the synthesis. The book offers comparisons of the concrete classes of nitroxides to help reveal the structural peculiarities and synthetic abilities of compounds of different classes. It also summarizes data on the magneto-structural correlation for the metal complexes with 3-imidazoline nitroxides and considers the ways in which the molecular design of 2- and 3-dimensional heterospin compounds is capable of magnetic phase transfer in a ferromagnetic state. The book will be a significant reference for chemists, biochemists, spectroscopists, and other users of nitroxides, spin labels, probes, and paramagnetic ligands.


Nitrile Oxides, Nitrones and Nitronates in Organic Synthesis

Nitrile Oxides, Nitrones and Nitronates in Organic Synthesis

Author: Henry Feuer

Publisher: John Wiley & Sons

Published: 2008-01-02

Total Pages: 768

ISBN-13: 9780470191545

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A comprehensive systematization of current novel data in nitrile oxide chemistry, this book authoritatively covers systematic strategies currently used in the preparation and utilization of nitrile oxides, nitrones, and nitronates in organic synthesis. It covers factors governing their stability and includes in-depth information on stable and unstable nitrile oxides. With contributions from leading experts, this is a definitive reference for practicing professionals in organic or medicinal chemistry and an excellent text for students studying organic synthesis.


Nitroxides

Nitroxides

Author: Alexander Kokorin

Publisher: BoD – Books on Demand

Published: 2012-09-12

Total Pages: 450

ISBN-13: 9535107224

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Nitroxide (aminoxyl) radicals became the start point for one of the most interesting and rapidly developing areas of modern chemical physics with valuable applications to biophysics, molecular biology, polymer sciences and medicine. This book, consisting of 15 chapters gathered in 3 sections, written by authors actively involved in the area of spin label/probe technique. The authors describe in detail some novel trends and analyze new approaches of practical applications of nitroxide radicals. The book, recommended by the Governing Council of N. Semenov International Center of Chemical Physics, Moscow, will be of help to many scientists: chemists, physical chemists, biophysicists, biologists, physicians and other experts in a variety of disciplines, in which spin labels and probes are used, as well as to students and PhD students. It may be also suitable for teaching, and may help to promote the progress in natural sciences.


Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, Volume 59

Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, Volume 59

Author: Albert Padwa

Publisher: John Wiley & Sons

Published: 2003-04-14

Total Pages: 952

ISBN-13: 0471461369

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Dipolar cycloaddition reactions have found many useful applications in chemistry, particularly with respect to the synthesis of compounds with new chiral centers. Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products updates the popular 1984 edition, featuring the advances made over the past twenty years and focusing on synthetic applications.


Nitroxides

Nitroxides

Author: Olivier Ouari

Publisher: Royal Society of Chemistry

Published: 2021-05-13

Total Pages: 611

ISBN-13: 1788019660

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Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.


March's Advanced Organic Chemistry

March's Advanced Organic Chemistry

Author: Michael B. Smith

Publisher: John Wiley & Sons

Published: 2007-01-29

Total Pages: 2379

ISBN-13: 0470084944

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The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations


Nitroxide Spin Labels

Nitroxide Spin Labels

Author: Nickolai Kocherginsky

Publisher: CRC Press

Published: 1995-05-11

Total Pages: 286

ISBN-13: 9780849342042

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Extending the use of nitroxides as probes into more complex systems such as viable cells and whole animals requires greater knowledge of their interactions in functioning biological systems and appropriate model systems. Nitroxide Spin Labels: Reactions in Biology and Chemistry presents information essential for research in this area. Nitroxide research offers the promise of important new ways of measuring metabolism and will be useful in the diagnosis of important disease categories such as cancer, inflammation, and ischemia.


Nitroxides

Nitroxides

Author: Gertz I. Likhtenshtein

Publisher: John Wiley & Sons

Published: 2008-06-25

Total Pages: 438

ISBN-13: 352762175X

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Covering all aspects of this field, this volume also critically discusses recent results obtained with the use of nitroxides, while providing an analysis of future developments. Written by a group of scientists with long-term experience in investigating the chemistry, physicochemistry, biochemistry and biophysics of nitroxides, the book is not intended as an exhaustive survey of each topic, but rather a discussion of their theoretical and experimental background, as well as recent advances. The first four chapters expound the general theoretical and experimental background and the advantages of modern ESR technique. Chapter 5 focuses on fundamentals and recent results in the preparation and basic chemical properties, while the next two chapters briefly outline principles and current results in nitroxides as spin probes, and as redox probes and spin traps. These chapters form the basis for the subsequent more detailed studies of nitroxides in physicochemistry, while the final chapters concentrate on the advantages of magnetic materials on the basis of nitroxides. Finally, the concluding chapter considers the rapidly developing field of biomedical, therapeutic and clinical applications. With more than 1,100 references to essential literature, this volume provides fundamental knowledge of instrumentation, data interpretation, capacity and recent advantages of nitroxide applications, allowing readers to understand how nitroxides can help them in solving their own problems.


The Nitro Group in Organic Synthesis

The Nitro Group in Organic Synthesis

Author: Noboru Ono

Publisher: John Wiley & Sons

Published: 2003-05-08

Total Pages: 392

ISBN-13: 0471458465

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The most useful reactions of organonitro compounds in organic synthesis Compounds containing nitro groups are useful intermediates for the synthesis of natural products and other complex organic molecules. The Nitro Group in Organic Synthesis focuses on reactions that proceed under mild conditions, important functional groups that can be synthesized by conversion of nitro groups, and the stereoselectivity of reactions of nitro compounds. These issues are of great importance to practicing researchers in today's pharmaceutical, agrochemical, and fine chemical industries. The Nitro Group in Organic Synthesis also emphasizes environmentally-friendly methods for nitration, the importance of aliphatic nitro compounds, and modern preparation of nitro compounds. Other topics discussed include: * Henry reaction * Asymmetric Michael addition * Alkylation, acylation, halogenation, and related reactions of RNO2 * Substitution and elimination of NO2 and RNO2 The Nitro Group in Organic Synthesis is a useful resource for researchers and students in organic and medicinal chemistry.