Modern Aspects of Electrochemistry 42
Modern Aspects of Electrochemistry 42

Author: Constantinos G. Vayenas

Publisher: Springer Science & Business Media

Published: 2008-03-08

Total Pages: 434

ISBN-13: 0387494898

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This volume analyzes and summarizes recent developments in several key interfacial electrochemical systems in the areas of fuel cell electrocatatalysis, electrosynthesis and electrodeposition. The six Chapters are written by internationally recognized experts in these areas and address both fundamental and practical aspects of several existing or emerging key electrochemical technologies. The Chapter by R. Adzic, N. Marinkovic and M. Vukmirovic provides a lucid and authoritative treatment of the electrochemistry and electrocatalysis of Ruthenium, a key element for the devel- ment of efficient electrodes for polymer electrolyte (PEM) fuel cells. Starting from fundamental surface science studies and interfacial considerations, this up-to-date review by some of the pioneers in this field, provides a deep insight in the complex catalytic-electrocatalytic phenomena occurring at the interfaces of PEM fuel cell electrodes and a comprehensive treatment of recent developments in this extremely important field. Several recent breakthroughs in the design of solid oxide fuel cell (SOFC) anodes and cathodes are described in the Chapter of H. Uchida and M. Watanabe. The authors, who have pioneered several of these developments, provide a lucid presentation d- cribing how careful fundamental investigations of interfacial electrocatalytic anode and cathode phenomena lead to novel electrode compositions and microstructures and to significant practical advances of SOFC anode and cathode stability and enhanced electrocatalysis.

Modern Aspects of Electrochemistry, Number 38
Modern Aspects of Electrochemistry, Number 38

Author: B. E. Conway

Publisher: Springer Science & Business Media

Published: 2006-02-02

Total Pages: 556

ISBN-13: 0387258388

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This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.

Modern Aspects of Electrochemistry
Modern Aspects of Electrochemistry

Author: B. E. Conway

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 497

ISBN-13: 1461574439

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As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.

Modern Aspects of Electrochemistry
Modern Aspects of Electrochemistry

Author: John O'M. Bockris

Publisher: Springer Science & Business Media

Published: 2006-04-18

Total Pages: 357

ISBN-13: 0306469103

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Prof. Jerzy Sobkowski starts off this 31st volume of Modern Aspects of Electrochemistry with a far-ranging discussion of experimental results from the past 10 years of interfacial studies. It forms a good background for the two succeeding chapters. The second chapter is by S. U. M. Khan on quantum mechanical treatment of electrode processes. Dr. Khan’s experience in this area is a good basis for this chapter, the contents of which will surprise some, but which as been well refereed. Molecular dynamic simulation is now a much-used technique in physical electrochemistry and in the third chapter Ilan Benjamin has written an account that brings together information from many recent publications, sometimes confirming earlier modeling approaches and sometimes breaking new territory. In Chapter 4, Akiko Aramata’s experience in researching single crystals is put to good advantage in her authoritative article on under- tential deposition. Finally, in Chapter 5, the applied side of electrochemistry is served by Bech-Neilsen et al. in the review of recent techniques for automated measurement of corrosion. J. O’M. Bockris, Texas A&M University B. E. Conway, University of Ottawa R. E. White, University of South Carolina Contents Chapter 1 METAL/SOLUTION INTERFACE: AN EXPERIMENTAL APPROACH Jerzy Sobkowski and Maria Jurkiewicz-Herbich I. Introduction.............................................. 1 II. Molecular Approach to the Metal/Solution Interface............. 3 1. Double-Layer Structure: General Considerations .......... 3 2. Solid Metal/Electrolyte Interface.......................... 8 3. Methods Used to Study Properties ofthe Metal/Solution Interface: Role of the Solvent and the Metal............. 15 The Thermodynamic Approach to the Metal/Solution Interface 35 III.

