Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces focuses on the formation of phase morphology in polymer blends and copolymers and considers various types of blends including thermosets, thermoplastics, thermoplastic vulcanizates, and structured copolymers. The book carefully debates the processing
Micro- and Nanostructured Multiphase Polymer Blend Systems: Phase Morphology and Interfaces focuses on the formation of phase morphology in polymer blends and copolymers and considers various types of blends including thermosets, thermoplastics, thermoplastic vulcanizates, and structured copolymers. The book carefully debates the processing
Multiphase polymeric systems include a wide range of materials such as composites, blends, alloys, gels, and interpenetrating polymer networks (IPNs). A one-stop reference on multiphase polymer systems, this book fully covers the preparation, properties, and applications of advanced multiphase systems from macro to nano scales. Edited by well-respected academics in the field of multiphase polymer systems, the book includes contributions from leading international experts. An essential resource for plastic and rubber technologists, filler specialists and researchers in fields studying thermal and electrical properties.
Crystallization in Multiphase Polymer Systems is the first book that explains in depth the crystallization behavior of multiphase polymer systems. Polymeric structures are more complex in nature than other material structures due to their significant structural disorder. Most of the polymers used today are semicrystalline, and the subject of crystallization is still one of the major issues relating to the performance of semicrystalline polymers in the modern polymer industry. The study of the crystallization processes, crystalline morphologies and other phase transitions is of great significance for the understanding the structure-property relationships of these systems. Crystallization in block copolymers, miscible blends, immiscible blends, and polymer composites and nanocomposites is thoroughly discussed and represents the core coverage of this book. The book critically analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale. Various experimental techniques used for the characterization of polymer crystallization process are discussed. Written by experts in the field of polymer crystallization, this book is a unique source and enables professionals and students to understand crystallization behavior in multiphase polymer systems such as block copolymers, polymer blends, composites and nanocomposites. - Covers crystallization of multiphase polymer systems, including copolymers, blends and nanocomposites - Features comprehensive, detailed information about the basic research, practical applications and new developments for these polymeric materials - Analyzes the kinetics of nucleation and growth process of the crystalline phases in multi-component polymer systems in different length scales, from macro to nanoscale
During the past 10 years a large variety of new multiphase polymer-based materials have been studied from a morphological point of view. Simultaneously, huge progress has been achieved in microscopy. These circumstances underline the need for a reference that delineates the differences of various types of nanostructures in multiphase polymer-based
Micro and Nano Fibrillar Composites (MFCs and NFCs) from Polymer Blends is a comprehensive reference for researchers, students and scientists working in the field of plastics recycling and composites. The book aims to determine the influence of micro and nanofibrillar morphology on the properties of immiscible blend systems. Chapters cover micro and nanofibrillar composites based on polyolefin, liquid crystal polymer, biodegradable polymers, polyester and polyamide blends in various industrial application fields. The book brings together panels of highly-accomplished experts in the field of plastics recycling, blends and composites systems. For several decades, plastic technology has played an important role in many industrial applications, such as packaging, automobiles, aerospace and construction. However the increasing use of plastics creates a lot of waste. This has led to restrictions on the use of some plastics for certain applications and a drive towards recycling of plastics. More recently, microfibrillar in-situ composites have been prepared from waste plastics such as PET/PP, PET/PE and Nylon/PP as a way of formulating new high performance polymer systems. This book tackles these issues and more, and is an ideal resource for anyone interested in polymer blends. - Provides information on MFC and NFC based polymer blends that have been accumulated over the last 25 years, providing a useful reference - Adopts a novel approach in terms of understanding the relationship between processing, morphology, structure, properties and applications in micro and nanofibrillar composites - Contains contributions from leading experts in the field from both industrial and academic research
The design of polymer blends constitutes an interesting alternative to obtaining micro- and nanostructured surfaces. The cost is reasonable and it is free from time-consuming procedures. Blending of polymers can yield materials with unprecedented properties that cannot be provided otherwise by using a single polymer. The free surface topography of polymer blend films, often related to phase domain structure, is critical to the applications. Two main aspects need to be considered in the preparation of multistructured blends: the interfaces involved and the morphology to be obtained. The control of these two aspects depends further on materials-related parameters involving the composition of the blend, the interfacial tension or viscosity ratio, and the processing conditions related to the temperature, time, or intensity of mixing, among others. Both domain structure and topography of the blend films have garnered increasing interest over the past decade. This chapter describes the nanomicrostructures formed at the polymer surface from polymer blends. Despite the crucial role that surfaces play in the final application of the material, up to now most of the studies concerning polymer blends have been related to the control of the mechanical properties (toughness, stiffness, thermal expansion, etc.), their barrier properties, or the electrical conductivity. This chapter focuses on the analysis of the structured polymer surfaces and thin films, giving an overview of the role of these structures on the final application. The principles of phase separation and the resulting structures formed are briefly discussed, followed by a wide overview of the possibilities of producing stimuli-responsive interfaces by introducing, among other things, pH- or temperature-responsive polymers within the blend. Finally, we look at how using particular preparation conditions and/or self-assembly of block copolymers, the formation of films and surfaces with hierarchical order length-scales can be induced. We also examine the main areas in which multiscale-ordered interfaces obtained from polymer blends have been applied.
