Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water
Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water

Author: B. Widman

Publisher:

Published: 2003

Total Pages:

ISBN-13:

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Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

Mass Transfer and Kinetics of Ion Exchange
Mass Transfer and Kinetics of Ion Exchange

Author: L. Liberti

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 461

ISBN-13: 940096899X

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While ion-exchange processes were originally used for the treatment of very dilute solutions, many applications for the treatment of concentrated solu tions have been developed in recent years. In these situations, the mass transfer bottlenecks are located in the~, rather than the liquid phase. Therefore, the development of quantitative models for ion-exchange kinetics requires knowledge about the conductance characteristics of ions and solvent in the solid phase. A useful approach towards this aim is the study of trans port characteristics of these species, and of their interactions in solid ion exchange membranes. Many different transport processes and related phenomena can be observed in membrane-solution systems, e.g., ion migration, electroosmosis, diffusion arid self-diffusion, osmosis, hydraulic flow, hyperfiltration (reverse osmosis) or ultrafiltration, streaming potential and streaming current, and membrane potentials (also called "membrane concentration potentials"). It is important to correlate all these phenomena so as to avoid a very large number of unnec essary measurements. Such correlation is often possible [Meares, 1976] since all these phenomena are determined by the ease of migration of the different species across the membrane. Important correlations have been made and summar ized even before high-capacity ion-exchange membranes became commercially available [Sollner, 1950, 197iJ.

Ion Exchange and Solvent Extraction
Ion Exchange and Solvent Extraction

Author: Arup K. SenGupta

Publisher: CRC Press

Published: 2004-03-01

Total Pages: 397

ISBN-13: 0824755359

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Reflecting the sustained and diverse experimental momentum in the field of ion exchange, Volume 16 summarizes revolutionary advances on par with the consistently high-level research related by this series. This text discusses the kinetics, theoretical models, experimental results/supporting data, and applications for isothermal supersaturation, metal separation via pH-induced parametric pumping, and for ultrapure water (UPW). Topics also include the engineering of activated carbons and carbonaceous materials for removal of metal ions; hydrophobic ionizable organic compounds (HIOCs); the sorption/desorption mechanisms of organic micropollutants in water; and ion exchange process variables on perchlorate treatment.

Demineralization by Ion Exchange in Water Treatment and Chemical Processing of Other Liquids
Demineralization by Ion Exchange in Water Treatment and Chemical Processing of Other Liquids

Author: Samuel B. Applebaum

Publisher:

Published: 1968

Total Pages: 416

ISBN-13:

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Survey of the impurities in water, their harmful effects in industry, and methods of removing them. The demineralization process and systems. Demineralizer equipment designs. Demineralizer technical design calculations and typical examples. Demineralizing water treatment in nuclear (Atomic) power plants. Comparison of evaporators and demineralizers and new demineralizer processes for desalination. Chemical processing by ion exchange.

Ion Exchange
Ion Exchange

Author: Friedrich G. Helfferich

Publisher: Courier Corporation

Published: 1995-01-01

Total Pages: 642

ISBN-13: 9780486687841

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Comprehensive text provides sound understanding of the relevant factors in ion exchange and the theoretical tools needed to solve specific problems. Detailed coverage of ion exchangers, equilibria, kinetics, electrochemical properties, ion-exchanger membranes, much more. Each chapter contains helpful summary and references. Accessible to nonmathematical students. Introduction. 1962 edition.

Ion Exchange in Environmental Processes
Ion Exchange in Environmental Processes

Author: Arup K. SenGupta

Publisher: John Wiley & Sons

Published: 2017-08-10

Total Pages: 730

ISBN-13: 1119421292

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Provides a comprehensive introduction to ion exchange for beginners and in-depth coverage of the latest advances for those already in the field As environmental and energy related regulations have grown, ion exchange has assumed a dominant role in offering solutions to many concurrent problems both in the developed and the developing world. Written by an internationally acknowledged leader in ion exchange research and innovation, Ion Exchange: in Environmental Processes is both a comprehensive introduction to the science behind ion exchange and an expert assessment of the latest ion exchange technologies. Its purpose is to provide a valuable reference and learning tool for virtually anyone working in ion exchange or interested in becoming involved in that incredibly fertile field. Written for beginners as well as those already working the in the field, Dr. SenGupta provides stepwise coverage, advancing from ion exchange fundamentals to trace ion exchange through the emerging area of hybrid ion exchange nanotechnology (or polymeric/inorganic ion exchangers). Other topics covered include ion exchange kinetics, sorption and desorption of metals and ligands, solid-phase and gas-phase ion exchange, and more. Connects state-of-the-art innovations in such a way as to help researchers and process scientists get a clear picture of how ion exchange fundamentals can lead to new applications Covers the design of selective or smart ion exchangers for targeted applications—an area of increasing importance—including solid and gas phase ion exchange processes Provides in-depth discussion on intraparticle diffusion controlled kinetics for selective ion exchange Features a chapter devoted to exciting developments in the areas of hybrid ion exchange nanotechnology or polymeric/inorganic ion exchangers Written for those just entering the field of ion exchange as well as those involved in developing the “next big thing” in ion exchange systems, Ion Exchange in Environmental Processes is a valuable resource for students, process engineers, and chemists working in an array of industries, including mining, microelectronics, pharmaceuticals, energy, and wastewater treatment, to name just a few.

Electrodialysis and Electrodialysis Reversal
Electrodialysis and Electrodialysis Reversal

Author: American Water Works Association

Publisher: American Water Works Association

Published: 1995-04-30

Total Pages: 63

ISBN-13: 0898677688

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This manual provides information on electrodialysis and electrodialysis reversal technologies in water treatment. This clearly written manual explains principles of operation, applications for water treatment, equipment, system design, costs, pretreatment and posttreatment, installation, operation, maintenance, and disposal of concentrate.

Ion Exchange and Solvent Extraction
Ion Exchange and Solvent Extraction

Author: Yitzhak Marcus

Publisher: CRC Press

Published: 2004-07-23

Total Pages: 416

ISBN-13: 9781135518813

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Volume 17 in the Ion Exchange and Solvent Extraction series represents the vanguard of research on solvent extraction. It covers the principles of electrolyte extraction and other subjects of increasing interest to the field. This volume begins with pharmaceutical applications of supercritical fluid solvents, particularly supercritical carbon dioxide. It also contains chapters on liquid ion exchangers and relevant experiment protocols, SCF applications in drug formulation and pollution reduction, exploiting SCF as reaction media, applications of metal bis(dicarbollide) in analytical chemistry and radioactive waste treatment, and synergistic extraction of metal ions. Volume 17 discusses the ion exchange isothermal supersaturation technique, metal separation via pH-induced parametric pumping, modeling of ion exchange kinetics for ultrapure water, and the engineering of activated carbons and carbonaceous materials for removal of metal ions and organic micropollutants in water. Volume 17 cover topics that include supercritical fluid applications, applications of metal bis(dicarbollide), and synergistic extraction of metal ions.