Modern Aspects of Electrochemistry No. 20
Modern Aspects of Electrochemistry No. 20

Author: John O'M. Bockris

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 528

ISBN-13: 1468487620

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Starts with the most fundamental aspects of the subject and work to the more complex. Topics treated include the electron overlap contribution to the double layer potential difference; the electron transfer theory; farzdaic rectification; photoelectrochemical reduction of CO 2; aluminum in aqueous s

Modern Aspects of Electrochemistry No. 4
Modern Aspects of Electrochemistry No. 4

Author: J. O’M. Bockris

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 323

ISBN-13: 1468409131

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The fourth volume of Modern Aspects of Electrochemistry is being prepared at a time of great growth of interest in electro chemistry. The situation can be summarized by saying that the realization is spreading among scientists that electrochemistry represents a broad interdisciplinary field, which has applications to many areas in physics, chemistry, metallurgy, and biology. Among the reasons for this awakening is the reorientation of what is understood under electrochemistry toward electrodics "the study of charged interfaces"-with the ionic-solution aspects of electrochemistry being regarded increasingly as aspects of physical chemistry which are helpful auxiliaries to the broad subject of charged interfaces. The pervasiveness of electrochemistry be comes clearer when one recalls that most interfaces carry a charge, or undergo local charge transfers, even though they are not con nected with a source of power. A further reason for the rapid increase in electrochemical studies arises from the technological aspects, in particular in energy conversion and storage, syntheses, extractions, devices, the stability and finishing of surfaces, the treatment of water, etc. The fact that electrodics allows the conversion of chemical to electric energy and the storage of the latter, at the same time producing fresh water as a by-product, presents an aspect of the subject which appears to have far-reaching significance.

Progress in Reaction Kinetics
Progress in Reaction Kinetics

Author: G. Porter

Publisher: Elsevier

Published: 2013-09-03

Total Pages: 532

ISBN-13: 1483224953

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Progress in Reaction Kinetics, Volume 4 is a 10-chapter text that focuses on the reactions of nitrogen atoms in the gas phase and some chemical factors in the kinetics of processes at electrodes. This volume describes first the free radical reactions dealing with halogenomethyl and alkoxyl radicals. The next chapters deal with electronically excited states, proton transfer, and kinetics of electrode processes. These topics are followed by discussions on the primary processes in the gas phase photochemistry of carbonyl compounds, as well as the mechanisms and rates of radiationless energy transfer. This book also looks into the methods used for the measurement of fluorescence lifetimes of aromatic compounds. A chapter examines the chemiluminescence in the oxidation of organic compounds and for other liquid-phase reactions. The last chapters discuss the role of the solvent in proton transfer reactions and some aspects of developments in the field of electrode processes. This book is of great value to reaction kinetics scientists and researchers.

Organic Inhibitors of Corrosion of Metals
Organic Inhibitors of Corrosion of Metals

Author: Y.I. Kuznetsov

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 295

ISBN-13: 1489919562

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Organic Inhibitors of Corrosion of Metals provides a detailed review of the various theories advanced to explain the mechanisms of organic inhibitors. Author Yu.I. Kuznetsov explores the role of potential and charge of the metal, the nature of the organic species used as the inhibitor, and the function of the solvent. The author draws connections between these key elements and the processes of passivation, pitting, synergism, and complex formation. This unique volume brings together the mechanistic and practical aspects of corrosion control by organic inhibitors.

Electrochemical Reduction of Carbon Dioxide
Electrochemical Reduction of Carbon Dioxide

Author: Frank Marken

Publisher: Royal Society of Chemistry

Published: 2018-05-21

Total Pages: 282

ISBN-13: 1788014529

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One of the crucial challenges in the energy sector is the efficient capture and utilisation of CO2 generated from fossil fuels. Carbon capture and storage technologies can provide viable alternatives for energy intensive processes, although implementation of large-scale demonstrators remains challenging. Therefore, innovative technologies are needed that are capable of processing CO2 emission from a wide range of sources, ideally without additional fossil energy demand (e.g. solar driven or overcoming the limits of photosynthesis). This book covers the most recent developments in the field of electrochemical reduction of CO2, from first-principle mechanistic studies to technological perspectives. An introduction to basic concepts in electrochemistry and electrocatalysis is included to provide a background for newcomers to this field. This book provides a comprehensive overview for researchers and industrial chemists working in environmental science, electrochemistry and chemical engineering.