Over 30% of commercial polymers are blends or alloys or one kind or another. Nanostructured blends offer the scientist or plastics engineer a new range of possibilities with characteristics including thermodynamic stablility; the potential to improve material transparency, creep and solvent resistance; the potential to simultaneously increase tensile strength and ductility; superior rheological properties; and relatively low cost. Nanostructured Polymer Blends opens up immense structural possibilities via chemical and mechanical modifications that generate novel properties and functions and high-performance characteristics at a low cost. The emerging applications of these new materials cover a wide range of industry sectors, encompassing the coatings and adhesives industry, electronics, energy (photovoltaics), aerospace and medical devices (where polymer blends provide innovations in biocompatible materials). This book explains the science of nanostructure formation and the nature of interphase formations, demystifies the design of nanostructured blends to achieve specific properties, and introduces the applications for this important new class of nanomaterial. All the key topics related to recent advances in blends are covered: IPNs, phase morphologies, composites and nanocomposites, nanostructure formation, the chemistry and structure of additives, etc. - Introduces the science and technology of nanostructured polymer blends – and the procedures involved in melt blending and chemical blending to produce new materials with specific performance characteristics - Unlocks the potential of nanostructured polymer blends for applications across sectors, including electronics, energy/photovoltaics, aerospace/automotive, and medical devices (biocompatible polymers) - Explains the performance benefits in areas including rheological properties, thermodynamic stablility, material transparency, solvent resistance, etc.
This book summarizes many of the recent research accomplishments in the area of polyvinylchloride (PVC)-based blends and their preparation, characterization and applications. Various sub-topics are addressed, such as the state-of-the-art of PVC based blends, new challenges and opportunities, emphasis being given to the types and sizes of components/fillers and optimum compositions of PVC blends, their processing and structure-properties relationships, modification/compatibilization methods, and possible applications. PVC/thermoplastic based nano, micro and macro blends, PVC membranes, bio-based plasticizers and PVC blends with components from renewable resources are reported. The various chapters in this book are contributed by prominent researchers from industry, academia and government/private research laboratories across the globe. It covers an up-to-date record on the major findings and observations in the field of PVC-based blends.
This book examines the current state of the art, new challenges, opportunities, and applications of IPNs. With contributions from experts across the globe, this survey is an outstanding resource reference for anyone involved in the field of polymer materials design for advanced technologies. • Comprehensively summarizes many of the recent technical research accomplishments in the area of micro and nanostructured Interpenetrating Polymer Networks • Discusses various aspects of synthesis, characterization, structure, morphology, modelling, properties, and applications of IPNs • Describes how nano-structured IPNs correlate their multiscale structure to their properties and morphologies • Serves as a one-stop reference resource for important research accomplishments in the area of IPNs and nano-structured polymer systems • Includes chapters from leading researchers in the IPN field from industry, academy, government and private research institutions
